摘要:
A novel copolymer of an unsaturated acidic reactant and an atactic vinyl terminated propene polymer (VTPP) and its use in preparation of fuel and lubricant additives is taught. The VTPP has a major amount of polymer chains containing terminal vinyl unsaturation, a number average molecular weight of at least 500, and comprises at least 70 weight per cent propene and 0 to 30 weight per cent of at least one olefin selected from the group consisting of C.sub.2 and C.sub.4 to C.sub.10 olefins. The unsaturated acidic reactant comprises at least one unsaturated C.sub.4 to C.sub.10 carboxylic or dicarboxylic acid or anhydride. An oil soluble dispersant additive of the invention useful in oleaginous compositions is prepared by contacting the atactic VTPP copolymer with at least one nucleophilic reagent selected from the group consisting of amines, alcohols, metal reactants and mixtures thereof under conditions effective to form adducts of the nucleophilic reagent with the copolymer. The novel dispersants made from the copolymers and terpolymers of the invention can be polymeric succinic ester-amide dispersants, polymeric succinimide dispersants, polymeric succinic amide-triazole dispersants, or polymeric succinic triazole dispersants. Fuel and lubricant compositions containing such additives are a part of the invention.
摘要:
Dispersant-viscosity improvers for lubricating oil compositions comprise the reaction product of reactants comprising(a) an oil soluble ethylene-alpha olefin copolymer wherein the alpha olefin is selected from the group consisting of C.sub.3-28 alpha olefins, said polymer having a number average molecular weight ranging from about 30,000 to about 300,000 grafted with an ethylenically unsaturated carboxylic acid or functional derivative thereof;(b-1) at least one polyester containing at least one condensable hydroxyl group; and(b-2) at least one polyamine having at least one condensable primary or secondary amino group, and optionally further comprising (c) at least one hydrocarbyl substituted carboxylic acid or anhydride.
摘要:
A tertiary amino alcohol, being useful as an emulsifier, is defined by the formula (1) or (2): ##STR1## where R is a C.sub.2 to C.sub.24 straight-chain or branched alkylene group, an alicyclic alkylene group, an aralkylene group or --CH.sub.2 CH.sub.2 O).sub.p (CH.sub.2 CH.sub.2).sub.q (where p is 0 or a positive integer and q is a positive integer), R' is a C.sub.1 to C.sub.24 straight-chain or branched alkyl group or an aralkyl group and n is a positive integer of 2 to 50.
摘要:
A method, composition and filter for reducing the presence of sludge or varnish precursors in a lubricating oil circulating within an internal combustion engine. The lubricating oil containing sludge or varnish precursors is contacted with discrete particles of an oil insoluble, oil wettable compound having an antioxidant functional group and/or a dispersant functional group, which are capable of complexing with sludge or varnish precursors. Preferably the compounds comprises a crosslinked amine having ethylene amine functionality. The starting polyethylene amines have a number average molecular weight in the range of about 100 to about 60,000, preferably 200 to 250 and are crosslinked with a silicon oxide, silane, silicate, epoxide, quinone, or phenol-formaldehyde crosslinking agent. The particles are encaged within a one or two stage oil filter together with filtering media such as chemically active filter media, physically active filter media and inactive filter media.
摘要:
A lubricating oil soluble compound suitable for use as a dispersant additive is obtainable by reacting at elevated temperature a polyepoxide with a dispersant having at least one reactive nitrogen-containing moiety. Intermediates of the general formula IV ##STR1## where Y' is a group derived from the reaction of the polyepoxide with reactive nitrogen-containing moieties (i.e. primary or secondary amines) are novel.The process for preparing the lubricating oil soluble compounds comprises at least 2 sequential steps.Lubricating oil compositions comprises a major proportion of lubricating oil and a minor proportion of the lubricating oil soluble compounds.
摘要:
According to the invention, oxyalkylates of aliphatic or cyclic, primarily primary diamines or polyamines, or block polymers (having recurring structural units of the abovementioned oxyalkylate type) produced by prior linking of such oxyalkylates with dicarboxylic acids, are converted into novel substances which are suitable for a very wide variety of areas of application in the field of interface-active agents and can be employed, for example, in the preparation of azo pigments to improve the coloristic properties, by esterification of the terminal hydroxyl group in these aminoxyalkylates using fatty acids or aromatic carboxylic acids and/or resin acids, and, if appropriate, subsequent reaction of free hydroxyl groups which are still present with dicarboxylic acids and sulfite to form the corresponding monoester (containing anionic radicals).
摘要:
Improved additives/detergents for lubricant and fuel compositions are obtained by condensing a hydroxyalkyl or hydroxyaryl compound with an amine compound. The condensates according to the present invention are produced by the acid catalyzed condensation of the amine reactant with the hydroxy reactant.
摘要:
The present invention is directed to a dispersant additive comprising at least one adduct of (A) a polyolefin of 300 to 10,000 number average molecular weight substituted with at least 0.3 (e.g., from about 1 to 4) dicarboxylic acid producing moieties (preferably acid or anhydride moieties) per polyolefin molecule, (B) an amido-amine or thioamido-amine characterized by being a reaction product of at least a polyamine and an alpha, beta-unsaturated compound of the formula: ##STR1## wherein X is sulfur or oxygen, Y is --OR.sup.4, --SR.sup.4, or --NR.sup.4 (R.sup.5), and R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl.
摘要:
This invention relates to a composition comprising the combination of(A) at least one alkyl phenol of the formula(R).sub.a --AR--(OH).sub.b (I)wherein each R is independently a substantially saturated hydrocarbon-based group of an average of at least about 10 aliphatic carbon atoms; a, and b are each independently an integer of one up to three times the number of aromatic nuclei present in Ar with the proviso that the sum of a, b and c does not exceed the unsatisfied valences of Ar; and Ar is an aromatic moiety which is a single ring, a fused ring or a linked polynuclear ring having 0 to 3 optional substituents selected from the group consisting essentially of lower alkyl, lower alkoxyl, carboalkoxy methylol or lower hydrocarbon-based substituted methylol, nitro, nitroso, halo and combinations of said optional substituents, and(B) at least one amino compound with the proviso that the amino compound is not an amino phenol.Lubricants and lubricating oil-fuel mixtures for two-cycle engines which include the above compositions, and methods for lubricating two-cycle engines are also within the scope of this invention.
摘要:
A lubricating oil composition for metal rolling is described, comprising (a) an oily component comprising one or more of fats and oils, mineral oils, and fatty acid esters, and (b) a dispersant comprising one or more of polyethyleneimine/epoxy compound adducts, polyethylene polyamine/epoxy compound adducts, fatty acid esters of the adducts, and salts of the adducts and the fatty acid esters. This composition is useful for rolling metals under high shear and high rolling speed conditions.