Abstract:
A reactor includes an essentially horizontal cylinder for carrying out an autothermal gas-phase dehydrogenation of a hydrocarbon-comprising gas stream using an oxygen-comprising gas stream to give a reaction gas mixture over a heterogeneous catalyst configured as monolith. The interior of the reactor is divided by a detachable, cylindrical or prismatic housing, which is arranged in the longitudinal direction of the reactor and is gastight in the circumferential direction, into an inner region having one or more catalytically active zones, each having a packing composed of monoliths stacked on top of one another, next to one another and behind one another and before each catalytically active zone in each case a mixing zone having solid internals are provided and into an outer region, which is supplied with an inert gas, arranged coaxially to the inner region. A heat exchanger is connected to the housing at one end of the reactor.
Abstract:
A hydrodesulfurization device includes a hydro-desulfurizer configured to remove a sulfur component from a raw material; and a heater configured to heat the hydro-desulfurizer; wherein the hydro-desulfurizer includes a plurality of blocks formed by division in a circumferential direction and disposed annularly around an outer periphery of the heater; wherein the hydro-desulfurizer is configured such that the raw material having passed through inside of each of the blocks moves to its adjacent block; and wherein the hydro-desulfurizer is configured such that adjacent blocks are communicated with each other and the raw material flows in the adjacent blocks in opposite directions.
Abstract:
Provided is a plant for the continuous production of monosilane and tetrachlorosilane by catalytic dismutation of trichlorosilane, wherein the plant contains: a countercurrent reactor having a double wall, a catalyst bed containing a catalyst which is located in the countercurrent reactor, a condenser at the top of the countercurrent reactor, a vaporizer unit at the bottom of the countercurrent reactor, a trichlorosilane feed line for the introduction of trichlorosilane into the countercurrent reactor, a heat exchanger, with the trichlorosilane conveyed by line via the heat exchanger and preheated there by a bottom product from the vaporizer unit and, for this purpose, the bottom product is fed by line via the heat exchanger into the double wall at a level in the lower part of the countercurrent reactor and discharged from the double wall at a level in the upper part of the countercurrent reactor, a condensation unit downstream of the condenser, and a distillation column having an outlet for monosilane.
Abstract:
A reactor with minimal dead volume especially suited to reverse-flow applications comprises: a) a reactor body; b) a first head engaged with said reactor body; c) a first conduit extending from outside said head to at least partially through said head; and d) a first valve in flow communication with said first conduit controlling fluid flow along a flow path extending from the first valve and through the reactor body. The reactor is especially suited for use in a process for rapid stream-switching of at least two streams in a reverse-flow reactor.
Abstract:
Fuel cell systems and methods are described. A method for generating electrical energy in a fuel cell receives hydrogen from a fuel processor configured to process a fuel source to produce the hydrogen, includes transporting a heating medium from the fuel processor to the fuel cell when electrical energy output by the fuel cell includes less than an electrical threshold or when temperature of a component in the fuel cell is less than a temperature threshold, heating a portion of the fuel cell, transporting hydrogen from the fuel processor to the fuel cell, detecting temperature of the component or electrical output of the fuel cell, and generating electrical energy in the fuel cell when the temperature of the component is about equal to or greater than the threshold temperature or when electrical energy output by the fuel cell is about equal to or greater than an electrical threshold.
Abstract:
The present invention relates to a plant and a process for the continuous production of monosilane and tetrachlorosilane by catalytic dismutation of trichlorosilane at an operating temperature and a pressure of from 1 to 50 bar abs. in a plant according to claim 1, in which—trichlorosilane (A) is preheated in a heat exchanger (7), and fed to the 10 countercurrent reactor (1) which is provided with catalyst (3),—product mixture formed in the countercurrent reactor (1) is at least partly condensed by means of the condenser (5) at a temperature in the range from −25 to 50° C. with the condensate flowing back into the countercurrent reactor (1),—the product phase which is not condensed in the condenser (5) is passed to the 15 condensation unit (8) which is operated at a temperature in the range from −40 to −110° C.,—the volatile product phase from the condensation unit (8) is fed to the distillation column (9) which is operated at a temperature in the range from −60 to −170° C. and monosilane (C) is discharged at the top of the distillation column (9), 20—the SiCl4-containing bottoms from the countercurrent reactor (1) are brought to a temperature in the range from 60 to 110° C. in the vaporizer unit (6) and—bottom product from the vaporizer (6) is conveyed via a heat exchanger (7) into the double wall (2) of the countercurrent reactor (1) and the SiCl4-containing product stream (B) is discharged at a level in the upper region of the reactor (1).
Abstract:
A gas mixture containing a fuel, water and air is supplied to one end of a reforming room, and a reformed gas containing hydrogen is discharged from the other end thereof. Two or more such reforming units are connected in series, and the upstream part of each reforming room is filled with a first catalyst which catalyzes a partial oxidation reaction in an oxygen-rich environment, and the downstream part is filled with a second catalyst which performs the reforming reaction. The gas mixture which has been heated in a heating unit passes through a distribution tube and is distributed evenly to the reforming units. The reforming room is composed of a reforming tube in which a reforming catalyst is charged, or two or more such reforming tubes, parallel to each other. After being reformed the high-temperature reformed gas is passed around the reforming tubes, and fed back to a manifold.
Abstract:
In one embodiment, a fuel processor for use in a fuel cell system, may have a bottom plate, having a regenerator having a first inlet to receive an air flow, a burner flow chamber within the regenerator, the burner flow chamber having a second inlet to receive the air flow from the regenerator, and a reformer flow chamber positioned between the regenerator and the burner flow chamber, the reformer flow chamber having a third inlet to receive the air flow from the burner chamber, wherein the burner flow chamber and the reformer flow chamber is formed of a monolithic structure having an elongated, rounded baffle in the center of the monolithic structure. The fuel processor may also have a top plate coupled to the bottom plate to enclose the fuel processor, the top plate having a top surface and a bottom surface.
Abstract:
A fluid processing apparatus having a plurality of processing spaces (S) includes a plurality of containers (B) juxtaposed in a direction to each other forming processing spaces (S) respectively therein. Pressing means (H) is provided for pressing the containers (B) as juxtaposed from opposed sides thereof in the juxtaposing direction of the containers. Each container (B) includes a pair of container-forming members (41a) disposed in the juxtaposing direction and having peripheral portions thereofjoined and welded to each other. At least one of the pair of container-forming members (41a) is in the form of a dish-like member having a peripheral portion used as a joining margin and a bulging central portion.
Abstract:
The system is a self-oxidation internal heating steam reforming system for conducting self-oxidation of a raw material gas under the presence of oxygen and conducting steam reforming to generate a hydrogen-rich reformed gas. The system includes a steam generator including a combustion section for combusting an air-fuel mixture obtained by mixing a combustion air with a fuel, thereby heating water using a combustion gas generated in the combustion section to generate hydrogen; a first sucking-mixer for sucking the raw material gas into a steam stream coming from the steam generator to obtain a raw material-steam mixture; and a reformer for oxidizing the raw material gas in the raw material-steam mixture by an oxygen-containing gas supplied from outside, thereby conducting steam reforming of the raw material gas using the reaction heat of the oxidation to generate a hydrogen-rich reformed gas.