Fluorine-Containing Nonaqueous Coating Material Composition, Coating Methods, And The Use Of The Coating Material Composition
    67.
    发明申请
    Fluorine-Containing Nonaqueous Coating Material Composition, Coating Methods, And The Use Of The Coating Material Composition 有权
    含氟的非水性涂料组合物,涂布方法以及涂料组合物的用途

    公开(公告)号:US20150240085A1

    公开(公告)日:2015-08-27

    申请号:US14432609

    申请日:2013-08-16

    Abstract: The present invention provides nonaqueous coating material compositions comprising 30% to 80% by weight of at least one poly(meth)acrylate (A), 20% to 70% by weight of one or more polyisocyanate group-containing compounds (B), and one or more catalysts (D), the weight percentages being based in each case on the binder content of (A) and (B), respectively, and the sum of the weight fractions of (A) plus (B) being in each case 100% by weight,wherein the poly(meth)acrylates (A) comprise 0.05% to 15.0% by weight of one more fluorine-containing reaction products of one or more diisocyanates (PI) having two isocyanate groups with different reactivities, one or more (per)fluoroalkyl monoalcohol components (FA), and optionally one or more compounds (V) having at least one group (G1) that is reactive toward isocyanate groups, and optionally having a further functional group (G2), which is different from group (G1).

    Abstract translation: 本发明提供包含30重量%至80重量%的至少一种聚(甲基)丙烯酸酯(A),20重量%至70重量%的一种或多种含多异氰酸酯基团的化合物(B)的非水性涂料组合物和 一种或多种催化剂(D),重量百分比分别基于(A)和(B)的粘合剂含量,并且在每种情况下(A)加(B)的重量分数之和 100重量%,其中所述聚(甲基)丙烯酸酯(A)包含0.05重量%至15.0重量%的一种或多种具有两个具有不同反应性的异氰酸酯基的二异氰酸酯(PI)的含氟反应产物,一种或多种 (全氟)烷基一元醇组分(FA)和任选的一种或多种具有至少一个对异氰酸酯基反应的基团(G1)的化合物(V),并且任选地具有另外的官能团(G2),其不同于 (G1)。

    FLUORINE-CONTAINING HIGHLY BRANCHED POLYMER AND EPOXY RESIN COMPOSITION CONTAINING THE SAME
    68.
    发明申请
    FLUORINE-CONTAINING HIGHLY BRANCHED POLYMER AND EPOXY RESIN COMPOSITION CONTAINING THE SAME 有权
    含氟聚合物的高分子量聚合物和含有该聚合物的环氧树脂组合物

    公开(公告)号:US20150158959A1

    公开(公告)日:2015-06-11

    申请号:US14406277

    申请日:2013-06-06

    Abstract: A fluorine-containing highly branched polymer obtained by polymerizing a polyfunctional monomer A that has two or more radically polymerizable double bonds and all or a portion of which has a bisphenol structure, a monomer B having a fluoroalkyl group and at least one radically polymerizable double bond, within a molecule, and a monomer C having at least one ring-opening polymerizable group selected from the group including an epoxy group and an oxetanyl group, and having at least one radically polymerizable double bond, within a molecule, under the presence of a polymerization initiator D with an amount of 5% by mole to 200% by mole to the number of moles of the polyfunctional monomer A; an epoxy resin composition including the polymer; and an epoxy resin cured product obtained from the resin composition.

    Abstract translation: 通过聚合具有两个或更多个可自由基聚合的双键并且全部或一部分具有双酚结构的多官能单体A,具有氟烷基的单体B和至少一个可自由基聚合的双键而获得的含氟高分支聚合物 和分子内具有至少一个选自环氧基和氧杂环丁烷基的开环聚合性基团并且在分子内具有至少一个自由基聚合性双键的单体C在存在下,在 聚合引发剂D的量相对于多官能单体A的摩尔数为5摩尔%〜200摩尔% 包含该聚合物的环氧树脂组合物; 和由该树脂组合物得到的环氧树脂固化物。

    COMPOSITION FOR THE APPLICATION OF A PROTECTIVE LAYER TO A SUBSTRATE AND METHOD FOR THE APPLICATION THEREOF
    69.
    发明申请
    COMPOSITION FOR THE APPLICATION OF A PROTECTIVE LAYER TO A SUBSTRATE AND METHOD FOR THE APPLICATION THEREOF 审中-公开
    将保护层应用于基板的组合物及其应用方法

    公开(公告)号:US20150112017A1

    公开(公告)日:2015-04-23

    申请号:US14367842

    申请日:2012-12-21

    CPC classification number: C09D123/22 C08L2201/56 C09D5/00 C09D7/20 C09D119/00

    Abstract: The present invention relates to a composition comprising: (a) about 5 wt. % to about 30 wt. % of an amorphous polymer, said amorphous polymer having a glass transition temperature of lower than about −20° C., (b) about 15 wt. % to about 60 wt. % of a filler, and (c) about 10 wt. % to about 80 wt. % of a solvent, wherein the amounts of (a), (b) and (c) are calculated on the total weight of the composition. The present invention also relates to a process for the application of a protective layer to a substrate, the process comprising application of a layer of the composition to the surface of the substrate or a part thereof. The present invention further relates to a container comprising the composition and a propellant.

    Abstract translation: 本发明涉及一种组合物,其包含:(a)约5wt。 %至约30wt。 %的无定形聚合物,所述无定形聚合物的玻璃化转变温度低于约-20℃,(b)约15wt。 %至约60wt。 %的填料,和(c)约10wt。 %至约80wt。 %的溶剂,其中根据组合物的总重量计算(a),(b)和(c)的量。 本发明还涉及一种将保护层应用于基底的方法,该方法包括将该组合物层施加到基底或其一部分的表面。 本发明还涉及包含该组合物和推进剂的容器。

    Method of sulfonation of block polymers
    70.
    发明授权
    Method of sulfonation of block polymers 有权
    嵌段聚合物的磺化方法

    公开(公告)号:US08835562B2

    公开(公告)日:2014-09-16

    申请号:US12498778

    申请日:2009-07-07

    Abstract: Improved methods for preparing sulfonated block polymers with acyl sulfates in non-halogenated aliphatic solvents are provided. The methods include the sulfonation of a precursor block polymer with an acyl sulfate in a reaction mixture further comprising at least one non-halogenated aliphatic solvent to form a sulfonated block polymer, wherein the initial concentration of the precursor block polymer is in the range of from about 0.1 wt % to a concentration that is below the limiting concentration of the precursor block polymer based on the total weight of the reaction mixture. A sulfonation degree of greater than about 1.0 milliequivalent sulfonic acid per gram sulfonated block polymer can be achieved substantially free of polymer precipitation and free of disabling gelation.

    Abstract translation: 提供了在非卤代脂族溶剂中制备具有酰基硫酸盐的磺化嵌段聚合物的改进方法。 所述方法包括在还含有至少一种非卤代脂族溶剂的反应混合物中使用酰基硫酸酯磺化前体嵌段聚合物以形成磺化嵌段聚合物,其中前体嵌段聚合物的初始浓度范围为 约0.1重量%至低于前体嵌段聚合物的极限浓度的浓度,基于反应混合物的总重量。 可以实现大于约1.0毫当量磺酸/克磺化嵌段聚合物的磺化度,基本上不含聚合物沉淀并且没有失效的凝胶化。

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