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11.发明申请PROCESS FOR SULPHUR RECOVERY WITH CONCURRENT HYDROGEN PRODUCTION FROM NH3 CONTAINING FEED 审中-公开从含NH3含量进行同时生产的硫回收方法公开(公告)号：US20150291420A1
公开(公告)日：2015-10-15
申请号：US14441162
申请日：2013-11-08
发明人： Michele COLOZZI , Lucia BARBATO , Fabio ANGELINI , Emma PALO , Vincenzo PALMA , Vincenzo VAIANO
IPC分类号： C01B3/04 , B01J27/051 , B01J21/04
CPC分类号： C01B3/04 , B01J21/04 , B01J27/0515 , C01B3/047 , Y02E60/364
摘要： Disclosed is a method for the production of hydrogen from a H2S-containing gas stream also containing ammonia, comprising subjecting both gas stream to catalytic oxidative cracking of both the H2S and the NH3, so as to form H2, S2 and N2. In this method, preferably, an additional amount of oxygen is added as compared to the amount used for H2S catalytic oxidative cracking. Also, preferably, the contact time of the gas stream with the catalyst is increased. The catalyst preferably is provided as a single bed, and then preferably comprises iron and molybdenum supported by a carrier comprising aluminum. The preferred carrier is alumina. The iron and molybdenum preferably are in the form of sulfides.
摘要翻译： 公开了一种从含有氨的含H2S的气体流中生产氢气的方法，包括使两种气流同时进行H2S和NH3两者的催化氧化裂解，以形成H2，S2和N2。 在该方法中，与用于H 2 S催化氧化裂化的量相比，优选加入附加量的氧。 此外，优选地，气流与催化剂的接触时间增加。 催化剂优选以单一床提供，然后优选包含由包含铝的载体担载的铁和钼。 优选的载体是氧化铝。 铁和钼优选为硫化物的形式。
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12.发明申请公开(公告)号：US20150283537A1
公开(公告)日：2015-10-08
申请号：US14441155
申请日：2013-11-08
发明人： Michele Colozzi , Lucia Barbato , Fabio Angelini , Emma Palo , Vincenzo Palma , Vincenzo Vaiano
CPC分类号： B01J27/0515 , B01J23/881 , B01J35/08 , B01J37/0201 , B01J37/0207 , B01J37/0215 , B01J37/08 , B01J37/20 , C01B3/04 , C01B17/046 , C01B17/0465 , C01B17/0495 , Y02E60/364
摘要： Disclosed is a catalyst suitable for the catalytic oxidative cracking of a H2S-containing gas stream, particularly in the event that the stream also contains methane and/or ammonia. The catalyst comprises iron and molybdenum supported by a carrier comprising aluminium. The carrier preferably is alumina. The iron and molybdenum preferably are in the form of sulphides. Also disclosed is a method for the production of hydrogen from a H2S-containing gas stream, comprising subjecting the gas stream to catalytic oxidative cracking so as to form H2 and S2, using a catalyst in accordance with any one of the preceding claims.
摘要翻译： 公开了一种适用于含H2S的气流的催化氧化裂解的催化剂，特别是在流还含有甲烷和/或氨的情况下。 催化剂包括由包含铝的载体负载的铁和钼。 载体优选为氧化铝。 铁和钼优选为硫化物的形式。 还公开了一种用于从含H 2 S的气流生产氢的方法，包括使用根据前述权利要求中任一项的催化剂使气流进行催化氧化裂化以形成H 2和S 2。
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公开(公告)号：US08956585B2
公开(公告)日：2015-02-17
申请号：US13010885
申请日：2011-01-21
IPC分类号： C01B17/00 , C01B25/14 , C01D5/08 , C01G39/06 , B01J27/04 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/02 , B01J35/10 , B01J37/03 , C01B17/20 , C01B19/00 , C01G39/00 , C01G41/00 , C01G49/00 , C01G51/00 , C01G53/00 , C10G47/02 , B82Y30/00
CPC分类号： C01G39/06 , B01J27/04 , B01J27/047 , B01J27/049 , B01J27/051 , B01J27/0515 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/031 , B82Y30/00 , C01B17/20 , C01B19/002 , C01B19/007 , C01G39/006 , C01G41/006 , C01G49/009 , C01G51/006 , C01G53/006 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/40 , C10G47/02
摘要： A method for producing a thiometallate or selenometallate material is provided in which a first salt containing an anionic component selected from the group consisting of MoS42−, MoSe42−, WS42−, WSe42−, VS43−, and VSe43− and a second salt containing a cationic component comprising a metal in any non-zero oxidation state selected from the group consisting of Cu, Fe, Ag, Co, Mn, Re, Ru, Rh, Pd, Ir, Pt, B, Al, Ce, La, Pr, Sm, Eu, Yb, Lu, Dy, Ni, Zn, Bi, Sn are mixed under anaerobic conditions in an aqueous mixture at a temperature of from 50° C. to 150° C.
摘要翻译： 提供一种生产硫属金属或硒金属酸盐材料的方法，其中含有选自MoS42-，MoSe42-，WS42-，WSe42-，VS43-和VSe43-的阴离子组分的第一盐和含有 阳离子组分，其包含选自Cu，Fe，Ag，Co，Mn，Re，Ru，Rh，Pd，Ir，Pt，B，Al，Ce，La，Pr中的任何非零氧化态的金属， 将Sm，Eu，Yb，Lu，Dy，Ni，Zn，Bi，Sn在厌氧条件下在50〜150℃的温度下在含水混合物中混合。
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公开(公告)号：US08940268B2
公开(公告)日：2015-01-27
申请号：US13010883
申请日：2011-01-21
IPC分类号： C01B17/00 , C01B25/14 , C01D5/08 , C01G39/00 , B01J27/04 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/10 , B01J37/03 , C01B17/20 , C01B19/00 , C01G39/06 , C01G41/00 , C01G49/00 , C01G51/00 , C01G53/00 , C01G55/00 , C10G47/02 , B82Y30/00
CPC分类号： C01G39/006 , B01J27/04 , B01J27/047 , B01J27/049 , B01J27/051 , B01J27/0515 , B01J35/1009 , B01J35/1038 , B01J35/1061 , B01J37/031 , B82Y30/00 , C01B17/20 , C01B19/002 , C01B19/007 , C01G39/06 , C01G41/006 , C01G49/009 , C01G51/006 , C01G53/006 , C01G55/002 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/40 , C10G47/02
摘要： A method for producing a thiometallate or selenometallate material is provided in which a first salt containing an anionic component selected from the group consisting of MoS42−, MoSe42−, WS42−, WSe42−, VS43−, and VSe43−, and a second salt containing a cationic component comprising a metal in any non-zero oxidation state selected from the group consisting of Fe, Ag, Co, Mn, Re, Ru, Rh, Pd, Ir, Pt, B, Al, Ce, La, Pr, Sm, Eu, Yb, Lu, Dy, Ni, Zn, Bi, Sn, Pb, Cd, Sb, Ge, Ga, In, Au, Hg are mixed under anaerobic conditions in an aqueous mixture at a temperature of from 15° C. to 150° C.
摘要翻译： 提供了一种生产硫代金属或硒金属酸盐材料的方法，其中含有选自MoS42-，MoSe42-，WS42-，WSe42-，VS43-和VSe43-的阴离子组分的第一盐和含 包含选自Fe，Ag，Co，Mn，Re，Ru，Rh，Pd，Ir，Pt，B，Al，Ce，La，Pr，Sm中的任何非零氧化态的金属的阳离子组分 ，Eu，Yb，Lu，Dy，Ni，Zn，Bi，Sn，Pb，Cd，Sb，Ge，Ga，In，Au，Hg在厌氧条件下在15℃的温度下在含水混合物中混合。 至150℃
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15.发明申请公开(公告)号：US20150018588A1
公开(公告)日：2015-01-15
申请号：US14375733
申请日：2012-11-01
申请人： Neste Oil Oyj
发明人： Jukka Myllyoja , Pekka Aalto , Rami Piilola
IPC分类号： C07C1/24 , B01J23/883 , C10M105/24 , C10L1/04 , C07C45/54
CPC分类号： B01J27/0515 , B01D3/009 , B01J21/063 , B01J23/04 , B01J23/883 , B01J23/8872 , B01J35/0006 , B01J37/20 , C07C1/22 , C07C1/24 , C07C5/2735 , C07C5/2737 , C07C45/41 , C07C45/54 , C07C2523/16 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C10G3/42 , C10G3/44 , C10G3/45 , C10G3/46 , C10L1/04 , C10L2200/0484 , C10M105/04 , C10M105/24 , C10M177/00 , C11C1/005 , C11C3/123 , Y02P30/20
摘要： The present invention provides a method for increasing hydrocarbon chain length. The method comprises providing a feedstock comprising fatty acids and/or fatty acid esters with hydrocarbon chain length below C23 into a reaction zone in which ketonisation is conducted in the presence of a hydrotreatment catalyst under hydrogen pressure. The obtained ketones have a hydrocarbon chain length of from C24 to C43. The present invention further provides a method for simultaneous production of base oil components and fuel components.
摘要翻译： 本发明提供了增加烃链长度的方法。 该方法包括提供包含低于C 23的烃链长度的脂肪酸和/或脂肪酸酯的原料进入在氢气压力下在加氢处理催化剂存在下进行酮化的反应区。 所得酮的烃链长度为C24至C43。 本发明还提供了一种用于同时生产基础油组分和燃料组分的方法。
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公开(公告)号：US20140339135A1
公开(公告)日：2014-11-20
申请号：US14453871
申请日：2014-08-07
申请人： SHELL OIL COMPANY
发明人： William Douglas GILLESPIE , Alexei Grigorievich GABRIELOV , Peter WOLOHAN , John Anthony SMEGAL
CPC分类号： B01J31/26 , B01J21/04 , B01J23/8885 , B01J27/0515 , B01J31/0234 , B01J31/22 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/0009 , B01J37/0201 , B01J37/0203 , B01J37/18 , B01J37/20 , B01J2231/005 , B01J2531/845 , C10G45/12 , C10G49/04
摘要： A composition and method of making such a composition that has application in the hydroprocessing of hydrocarbon feedstocks. The method comprises selecting an organic additive by the use of a correlation model for predicting catalytic activity as a function of a physical property that is associated with the organic additive and incorporating the organic additive into a support material to provide the additive impregnated composition.
摘要翻译： 制备这种组合物的组合物和方法，其可用于烃原料的加氢处理。 该方法包括通过使用用于预测催化活性的相关模型来选择有机添加剂，作为与有机添加剂相关的物理性能的函数，并将有机添加剂并入载体材料中以提供添加剂浸渍的组合物。
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公开(公告)号：US08809222B2
公开(公告)日：2014-08-19
申请号：US13331372
申请日：2011-12-20
申请人： Oleg Mironov , Alexander E. Kuperman , Julie Chabot , Shuwu Yang , Joseph V. Nguyen , Ling Jiao , Bruce Edward Reynolds , Axel Brait , Kenneth Kwik , Modinat Kotun
发明人： Oleg Mironov , Alexander E. Kuperman , Julie Chabot , Shuwu Yang , Joseph V. Nguyen , Ling Jiao , Bruce Edward Reynolds , Axel Brait , Kenneth Kwik , Modinat Kotun
IPC分类号： B01J27/02 , B01J27/047 , B01J27/049 , B01J27/043 , B01J27/045 , B01J23/00 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/58 , B01J23/70 , B01J23/74 , B01J23/85 , B01J23/883 , B01J23/887 , B01J27/051 , B01J23/24 , B01J35/00 , B01J37/20 , C10G49/04 , B01J35/10
CPC分类号： B01J23/883 , B01J23/24 , B01J23/85 , B01J23/8872 , B01J23/8873 , B01J27/051 , B01J27/0515 , B01J35/0073 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1095 , B01J37/20 , C10G49/04 , C10G49/06 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/301 , C10G2300/701 , C10G2300/703 , C10G2300/802
摘要： An improved process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. In the process, high shear mixing is employed to generate an emulsion containing droplets of metal precursor in oil with droplet sizes ranging from 0.1 to 300 μm. The emulsion is subsequently sulfided with a sulfiding agent, or in-situ in a heavy oil feedstock to form a slurry catalyst. The in-situ sulfidation in heavy oil is under sufficient condition for the heavy oil feedstock to generate the sulfiding source needed for the sulfidation.
摘要翻译： 提供了一种用于制备用于重油原料升级的浆料催化剂的改进方法。 在此过程中，使用高剪切混合产生含有液滴尺寸范围为0.1至300μm的油中金属前体的液滴的乳液。 然后将乳液用硫化剂硫化，或在重油原料中原位形成浆料催化剂。 重油中的原位硫化在足够的条件下使重油原料产生硫化所需的硫化源。
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公开(公告)号：US08722556B2
公开(公告)日：2014-05-13
申请号：US12004014
申请日：2007-12-20
申请人： Andre R. DaCosta , Paul Bryan
发明人： Andre R. DaCosta , Paul Bryan
IPC分类号： B01J38/48 , B01D61/14 , C10G31/09 , C10G31/11 , B01J27/051
CPC分类号： B01J38/48 , B01D61/142 , B01D61/147 , B01D65/08 , B01D2311/06 , B01D2315/10 , B01D2315/16 , B01D2321/2058 , B01J27/051 , B01J27/0515 , B01J38/72 , C10G31/09 , C10G31/11 , B01D2311/2669
摘要： A method of recovering unsupported fine catalyst from heavy oil comprises combining a slurry comprising unsupported fine catalyst in heavy oil with solvent to form a combined slurry-solvent stream. The combined slurry-solvent stream is filtered in a deoiling zone. A stream comprising unsupported fine catalyst and solvent is recovered from the deoiling zone. Unsupported fine catalyst is separated from the stream comprising unsupported fine catalyst and solvent. The deoiling zone can comprise a membrane that is rapidly displaced in a horizontal direction.
摘要翻译： 从重油中回收未负载的细催化剂的方法包括将包含重油中的无载体细催化剂的浆料与溶剂组合以形成组合的浆料 - 溶剂流。 将合并的浆料 - 溶剂流在脱油区中过滤。 从脱油区回收包含未负载的细催化剂和溶剂的料流。 将不负载的细催化剂与包含无载体的细催化剂和溶剂的流分离。 脱油区可以包括在水平方向上快速位移的膜。
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公开(公告)号：US20140066297A1
公开(公告)日：2014-03-06
申请号：US14019421
申请日：2013-09-05
IPC分类号： B01J27/051 , B01J27/049
CPC分类号： B01J27/0515 , B01J27/043 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/002 , B01J35/1014 , B01J35/1038 , C10G45/08
摘要： The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst is characterized as having a multi-phased structure comprising five phases: a molybdenum sulfide phase, a tungsten sulfide phase, a molybdenum tungsten sulfide phase, an active nickel phase, and a nickel sulfide phase.
摘要翻译： 本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。 MMS催化剂的特征在于具有包含五相的多相结构：硫化钼相，硫化钨相，硫化钨相，活性镍相和硫化镍相。
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公开(公告)号：US08530370B2
公开(公告)日：2013-09-10
申请号：US13010894
申请日：2011-01-21
IPC分类号： B01J31/00 , B01J27/057 , B01J27/02 , B01J27/047 , B01J27/049 , B01J27/051 , B01J27/043 , B01J27/045
CPC分类号： C01G39/006 , B01J23/8878 , B01J27/049 , B01J27/0515 , B01J35/0013 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/009 , B01J37/0236 , B01J37/038 , B01J37/088 , B82Y30/00 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/80 , C10G47/02
摘要： The present invention is directed to a composition comprising a solid material comprised of a first metal/metalloid comprised of a metal or metalloid selected from the group consisting of Cu, Fe, Ag, Co, Mn, Zr, Zn, Sn, Re, Rh, Ru, Pd, Ir, Pt, B, Al, Ce, La, Pb, Cd, Sb, Ge, Ga, In, Bi, and Au; and a second metal selected from molybdenum, tungsten, or vanadium, where the first metal/metalloid and the second metal form a bimetallic tetrathiometallate or a bimetallic tetraselenometallate with sulfur or with selenium. The solid material is comprised of particles and has a particle size distribution, where the mean particle size of the particle size distribution is from about 50 nm to about 5 μm.
摘要翻译： 本发明涉及包含固体材料的组合物，该固体材料由选自Cu，Fe，Ag，Co，Mn，Zr，Zn，Sn，Re，Rh中的金属或准金属构成的第一金属/准金属构成 ，Ru，Pd，Ir，Pt，B，Al，Ce，La，Pb，Cd，Sb，Ge，Ga，In，Bi和Au; 和选自钼，钨或钒的第二种金属，其中第一金属/准金属和第二金属与硫或硒形成双金属四金属酸金属或双金属四硒金属盐酸盐。 固体材料由颗粒组成并且具有粒度分布，其中粒度分布的平均粒度为约50nm至约5μm。
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