TITANIUM OXYNITRIDE HARD MASK FOR LITHOGRAPHIC PATTERNING
    66.
    发明申请
    TITANIUM OXYNITRIDE HARD MASK FOR LITHOGRAPHIC PATTERNING 有权
    用于石墨图案的氧化钛硬质掩模(TITANIUM OXYNITRIDE HARD MASK FOR LITHOGRAPHIC PATTERNING)

    公开(公告)号:US20140199832A1

    公开(公告)日:2014-07-17

    申请号:US13741638

    申请日:2013-01-15

    Abstract: A vertical stack including a dielectric hard mask layer and a titanium nitride layer is formed over an interconnect-level dielectric material layer such as an organosilicate glass layer. The titanium nitride layer may be partially or fully converted into a titanium oxynitride layer, which is subsequently patterned with a first pattern. Alternately, the titanium nitride layer, with or without a titanium oxynitride layer thereupon, may be patterned with a line pattern, and physically exposed surface portions of the titanium nitride layer may be converted into titanium oxynitride. Titanium oxynitride provides etch resistance during transfer of a combined first and second pattern, but can be readily removed by a wet etch without causing surface damages to copper surfaces. A chamfer may be formed in the interconnect-level dielectric material layer by an anisotropic etch that employs any remnant portion of titanium nitride as an etch mask.

    Abstract translation: 在诸如有机硅酸盐玻璃层的互连层电介质材料层上形成包括电介质硬掩模层和氮化钛层的垂直叠层。 氮化钛层可以部分地或完全地转化成氮氧化钛层,其随后用第一图案图案化。 或者,可以用线图案来图案化具有或不具有氮氧化钛层的氮化钛层,并且氮化钛层的物理暴露的表面部分可以转化为氮氧化钛。 钛氮氧化合物在组合的第一和第二图案的转印期间提供耐蚀刻性,但是可以通过湿蚀刻容易地除去而不会对铜表面造成表面损伤。 可以通过使用氮化钛的任何残余部分作为蚀刻掩模的各向异性蚀刻在互连级介电材料层中形成倒角。

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