Composition for photo imaging
    1.
    发明授权
    Composition for photo imaging 失效
    摄影成像的组成

    公开(公告)号:US5264325A

    公开(公告)日:1993-11-23

    申请号:US918304

    申请日:1992-07-21

    摘要: An improved photoimagable cationically polymerizable epoxy based coating material is provided, that is suitable for use on a variety of substrates. The material includes an epoxy resin system consisting essentially of between about 10% and about 80% by weight of a polyol resin which preferably is a condensation product of epichlorohydrin and bisphenol A having a molecular weight of between about 40,000 and 130,000; and between about 35% and 72% by weight of an epoxidized glycidyl ether of a brominated bisphenol A having a softening point of between about 60.degree. C. and about 110.degree. C. and a molecular weight of between about 600 and 2,500. A third resin, either an epoxy cresol novolak or a polyepoxy resin, is also added to the resin system. To this resin system is added about 0.1 to about 15 parts by weight per 100 parts of resin of a cationic photoinitiator capable of initiating polymerization of said epoxidized resin system upon exposure to actinic radiation; the system being further characterized by having an absorbance of light in the 330 to 700 nm region of less than 0.1 for a 2.0 mil thick film. Optionally a photosensitizer such as perylene and its derivatives or anthracene and its derivatives may be added.

    摘要翻译: 提供了一种改进的可光成像的可阳离子聚合的环氧基涂料,其适用于各种基材。 该材料包括基本上由约10重量%至约80重量%的多元醇树脂组成的环氧树脂体系,多元醇树脂优选为分子量为约40,000至130,000的表氯醇和双酚A的缩合产物; 和约35重量%至72重量%的软化点为约60℃至约110℃,分子量为约600至2,500的溴化双酚A的环氧化缩水甘油醚。 树脂体系中还加入第三树脂,环氧甲酚酚醛清漆或聚环氧树脂。 向该树脂体系中添加约0.1〜约15重量份/ 100份阳离子光引发剂的树脂,其能够在暴露于光化辐射下引发所述环氧化树脂体系的聚合; 该系统的特征还在于,对于2.0密耳厚的膜,在330至700nm区域中的光的吸光度小于0.1。 任选地,可加入光敏剂如苝及其衍生物或蒽及其衍生物。

    Composition for photo imaging
    2.
    发明授权
    Composition for photo imaging 失效
    摄影成像的组成

    公开(公告)号:US5439766A

    公开(公告)日:1995-08-08

    申请号:US976115

    申请日:1992-11-13

    IPC分类号: G03C1/725

    CPC分类号: G03C1/725

    摘要: According to the present invention, good image resolution of a cationically polymerized epoxy based coating, such as a solder mask or dielectric or etch resist, is provided by combining a cationically polymerized epoxy based coating with conventional epoxy glass substrates cured with a curing agent that does not produce basic reaction products. Preferably, the coating is photoimagable. The method for making the same is also provided. The coating material includes an epoxy resin system comprising between from about 10% to about 90%, preferably about 28% to about 57% by weight of a polyol epoxy resin, and from about 10% to about 90%, preferably about 43% to 72% by weight, of a brominated epoxy resin. Optionally, a polyepoxy resin or an epoxy creosol novolak resin is added to the resin system. The polyepoxy resin may be added from an effective amount up to less than 90% of the resin system; the epoxy creosol novolak may be added from an effective amount up to about 80 pph.

    摘要翻译: 根据本发明,通过将阳离子聚合的环氧基涂层与用固化剂固化的常规环氧玻璃基底组合来提供阳离子聚合的环氧基涂层(例如焊料掩模或电介质或抗蚀剂)的良好图像分辨率, 不产生碱性反应产物。 优选地,涂层是可光成像的。 还提供了制造它们的方法。 涂料包括环氧树脂体系,其包含约10%至约90%,优选约28%至约57%重量的多元醇环氧树脂,以及约10%至约90%,优选约43%至 72重量%的溴化环氧树脂。 任选地,在树脂体系中加入聚环氧树脂或环氧酚醛清漆树脂。 聚环氧树脂可以从有效量添加到树脂体系的90%以下; 可以从高达约80pph的有效量加入环氧裂解酚醛清漆。

    Composition for photo imaging
    4.
    发明授权
    Composition for photo imaging 失效
    摄影成像的组成

    公开(公告)号:US5300402A

    公开(公告)日:1994-04-05

    申请号:US730149

    申请日:1991-07-15

    摘要: An improved photoimagable cationically polymerizable epoxy based coating material is provided. The material includes an epoxy resin system consisting essentially of between about 10% and about 80% by weight of a polyol resin which is a condensation product of epichlorohydrin and bisphenol A having a molecular weight of between about 40,000 and 130,000; between about 20% and about 90% by weight of an epoxidized octafunctional bisphenol A formaldehyde novolak resin having a molecular weight of 4,000 to 10,000; and if flame retardancy is required between about 35% and 50% by weight of an epoxidized glycidyl ether of tetrabromo bisphenol A having a softening point of between about 60 C. and about 110 C. and a molecular weight of between about 600 and 2,500. To this resin system is added about 0.1 to about 15 parts by weight per 100 parts of resin of a cationic photoinitiator capable of initiating polymerization of said epoxidized resin system upon exposure to actinic radiation; the system being further characterized by having an absorbance of light in the 330 to 700 nm region of less than 0.1 for a 2.0 mil thick film, and an effective amount of thixatropic agent. Optionally a photosensitizer such as perylene and its derivatives or anthracene and its derivatives may be added.

    摘要翻译: 提供了一种改进的可光成像的可阳离子聚合的环氧基涂料。 该材料包括基本上由约10重量%至约80重量%的多元醇树脂组成的环氧树脂体系,多元醇树脂是分子量为约40,000至130,000的表氯醇和双酚A的缩合产物; 约20%至约90%重量的分子量为4,000至10,000的环氧化八官能双酚A甲醛酚醛清漆树脂; 并且如果阻燃性需要约35重量%至50重量%的四氟双酚A的环氧化缩水甘油醚,其软化点为约60℃至约110℃,分子量为约600至2,500。 向该树脂体系中添加约0.1〜约15重量份/ 100份阳离子光引发剂的树脂,其能够在暴露于光化辐射下引发所述环氧化树脂体系的聚合; 该系统的特征还在于,对于2.0密耳厚的膜,330〜700nm区域的光的吸光度小于0.1,有效量的触变剂。 任选地,可加入光敏剂如苝及其衍生物或蒽及其衍生物。

    Composition for photo imaging
    5.
    发明授权
    Composition for photo imaging 失效
    摄影成像的组成

    公开(公告)号:US5278010A

    公开(公告)日:1994-01-11

    申请号:US956831

    申请日:1992-10-05

    IPC分类号: G03C3/00

    CPC分类号: G03C3/00

    摘要: An improved photoimagable cationically polymerizable epoxy based coating material is provided. The material includes an epoxy resin system consisting essentially of between about 10% and about 80% by weight of a polyol resin which is a condensation product of epichlorohydrin and bisphenol A having a molecular weight of between about 40,000 and 130,000; between about 20% and about 90% by weight of an epoxidized octafunctional bisphenol A formaldehyde novolak resin having a molecular weight of 4,000 to 10,000; and if flame retardancy is required between about 35% and 50% by weight of an epoxidized glycidyl ether of tetrabromo bisphenol A having a softening point of between about 60.degree. C. and about 110.degree. C. and a molecular weight of between about 600 and 2,500. To this resin system is added about 0.1 to about 15 parts by weight per 100 parts of resin of a cationic photoinitiator capable of initiating polymerization of said epoxidized resin system upon exposure to actinic radiation; the system being further characterized by having an absorbance of light in the 330 to 700 nm region of less than 0.1 for a 2.0 mil thick film. Optionally a photosensitizer such as perylene and its derivatives or anthracene and its derivatives may be added.

    摘要翻译: 提供了一种改进的可光成像的可阳离子聚合的环氧基涂料。 该材料包括基本上由约10重量%至约80重量%的多元醇树脂组成的环氧树脂体系,多元醇树脂是分子量为约40,000至130,000的表氯醇和双酚A的缩合产物; 约20%至约90%重量的分子量为4,000至10,000的环氧化八官能双酚A甲醛酚醛清漆树脂; 并且如果阻燃性需要约35重量%至50重量%的四溴双酚A的环氧化缩水甘油醚,其软化点在约60℃至约110℃之间,分子量为约600至 2,500。 向该树脂体系中添加约0.1〜约15重量份/ 100份阳离子光引发剂的树脂,其能够在暴露于光化辐射下引发所述环氧化树脂体系的聚合; 该系统的特征还在于,对于2.0密耳厚的膜,在330至700nm区域中的光的吸光度小于0.1。 任选地,可加入光敏剂如苝及其衍生物或蒽及其衍生物。

    Composition for photo imaging
    6.
    发明授权
    Composition for photo imaging 失效
    摄影成像的组成

    公开(公告)号:US5026624A

    公开(公告)日:1991-06-25

    申请号:US318536

    申请日:1989-03-03

    摘要: An improved photoimagable cationically polymerizable epoxy based coating material is provided. The material includes an epoxy resin system consisting essentially of between about 10% and about 80% by weight of a polyol resin which is a condensation product of epichlorohydrin and bisphenol A having a molecular weight of between about 40,000 and 130,000; between about 20% and about 90% by weight of an epoxidized octafunctional bisphenol A formaldehyde novolak resin having a molecular weight of 4,000 to 10,000; and if flame retardancy is required between about 35% and 50% by weight of an epoxidized glycidyl ether of tetrabromo bisphenol A having a softening point of between about 60.degree. C. and about 110.degree. C. and a molecular weight of between about 600 and 2,500. To this resin system is added about 0.1 to about 15 parts by weight per 100 parts of resin of a cationic photoinitiator capable of initiating polymerization of said epoxidized resin system upon exposure to actinic radiation; the system being further characterized by having an absorbance of light in the 330 to 700 nm region of less than 0.1 for a 2.0 mil thick film. Optionally a photosensitizer such as perylene and its derivatives or anthracene and its derivatives may be added.

    Composition for photo imaging
    7.
    发明授权

    公开(公告)号:US5304457A

    公开(公告)日:1994-04-19

    申请号:US956836

    申请日:1992-10-05

    IPC分类号: G03C1/725

    CPC分类号: G03C1/725

    摘要: An improved photoimagable cationically polymerizable epoxy based coating material is provided. The material includes an epoxy resin system consisting essentially of between about 10% and about 80% by weight of a polyol resin which is a condensation product of epichlorohydrin and bisphenol A having a molecular weight of between about 40,000 and 130,000; between about 20% and about 90% by weight of an epoxidized octafunctional bisphenol A formaldehyde novolak resin having a molecular weight of 4,000 to 10,000; and if flame retardancy is required between about 35% and 50% by weight of an epoxidized glycidyl ether of tetrabromo bisphenol A having a softening point of between about 60.degree. C. and about 110.degree. C. and a molecular weight of between about 600 and 2,500. To this resin system is added about 0.1 to about 15 parts by weight per 100 parts of resin of a cationic photoinitiator capable of initiating polymerization of said epoxidized resin system upon exposure to actinic radiation; the system being further characterized by having an absorbance of light in the 330 to 700 nm region of less than 0.1 for a 2.0 mil thick film. Optionally a photosensitizer such as perylene and its derivatives or anthracene and its derivatives may be added.