摘要:
The invention relates to ionic compounds in which the anionic load has been displaced, and the uses of these compounds. A compound disclosed by the invention comprises an anionic portion combined with at least one cationic portion M+m in sufficient numbers to ensure overall electronic neutrality. The anionic portion is comprised of one of the groups (A) and (B): wherein Y1, Y2, Y3, Y4 and Y5 represent a carbonyl group, a sulfonyl group, a thiocarbonyl group, a thionyl group, a —C(═NCN)— or a —C(═C(CN)2)— group; Z represents an electroattractive radical; each of the substituents, RA, RB, RC and RD represents independently of one another a monovalent or divalent organic radical or is part of a polymer chain, with at least one of the substituents RC and RD being a perfluorinated radical. The compounds can be used especially for ionic conducting materials, electronic conducting materials, colorants, and the catalysis of various chemical reactions.
摘要:
The invention relates to ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention includes an anionic portion combined with at least one cationic portion Mm+ in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic load is carried by a pentacyclical nucleus of tetrazapentalene derivative bearing electroattractive substituents. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorant, and the catalysis of various chemical reactions.
摘要:
The invention relates to ionic compositions having a high ionic conductivity comprising a salt with a delocalized anionic charge. An ionic composition comprises a salt in solution in a solvent and has a conductivity of greater than 10−5 S.cm−1 between −30° C. and 150° C. The cation is a proton, a hydronium, a hydroxonium, a nitrosonium NO+, an ammonium NH4+ or a metal, organic or organometallic cation. The anion is a carbanion carrying a perfluorinated substituent or a substituent carrying at least one F on the carbon &agr; to the carbanion and two nonperfluorinated electron-withdrawing substituents. Use as electrolyte in electrochemical devices, as catalyst of chemical reactions, or as photochemical or thermochemical initiator for polymerization or crosslinking reactions.
摘要:
The invention relates to ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention includes an anionic portion combined with at least one cationic portion Mm+ in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic load is carried by a pentacyclical nucleus of tetrazapentalene derivative bearing electroattractive substituents. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorant, and the catalysis of various chemical reactions.
摘要:
The invention is related to ionic compounds, derivatives of malononitrile, in which the anionic load has been displaced. An ionic compound disclosed by the invention includes an anionic portion combined with at least one cationic portion M+m in sufficient number to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion corresponds to one of the formulas RD—Y—C(C≡N)2− or Z—C(C≡N)2− in which Z is an electroattractive group, RD is an organic radical, and Y is a carbonyl, a thiocarbonyl, a sulfonyl, a sulfinyl, or a phosphonyl. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants, and the catalysis of various chemical reactions.
摘要:
The invention concerns ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention is comprised of an amide or one of its salts, including an anionic portion combined with at least one cationic portion M+m in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic portion matches the formula RF—SOx—N−Z, where RF is a perflourinated group, x is 1 or 3, and Z is an electroattractive substituent. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorants and the catalysis of various chemical reactions.
摘要:
The invention relates to ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention includes an anionic portion combined with at least one cationic portion Mm+ in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic load is carried by a pentacyclical nucleus of tetrazapentalene derivative bearing electroattractive substituents. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorant, and the catalysis of various chemical reactions.
摘要:
Grafting a polymer at the surface of a carbonated material containing carboxyl amine and/or hydroxyl functions at its surface. This material is suspended in a solution comprising the polymer to be grafted, which includes a carboxyl amine and/or hydroxyl function, the solution also comprising a solvent of the polymer. This is followed by a treatment causing dehydration into a carboxyl function, an amide and/or hydroxyl function and the polymer is thus grafted on the carbonated material by means of ester or amide bonds. Utilization in the cathode or anode of an electrochemical generator, in a polymer material with low polarity, in an ink, and as a conductive deposit on flexible plastic used as electrical contact, electromagnetic protection and antistatic protection.
摘要:
The present invention relates to copolymers, to a process for their preparation and to their use for the production of ionically conductive materials. A copolymer according to the invention consists of monomer units corresponding to the formula --CH.sub.2 --O--CHR--CH.sub.2 O (I) and monomer units corresponding to the formula --CH.sub.2 --CHR'--O-- (II), in which: R denotes a hydrogen atom, a linear or branched alkyl radical containing from 1 to 8 carbon atoms or a radical CH.sub.3 (--O--CH.sub.2 --CH.sub.2).sub.n --O--CH.sub.2 --, in which 1.ltoreq.n.ltoreq.10; R' denotes an aliphatic radical containing an unsaturation which can be polymerized by a radical route and inert in the conditions of cationic polymerization. The copolymers can be obtained by cationic polymerization of the appropriate oxirane and dioxolane. Application to the production of ionically conductive materials.
摘要:
The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator. The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.