Low noack volatility poly &agr;-olefins
    61.
    发明授权
    Low noack volatility poly &agr;-olefins 有权
    低不挥发性聚α-烯烃

    公开(公告)号:US06824671B2

    公开(公告)日:2004-11-30

    申请号:US09860142

    申请日:2001-05-17

    IPC分类号: C10M15912

    摘要: The present invention relates to poly &agr;-olefins (PAO's) which exhibit superior Noack volatility at low pour points. Mixtures of 1-decene and 1-dodecene are polymerized using an alcohol promoted BF3 in conjunction with a combination of cocatalysts. The reaction mixture is distilled to remove the unreacted monomeric and dimeric species. The resulting product is then hydrogenated to saturate the oliogomers to provide a hydrogenated product which has a viscosity of 5 cSt. This product is distilled to provide PAO's of varying viscosity grades. The 4 cSt PAO is comprised mostly of trimers and tetramers while the 6 cSt product is comprised of trimers, tetramers, and pentamers.

    摘要翻译: 本发明涉及在低倾点下表现出优异的Noack挥发性的聚α-烯烃(PAO)。 使用醇促进的BF 3与助催化剂的组合结合使1-癸烯和1-十二碳烯的混合物聚合。 蒸馏反应混合物以除去未反应的单体和二聚物质。 然后将所得产物氢化以使所述橄榄醇饱和以提供粘度为5cSt的氢化产物。 将该产品蒸馏以提供不同粘度等级的PAO。 4 cSt PAO主要由三聚体和四聚体组成,而6 cSt产品由三聚体,四聚体和五聚体组成。