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    PROCESS FOR SYNTHESIZING HYDROCARBONS FROM SYNTHESIS GAS WITH CONTROL OF THE TEMPERATURE OF THE EXTERNAL LOOP
    41.
    发明申请
    PROCESS FOR SYNTHESIZING HYDROCARBONS FROM SYNTHESIS GAS WITH CONTROL OF THE TEMPERATURE OF THE EXTERNAL LOOP 有权
    合成气体合成气体的方法控制外部环境的温度

    公开(公告)号：US20150259608A1

    公开(公告)日：2015-09-17

    申请号：US14408621

    申请日：2013-04-10

    申请人： IFP ENERGIES NOUVELLES ,  ENI S.P.A.

    发明人： Jean Philippe Heraud ,  Jean-Christophe Viguie ,  Sebastien Boucher ,  Chiara Della Torre ,  Elsa Mignone

    IPC分类号： C10G2/00

    CPC分类号： C10G2/332 ,  B01D21/02 ,  B01J8/001 ,  B01J8/007 ,  B01J8/228 ,  B01J23/75 ,  B01J2208/00176 ,  B01J2208/003 ,  B01J2219/00202 ,  B01J2219/00207 ,  B01J2219/00213 ,  B01J2219/00238 ,  B01J2219/0024 ,  C10G2/342

    摘要： The present invention concerns a process for the synthesis of hydrocarbons from a feed comprising synthesis gas, in which a solid catalyst comprising cobalt is used in a three-phase reaction section operated such that said catalyst is maintained in suspension in a liquid phase by movement of a gas phase from the bottom to the top of said reaction section, said process comprising an external loop for separating waxes, characterized in that: 1) the theoretical ratio PH2O:PH2 in the external loop for separating waxes is determined using the following calculation: PH2O:PH2 theoretical=Cv/(R1−Rft×Cv) where Cv=(COinlet−COdegas)/COinlet R1=H2 inlet/COinlet Rft=(H2 inlet−H2 degas)/(COinlet−COdegas) 2) if the theoretical ratio PH2O:PH2 determined in step 1) has a value of Rthreshold or higher, the temperature in the degassing means for the external loop for separating waxes is reduced, 3) steps 1) to 2) are repeated until the theoretical ratio PH2O:PH2 has a value strictly less than Rthreshold, where Rthreshold is in the range 0.1 to 1.1.

    摘要翻译： 本发明涉及从包含合成气的原料合成烃的方法，其中在三相反应段中使用含有钴的固体催化剂，其操作使得所述催化剂在液相中通过运动而保持在液相中的悬浮液 所述方法包括用于分离蜡的外部回路，其特征在于：1）用于分离蜡的外部回路中的理论比PH 2 O：PH 2通过以下计算确定： PH2理论值= Cv /（R1-Rft×Cv）其中Cv =（COinlet-Codegas）/ COinlet R1 = H2入口/ COinlet Rft =（H2入口-H2脱气）/（COinlet-COdegas）2） 在步骤1）中测定的PH2O：PH2的值为Rthreshold以上，用于分离蜡的外部回路的脱气装置中的温度降低3）重复步骤1）〜2），直到理论比PH 2 O：PH 2 具有严格小于Rt的值 阈值，其中Rthreshold在0.1到1.1的范围内。

    Enhanced GTL process
    45.
    发明授权
    Enhanced GTL process 有权
    增强GTL流程

    公开(公告)号：US09062257B1

    公开(公告)日：2015-06-23

    申请号：US14546109

    申请日：2014-11-18

    申请人： Emerging Fuels Technology, Inc.

    发明人： Kenneth L. Agee ,  Kym B. Arcuri ,  Rafael L. Espinoza

    IPC分类号： C10G2/00 ,  C07C1/04

    CPC分类号： C10G2/32 ,  C07C1/04 ,  C10G2/332 ,  C10G49/007 ,  C10G2300/1022 ,  C10K1/32 ,  C10K3/04

    摘要： A process for converting carbonaceous materials or light hydrocarbon gases into products comprising predominately C5+ hydrocarbons. The process converts the feedstock into synthesis gas comprising hydrogen and carbon monoxide and then uses the Fischer-Tropsch reaction to produce heavy hydrocarbons. A small excess of hydrogen is produced in the syngas generator or by water gas shift for use in product upgrading and for blending with Fischer-Tropsch tail gas for recycle back to syngas generation. A portion of the Fischer-Tropsch tail gas is used as fuel, thus purging combustible light gases and CO2 from the tail gas. Hydrogen rich purge gas is blended into the remaining tail gas resulting in a recycle stream that is returned to the syngas generator. The tail gas components are therefore efficiently used to produce more products.

    摘要翻译： 将碳质材料或轻烃气体转化成主要包含C5 +烃的产品的方法。 该方法将原料转化成包含氢气和一氧化碳的合成气，然后使用费 - 托反应来生产重烃。 在合成气发生器中产生少量氢气，或通过水煤气变换产生产品升级，并与费 - 托尾气混合，以循环回合成气。 一部分费 - 托尾气用作燃料，从而从尾气中清除可燃的轻质气体和二氧化碳。 将富氢吹扫气体混合到剩余的尾气中，产生回流到合成气发生器的再循环流。 因此，尾气组分有效地用于生产更多的产品。

    System, process and reactor for conducting a synthesis gas conversion reaction
    47.
    发明授权
    System, process and reactor for conducting a synthesis gas conversion reaction 有权
    用于进行合成气转化反应的系统，工艺和反应器

    公开(公告)号：US09023901B2

    公开(公告)日：2015-05-05

    申请号：US13955897

    申请日：2013-07-31

    申请人： Lixin You ,  Shabbir Husain ,  Christopher M. Chen

    发明人： Lixin You ,  Shabbir Husain ,  Christopher M. Chen

    IPC分类号： C07C27/06 ,  C07C1/04 ,  C10G2/00

    CPC分类号： C07C1/0485 ,  C07C1/041 ,  C07C2523/75 ,  C10G2/32 ,  C10G2/332 ,  C10G2/341 ,  C07C11/02

    摘要： A synthesis gas conversion process and system are disclosed. Fresh syngas from a methane reformer is used as a sweep zone gas feed which is caused to flow across a water permselective membrane in a membrane reactor. The water permselective membrane is adjacent a synthesis gas conversion reaction zone in which synthesis gas is contacted with a catalyst and converted to effluent including water. Water is removed from the reaction zone through the membrane and passes out of the reactor with the sweep zone gas. The water is then removed from the sweep zone gas forming a modified gas feed which is fed to the reaction zone. The modified gas feed has a preferred H2/CO ratio to feed into the reaction zone.

    摘要翻译： 公开了一种合成气转化方法和系统。 使用来自甲烷重整器的新鲜合成气作为吹扫区气体进料，其被流过膜反应器中的水选择性膜。 水选择性膜与合成气转化反应区相邻，其中合成气与催化剂接触并转化成包含水的流出物。 通过膜从反应区域除去水，并用扫气区气体从反应器中排出。 然后将水从吹扫区气体中除去，形成进料到反应区的改性气体进料。 改性气体进料具有优选的进料到反应区中的H 2 / CO比。

    PRODUCTION OF LIQUID HYDROCARBONS
    49.
    发明申请
    PRODUCTION OF LIQUID HYDROCARBONS 有权
    生产液体碳氢化合物

    公开(公告)号：US20150060326A1

    公开(公告)日：2015-03-05

    申请号：US14389817

    申请日：2013-04-05

    申请人： IGTL TECHNOLOGY LTD

    发明人： Richard John Hyman

    IPC分类号： C10L1/04

    CPC分类号： C10L1/04 ,  C10G2/332 ,  C10G2/343 ,  C10G35/04 ,  C10G45/58 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/20 ,  C10L1/06 ,  C10L1/08 ,  C10L2200/0438 ,  C10L2200/0446 ,  C10L2200/0492 ,  C10L2270/023 ,  C10L2270/026

    摘要： The invention relates to a process for the conversion of hydrogen and one or more oxides of carbon to hydrocarbons, which process comprises: contacting hydrogen and one or more oxides of carbon with a catalyst in a reaction zone; removing from the reaction zone an outlet stream comprising unreacted hydrogen, unreacted one or more oxides of carbon and one or more hydrocarbons and feeding the outlet stream to a separation zone in which the outlet stream is divided into at least three fractions, in which; a first fraction predominantly comprises unreacted hydrogen, unreacted one or more oxides of carbon and hydrocarbons having from 1 to 4 carbon atoms; a second fraction predominantly comprises hydrocarbons having 5 to 9 carbon atoms, at least a portion of which hydrocarbons having from 5 to 9 carbon atoms are olefinic; and a third fraction predominantly comprises hydrocarbons having 10 or more carbon atoms; characterised in that at least a portion of the second fraction is recycled to the reaction zone.

    摘要翻译： 本发明涉及一种将氢和一种或多种碳氧化物转化成烃的方法，该方法包括：使氢和一种或多种碳氧化物与反应区中的催化剂接触; 从反应区域除去包含未反应的氢，未反应的一种或多种碳和一种或多种烃的氧化物的出口物流，并将出口物流输送到分离区，其中出口物流被分成至少三个馏分。 第一级分主要包括未反应的氢，未反应的一种或多种碳和碳原子数为1至4的氧化物; 第二部分主要包含具有5至9个碳原子的烃，其中至少一部分具有5至9个碳原子的烃是烯属的; 并且第三级分主要包含具有10个或更多个碳原子的烃; 其特征在于，所述第二级分的至少一部分被再循环至所述反应区。

    PROTECTED FISCHER-TROPSCH CATALYST AND METHOD OF PROVIDING SAME TO A FISCHER-TROPSCH PROCESS
    50.
    发明申请
    PROTECTED FISCHER-TROPSCH CATALYST AND METHOD OF PROVIDING SAME TO A FISCHER-TROPSCH PROCESS 有权
    受保护的捕获 - 传递催化剂及其提供给FISCHER-TROPSCH过程的方法

    公开(公告)号：US20150023842A1

    公开(公告)日：2015-01-22

    申请号：US14467878

    申请日：2014-08-25

    申请人： RENTECH, INC.

    发明人： Harold A. WRIGHT ,  Belma Demirel ,  Sergio Mohedas ,  Bahman Rejai ,  Ray J. Huang ,  Deena Ferdous ,  Jesse W. Taylor ,  Dawid J. Duvenhage ,  Sara L. Rolfe

    IPC分类号： B01J8/00 ,  B01J8/18

    CPC分类号： B01J8/006 ,  B01J8/18 ,  B01J8/1809 ,  B01J23/745 ,  B01J33/00 ,  B01J35/023 ,  B01J37/0045 ,  B01J37/18 ,  C10G2/32 ,  C10G2/33 ,  C10G2/332 ,  C10G2300/703

    摘要： A method of preparing a spray dried catalyst by combining spray dried catalyst particles with wax so the spray dried catalyst particles are coated with wax, yielding wax coated catalyst particles, and shaping the wax coated catalyst to provide shaped wax coated catalyst. A method of activating Fischer-Tropsch catalyst particles containing oxides by contacting the catalyst particles with a reducing gas in an activation vessel to produce an activated catalyst, wherein contacting is performed in the absence of a liquid medium under activation conditions. A system for activating a Fischer-Tropsch catalyst containing an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst in the absence of a liquid medium and at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.

    摘要翻译： 通过将喷雾干燥的催化剂颗粒与蜡组合来制备喷雾干燥的催化剂的方法，使喷雾干燥的催化剂颗粒用蜡涂覆，产生蜡涂覆的催化剂颗粒，并使蜡涂覆的催化剂成形以提供成形的涂蜡催化剂。 通过使催化剂颗粒与活化容器中的还原气体接触以产生活化的催化剂来活化含有氧化物的费 - 托催化剂颗粒的方法，其中在不存在液体介质的条件下进行接触。 一种用于活化费 - 托催化剂的系统，其包含活化反应器，所述活化反应器配置成在没有液体介质的情况下将活化气体引入费 - 托催化剂的固定或流化床，以及至少一个分离装置，其被配置为分离气流 包括夹带的催化剂细粒，其具有低于来自活化反应器的所需截留尺寸的平均粒度。