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公开(公告)号：US09597670B2
公开(公告)日：2017-03-21
申请号：US13002381
申请日：2009-06-24
Applicant: Carolus Maria Ballegoy , Dinyar Khushroo Captain , Joseph Cornelis Van Giezen , Lucas Petrus Simon Keyzer , Nicoleta Cristina Nenu , Ingrid Maria Van Vegchel
Inventor： Carolus Maria Ballegoy , Dinyar Khushroo Captain , Joseph Cornelis Van Giezen , Lucas Petrus Simon Keyzer , Nicoleta Cristina Nenu , Ingrid Maria Van Vegchel
CPC classification number: B01J29/7469 , B01J29/7269 , B01J29/7669 , B01J35/0026 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J2229/16 , B01J2229/20 , B01J2229/42 , C07C5/2754 , C07C5/2791 , C07C2529/70 , C07C2529/72 , C07C2529/74 , C07C2529/76 , Y02P20/52 , C07C15/08
Abstract: An alkylaromatics isomerisation catalyst, which catalyst comprises at least 50 wt % of an inorganic binder; at least 0.01 wt % of a Group VIII metal and 1-9 wt % ZSM-12 zeolite wherein the silica to alumina molar ratio (SAR) of the ZSM-12 zeolite is in the range of from 60 to 200, and a process for the isomerisation of alkylaromatics to provide a reaction mixture, said process comprising contacting a hydrocarbon stream comprising alkylaromatics with such catalyst.
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22.发明申请公开(公告)号：US20160354724A1
公开(公告)日：2016-12-08
申请号：US15203913
申请日：2016-07-07
Applicant: Haldor Topsøe A/S
Inventor： Manuel Moliner Marin , Cristina Franch Marti , Antonio Eduardo Palomares Gimeno , Avelino Corma Canós , Peter N.R. Vennestrøm , Marie Grill , Arkady Kustov , Joakim Reimer Thøgersen
CPC classification number: B01D53/9418 , B01D53/9431 , B01D2251/206 , B01D2255/20761 , B01D2255/50 , B01D2255/915 , B01D2257/404 , B01D2258/012 , B01J23/72 , B01J29/76 , B01J29/85 , B01J35/1019 , B01J35/1038 , B01J37/0246 , B01J2229/20 , F01N3/023 , F01N3/035 , F01N3/2066 , F01N13/001 , F01N13/008 , F01N2330/06 , F01N2370/04 , F01N2610/02 , Y02T10/24
Abstract: An exhaust gas cleaning system, comprising an active regenerable particulate filter and an SCR catalyst comprising a hydrothermally microporous stable zeolite having the AEI type framework and being promoted with copper, where the zeolite is SSZ-39.
Abstract translation: 一种废气净化系统，包括活性可再生微粒过滤器和SCR催化剂，其包含具有AEI型骨架的水热微孔稳定沸石，并用铜促进，其中沸石是SSZ-39。
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公开(公告)号：US09464011B2
公开(公告)日：2016-10-11
申请号：US14770657
申请日：2014-03-06
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Gabor Kiss , Thomas E. Green , Terry E. Helton , William C. Horn , William A. Lamberti , Tan-Jen Chen
IPC: C07C45/53 , C07C37/08 , C07C2/66 , B01J37/00 , B01J35/00 , C07C2/74 , C07C407/00 , B01J29/74 , B01J35/02 , C07C409/14 , B01J37/02 , B01J35/10
CPC classification number: C07C2/74 , B01J29/7476 , B01J35/0006 , B01J35/0073 , B01J35/008 , B01J35/026 , B01J35/1019 , B01J37/0009 , B01J37/02 , B01J37/0201 , B01J37/0223 , B01J2229/20 , B01J2229/42 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
Abstract: A process for producing an alkylated aromatic compound comprises contacting an aromatic starting material and hydrogen with a plurality of catalyst particles under hydroalkylation conditions to produce an effluent comprising the alkylated aromatic compound, the catalyst comprising a composite of a solid acid, an inorganic oxide different from the solid acid and a hydrogenation metal, wherein the distribution of the hydrogenation metal in at least 60 wt % of the catalyst particles is such that the average concentration of the hydrogenation metal in the rim portion of a given catalyst particle is Crim, the average concentration of the hydrogenation metal in the outer portion of a given catalyst particle is Couter, the average concentration of the hydrogenation metal in the center portion of the given catalyst particle is Ccenter, where Crim/Ccenter≧2.0 and/or Couter/Ccenter2.0. Also disclosed are rimmed catalyst and process for making phenol and/or cyclohexanone using the catalyst.
Abstract translation: 一种制备烷基化芳族化合物的方法包括在加氢烷基化条件下使芳族起始原料和氢气与多个催化剂颗粒接触以产生包含烷基化芳族化合物的流出物，所述催化剂包含固体酸，不同于 固体酸和氢化金属，其中氢化金属在至少60重量％催化剂颗粒中的分布使得给定催化剂颗粒的边缘部分中的氢化金属的平均浓度为Crim，平均浓度 在给定催化剂颗粒的外部部分的氢化金属是Couter，给定催化剂颗粒的中心部分的氢化金属的平均浓度是Ccenter，其中Crim /Ccenter≥2.0和/或Couter / Ccenter2.0。 还公开了边缘催化剂和使用催化剂制备苯酚和/或环己酮的方法。
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公开(公告)号：US09441167B2
公开(公告)日：2016-09-13
申请号：US14134629
申请日：2013-12-19
Applicant: BASF Corporation
Inventor： Robert McGuire, Jr. , Gary M. Smith , Bilge Yilmaz
CPC classification number: C10G11/04 , B01J21/02 , B01J29/088 , B01J35/0006 , B01J37/0045 , B01J37/04 , B01J2229/186 , B01J2229/20 , B01J2229/42 , B01J2229/64 , C10G11/02 , C10G11/18
Abstract: Fluid catalytic cracking (FCC) processes are described, the processes utilizing one or more boron oxide components. Also described are FCC compositions and methods of manufacture. One or more boron oxide components on FCC compatible inorganic particles are added to a FCC unit to crack hydrocarbon feeds, resulting in lower hydrogen and coke yields.
Abstract translation: 流程催化裂化（FCC）方法描述了利用一种或多种氧化硼组分的方法。 还描述了FCC组合物和制造方法。 将FCC兼容的无机颗粒上的一种或多种氧化硼组分加入到FCC单元中以裂解烃进料，导致较低的氢气和焦炭产率。
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公开(公告)号：US20160256858A1
公开(公告)日：2016-09-08
申请号：US15015335
申请日：2016-02-04
Applicant: SHELL OIL COMPANY
Inventor： László DOMOKOS , Ralph HASWELL , Hong-Xin LI
CPC classification number: B01J29/46 , B01J29/40 , B01J29/405 , B01J29/44 , B01J37/0009 , B01J2229/16 , B01J2229/20 , B01J2229/42 , C01B39/12 , C01B39/38 , C01B39/40 , C07C4/18 , C07C2529/40 , C07C2529/42 , C07C2529/44 , C07C2529/46 , C07C2529/48 , Y02P20/52 , C07C15/08
Abstract: A new configuration of ZSM-5 is provided whereby the crystals have a higher average silica to alumina ratio at the edges of each crystallite than in the centre as determined from a narrow slit line scan profile obtained from SEM/EDX or TEM/EDX elemental analysis. Such ZSM-5 crystals are obtained by a preparation process using L-tartaric acid. The new configuration ZSM-5 provides significantly reduced xylene losses in ethylbenzene dealkylation, especially when combined with silica as binder, and one or more hydrogenation metals selected from platinum, tin, lead, silver, copper, and nickel.
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Patent Agency Ranking
26.发明申请Modified Y Molecular Sieve and Preparation Method and Use Thereof, Supported Catalyst, and Hydrocracking Method 审中-公开改性Y分子筛及其制备方法及用途，载体催化剂和加氢裂化法公开(公告)号：US20160229700A1
公开(公告)日：2016-08-11
申请号：US14930707
申请日：2015-11-03
Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION , Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.
Inventor： Wei LIU , MingHua GUAN , Yanze DU , Fenglai WANG , Chang LIU , Bo QIN
CPC classification number: C01B39/24 , B01J23/888 , B01J29/084 , B01J29/126 , B01J29/166 , B01J35/0006 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1071 , B01J37/0207 , B01J2029/081 , B01J2229/16 , B01J2229/186 , B01J2229/20 , C01B39/06 , C10G47/16 , C10G47/20
Abstract: The present invention discloses a modified Y molecular sieve, a preparation method and a use of the modified Y molecular sieve, a supported catalyst, and a hydrocracking method. The silica-alumina mole ratio in the surface layer of the modified Y molecular sieve is 20-100:1, and the silica-alumina mole ratio in the body phase of the modified Y molecular sieve is 8-30:1. When a hydrocracking catalyst prepared from the modified Y molecular sieve is used for hydrocracking, the hydrocracking catalyst has higher reactivity and higher nitrogen tolerance. The hydrocracking catalyst prepared from the modified Y molecular sieve is suitable for use for increasing the yield of diesel oil, increasing the yield of chemical materials, and catalyzed hydrogenation conversion of diesel oil, etc.
Abstract translation: 本发明公开了改性Y分子筛，改性Y分子筛，负载催化剂和加氢裂化方法的制备方法和用途。 改性Y分子筛表面层的二氧化硅 - 氧化铝摩尔比为20-100:1，改性Y分子筛的体相的二氧化硅 - 氧化铝摩尔比为8〜30:1。 当由改性Y分子筛制备的加氢裂化催化剂用于加氢裂化时，加氢裂化催化剂具有较高的反应活性和较高的氮耐受性。 由改性Y分子筛制备的加氢裂化催化剂适用于提高柴油的产率，提高化学成分的产率，催化氢化转化柴油等。
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公开(公告)号：US20160214094A1
公开(公告)日：2016-07-28
申请号：US14602394
申请日：2015-01-22
Applicant: Jifei Jia , Andrew Rainis , Theodorus Ludovicus Michael Maesen , Richard Coser , Yihua Zhang
Inventor： Jifei Jia , Andrew Rainis , Theodorus Ludovicus Michael Maesen , Richard Coser , Yihua Zhang
CPC classification number: B01J37/0201 , B01J21/04 , B01J21/12 , B01J29/126 , B01J35/0006 , B01J35/002 , B01J35/0026 , B01J35/1004 , B01J35/1023 , B01J37/0009 , B01J37/0207 , B01J37/30 , B01J2229/18 , B01J2229/186 , B01J2229/20 , B01J2229/40 , B01J2229/42 , C10G47/16 , C10G47/18
Abstract: A second-stage hydrocracking catalyst is provided comprising: a. from 40 wt % to 70 wt % of a zeolite USY having an ASDI from 0.05 to 0.18; b. an amorphous silica alumina; c. a second alumina; and d. 0.1 to 10 wt % noble metal; wherein the second-stage hydrocracking catalyst has a BET surface area from 450 to 650 m2/g. A second-stage hydrocracking process is provided comprising using the second-stage hydrocracking catalyst to produce middle distillate. A method for making the second-stage hydrocracking catalyst is also provided.
Abstract translation: 提供了第二级加氢裂化催化剂，其包括：a。 40重量％至70重量％的具有0.05至0.18的ASDI的沸石USY; b。 无定形二氧化硅氧化铝; C。 第二氧化铝; 和d。 贵金属0.1〜10重量％ 其中第二级加氢裂化催化剂的BET表面积为450〜650m2 / g。 提供第二阶段加氢裂化方法，包括使用第二级加氢裂化催化剂生产中间馏分。 还提供了制备第二级加氢裂化催化剂的方法。
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公开(公告)号：US09387467B2
公开(公告)日：2016-07-12
申请号：US13626904
申请日：2012-09-26
Applicant: Chevron Phillips Chemical Company LP
Inventor： Gyanesh P. Khare
IPC: B01J29/06 , B01J29/62 , B01J29/068 , C10G35/095 , B01J29/072 , B01J29/63 , B01J37/24 , B01J37/30 , B01J35/10 , B01J38/12 , B01J29/90 , B01J37/00
CPC classification number: B01J29/62 , B01J29/061 , B01J29/068 , B01J29/072 , B01J29/63 , B01J29/90 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/108 , B01J37/0018 , B01J37/0207 , B01J37/08 , B01J37/24 , B01J37/30 , B01J38/10 , B01J38/12 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C10G35/095
Abstract: Regenerable aromatization catalysts having high surface area and pore volume, as well as methods for producing these catalysts, are disclosed.
Abstract translation: 公开了具有高表面积和孔体积的可再生芳构化催化剂以及制备这些催化剂的方法。
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公开(公告)号：US09365779B2
公开(公告)日：2016-06-14
申请号：US11667149
申请日：2005-11-03
Applicant: Wu Cheng Cheng , Meenakshi Sundaram Krishnamoorthy , Ranjit Kumar , Xinjin Zhao , Michael Scott Ziebarth
Inventor： Wu Cheng Cheng , Meenakshi Sundaram Krishnamoorthy , Ranjit Kumar , Xinjin Zhao , Michael Scott Ziebarth
IPC: B01J29/00 , B01J29/08 , B01J29/89 , C10G11/18 , B01J29/80 , B01J35/00 , C10G11/05 , B01J29/40 , B01J37/00
CPC classification number: C10G11/182 , B01J29/084 , B01J29/088 , B01J29/40 , B01J29/80 , B01J35/0006 , B01J37/0045 , B01J2229/20 , B01J2229/42 , C10G11/05 , C10G11/18 , C10G2300/202 , C10G2300/301 , C10G2300/4025 , C10G2300/4093 , C10G2400/02 , C10G2400/20 , C10G2400/28
Abstract: A catalyst composition comprising at least about 10% by weight pentasil, at least about 12% by weight Y-type zeolite at a pentasil to Y zeolite ratio of at least 0.25, and wherein the pentasil and Y zeolite comprise at least about thirty-five percent of the catalyst have been shown to optimize light olefin yields and LPG from FCC processes. Embodiments having matrix surface areas greater than 25 m2/g, phosphorous and rare earth are preferred. The compositions of this invention are particularly useful in typical fluid catalytic cracking (FCC) processes.
Abstract translation: 催化剂组合物，其包含至少约10重量％的pentasil，至少约12重量％的Y型沸石，在pentasil至Y沸石比为至少0.25，并且其中pentasil和Y沸石包含至少约35 已经显示催化剂的百分比优化了来自FCC方法的轻烯烃产率和LPG。 具有大于25m 2 / g的矩阵表面积的实施例是磷和稀土是优选的。 本发明的组合物在典型的流化催化裂化（FCC）方法中特别有用。
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公开(公告)号：US09364819B2
公开(公告)日：2016-06-14
申请号：US14771140
申请日：2014-03-06
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Gabor Kiss , Thomas E. Green , Terry E. Helton , William C. Horn , William A. Lamberti , Tan-Jen Chen
IPC: C07C2/66 , B01J29/74 , B01J23/44 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , B01J29/03 , B01J35/02 , B01J35/10 , B01J29/70 , B01J35/00 , B01J29/76
CPC classification number: B01J29/7476 , B01J23/44 , B01J29/0325 , B01J29/0333 , B01J29/7038 , B01J29/7676 , B01J35/0006 , B01J35/0073 , B01J35/023 , B01J35/026 , B01J35/1019 , B01J2229/20 , B01J2229/42 , C07C2/66 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/44 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C409/14 , C07C13/28 , C07C49/403 , C07C39/04
Abstract: A process for producing an alkylated aromatic compound comprises contacting an aromatic starting material and hydrogen with a plurality of catalyst particles under hydroalkylation conditions to produce an effluent comprising the alkylated aromatic compound, the catalyst comprising a composite of a solid acid, an inorganic oxide different from the solid acid and a hydrogenation metal, wherein the distribution of the hydrogenation metal in at least 60 wt % of the catalyst particles is such that the average concentration of the hydrogenation metal in the rim portion of a given catalyst particle is Crim, the average concentration of the hydrogenation metal in the center portion of the given catalyst particle is Ccenter, where 0.2≦Crim/Ccenter
Abstract translation: 一种制备烷基化芳族化合物的方法包括在加氢烷基化条件下使芳族起始原料和氢气与多个催化剂颗粒接触以产生包含烷基化芳族化合物的流出物，所述催化剂包含固体酸，不同于 固体酸和氢化金属，其中氢化金属在至少60重量％催化剂颗粒中的分布使得给定催化剂颗粒的边缘部分中的氢化金属的平均浓度为Crim，平均浓度 在给定的催化剂颗粒的中心部分的氢化金属是Ccenter，其中0.2＆lt; lI; Crim / Ccenter <2.0。 还公开了加氢烷基化催化剂和使用该催化剂制备苯酚和/或环己酮的方法。
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