利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

70 条记录 (耗时 0.017 秒)

    Process for the oligomerization of alpha-olefins having low unsaturation
    12.
    发明申请
    Process for the oligomerization of alpha-olefins having low unsaturation 有权
    具有低不饱和度的α-烯烃的低聚方法

    公开(公告)号：US20040147693A1

    公开(公告)日：2004-07-29

    申请号：US10761515

    申请日：2004-01-20

    申请人： CROMPTON CORPORATION, a corporation of the State of Delaware

    发明人： Anthony-Joseph DiMaio

    IPC分类号： C08F004/44

    CPC分类号： C10M145/08 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/14 ,  C10M107/02 ,  C10M107/10 ,  C10M145/02 ,  C10M2205/02 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/024 ,  C10N2230/02 ,  C10N2270/02 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/03 ,  C08F2500/17

    摘要： A process is disclosed for the preparation of a poly(null-olefin) polymer wherein the process comprises polymerizing at least one null-olefin in the presence of hydrogen and a catalytically effective amount of catalyst comprising the product obtained by combining a metallocene catalyst with a cocatalyst, the metallocene catalyst being at least one meso compound of general formula: 1 wherein: A1 and A2 are independently selected from the group consisting of mononuclear and polynuclear hydrocarbons; M1 is a metal from group IVb, Vb, or VIb of the Periodic Table; R1 and R2 are independently selected from the group consisting of hydrogen, C1-C10 alkyl, C1-C10-alkoxy, C6-C10 aryl, C6-C10 aryloxy, C2-C10 alkenyl, C7-C40 arylalkyl, C7-C40 alkylaryl, C8-C40 arylalkenyl and halogen; R7 is selected from the group consisting of: 2 nullBR11, nullAlR11, nullGenull, nullSnnull, nullOnull, nullSnull, nullSO, nullSO2, nullNR11, nullCO, nullPR11 and nullP(O)R11, where R11, R12, and R13 are independently selected from the group consisting of hydrogen, halogen, C1-C10 alkyl, C1-C10 fluoroalkyl, C6-C10 aryl, C6-C10 fluoroaryl, C1-C10 alkoxy, C2-C10 alkenyl, C7-C40 arylalkyl, C8-C40 arylalkenyl, and C7-C40 alkylaryl, or R11 and R12 or R11 and R13, in each case with the atoms connecting them, form a ring; and M2 is selected from the group consisting of silicon, germanium, and tin; R8 and R9 are independently selected from the group consisting of hydrogen, halogen, C1-C10 alkyl, C1-C10 fluoroalkyl, C6-C10 aryl, C6-C10 fluoroaryl, C1-C10 alkoxy, C2-C10 alkenyl, C7-C40 arylalkyl, C8-C40 arylalkenyl, and C7-C40 alkylaryl; m and n are identical or different and are zero, 1, or 2, with m plus n being zero, 1 or 2.

    摘要翻译： 公开了一种用于制备聚（α-烯烃）聚合物的方法，其中该方法包括在氢存在下使至少一种α-烯烃和催化有效量的催化剂聚合，所述催化剂包含通过将茂金属催化剂与 助催化剂，茂金属催化剂是至少一种通式化合物：其中：A 1和A 2独立地选自单核和多核烃; M 1是元素周期表IVb，Vb或VIb族的金属; R 1和R 2独立地选自氢，C 1 -C 10烷基，C 1 -C 10 - 烷氧基，C 6 -C 10芳基，C 6 -C 10芳氧基，C 2 -C 10烯基，C 7 -C 40芳基烷基， C7-C40烷基芳基，C8-C40芳基烯基和卤素; R 7选自：= BR 11，= AlR 11，-Ge-，-Sn-，-O - ， - S - ，= SO，= SO 2，= NR 11 ，= CO，= PR 11和= P（O）R 11，其中R 11，R 12和R 13独立地选自氢，卤素，C 1 -C 10烷基，C 1 -C 10氟代烷基，C 6 -C 10芳基，C 6 -C 10氟芳基，C 1 -C 10烷氧基，C 2 -C 10烯基，C 7 -C 40芳基烷基，C 8 -C 40芳基烯基和C 7 -C 40烷基芳基， 并且R 12或R 11和R 13各自与连接它们的原子形成环; 并且M 2选自硅，锗和锡; R 8和R 9