PROCESS FOR PRODUCING MONOSILANE
    36.
    发明申请
    PROCESS FOR PRODUCING MONOSILANE 失效
    生产单体的方法

    公开(公告)号:US20090155156A1

    公开(公告)日:2009-06-18

    申请号:US12088286

    申请日:2006-06-19

    Abstract: The present invention relates to a plant and a process for the continuous production of monosilane and tetrachlorosilane by catalytic dismutation of trichlorosilane at an operating temperature and a pressure of from 1 to 50 bar abs. in a plant according to claim 1, in which—trichlorosilane (A) is preheated in a heat exchanger (7), and fed to the 10 countercurrent reactor (1) which is provided with catalyst (3),—product mixture formed in the countercurrent reactor (1) is at least partly condensed by means of the condenser (5) at a temperature in the range from −25 to 50° C. with the condensate flowing back into the countercurrent reactor (1),—the product phase which is not condensed in the condenser (5) is passed to the 15 condensation unit (8) which is operated at a temperature in the range from −40 to −110° C.,—the volatile product phase from the condensation unit (8) is fed to the distillation column (9) which is operated at a temperature in the range from −60 to −170° C. and monosilane (C) is discharged at the top of the distillation column (9), 20—the SiCl4-containing bottoms from the countercurrent reactor (1) are brought to a temperature in the range from 60 to 110° C. in the vaporizer unit (6) and—bottom product from the vaporizer (6) is conveyed via a heat exchanger (7) into the double wall (2) of the countercurrent reactor (1) and the SiCl4-containing product stream (B) is discharged at a level in the upper region of the reactor (1).

    Abstract translation: 本发明涉及一种在操作温度和1至50巴绝对压力下通过三氯硅烷的催化分解连续生产甲硅烷和四氯硅烷的设备和方法。 在根据权利要求1的设备中,其中在热交换器(7)中预热三氯硅烷(A),并送入设有催化剂(3)的10逆流反应器(1), - 形成在 逆流反应器(1)通过冷凝器(5)至少部分地在-25至50℃的温度范围内冷凝,冷凝物流回到逆流反应器(1)中,产物相位 在冷凝器(5)中未冷凝的冷凝单元(8)在-40至-110℃的温度范围内运行, - 来自冷凝单元(8)的挥发性产物相 进料到在-60至-70℃范围内操作的蒸馏塔(9)中,并且甲硅烷(C)在蒸馏塔(9)的顶部排出,20- SiCl 4 - 来自逆流反应器(1)的含底部物质在蒸发器单元(6)中的温度范围为60至110℃,-toto 来自蒸发器(6)的产物经由热交换器(7)输送到逆流反应器(1)的双壁(2)中,并且含SiCl4的产物流(B)在上部区域中被排出 的反应器(1)。

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