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1.发明申请公开(公告)号：US20170355649A1
公开(公告)日：2017-12-14
申请号：US15178046
申请日：2016-06-09
Applicant: UT-BATTELLE, LLC
Inventor： Chaitanya K. Narula , Brian H. Davison , Zhenglong Li
CPC classification number: C07C1/20 , C07C1/24 , C07C2/12 , C07C2/58 , C07C2529/40 , C07C2529/48 , C10G3/45 , C10G3/49 , C10G50/00 , C10G2300/1014 , C10L1/04 , C10L1/06 , C10L1/08 , C10L2200/0423 , C10L2200/043 , C10L2200/0446 , C10L2200/0469 , C10L2270/023 , C10L2270/026 , C10L2270/04 , C10L2290/26 , Y02P20/52 , C07C11/04
Abstract: A method for converting an alcohol to a hydrocarbon fraction reduced in gaseous hydrocarbon content, the method comprising: (i) contacting said alcohol with a metal-loaded zeolite catalyst under conditions suitable for converting said alcohol to a first hydrocarbon fraction containing liquid hydrocarbons having at least five carbon atoms along with gaseous hydrocarbons having less than five carbon atoms, wherein said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said first hydrocarbon fraction; and (ii) selectively removing said gaseous hydrocarbons from the first hydrocarbon fraction and contacting said gaseous hydrocarbons with a metal-loaded zeolite catalyst under conditions suitable for converting said gaseous hydrocarbons into liquid hydrocarbons having at least five carbon atoms to produce a second hydrocarbon fraction reduced in gaseous hydrocarbon content, wherein the metal-loaded zeolite catalyst in steps (i) and (ii) are the same or different.
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公开(公告)号：US10696606B2
公开(公告)日：2020-06-30
申请号：US15178046
申请日：2016-06-09
Applicant: UT-BATTELLE, LLC
Inventor： Chaitanya K. Narula , Brian H. Davison , Zhenglong Li
IPC: C10G3/00 , C07C1/20 , B01J29/48 , C07C1/24 , C10G50/00 , C07C2/12 , C07C2/58 , C10L1/04 , C10L1/06 , C10L1/08
Abstract: A method for converting an alcohol to a hydrocarbon fraction reduced in gaseous hydrocarbon content, the method comprising: (i) contacting said alcohol with a metal-loaded zeolite catalyst under conditions suitable for converting said alcohol to a first hydrocarbon fraction containing liquid hydrocarbons having at least five carbon atoms along with gaseous hydrocarbons having less than five carbon atoms, wherein said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said first hydrocarbon fraction; and (ii) selectively removing said gaseous hydrocarbons from the first hydrocarbon fraction and contacting said gaseous hydrocarbons with a metal-loaded zeolite catalyst under conditions suitable for converting said gaseous hydrocarbons into liquid hydrocarbons having at least five carbon atoms to produce a second hydrocarbon fraction reduced in gaseous hydrocarbon content, wherein the metal-loaded zeolite catalyst in steps (i) and (ii) are the same or different.
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公开(公告)号：US09533921B2
公开(公告)日：2017-01-03
申请号：US14293248
申请日：2014-06-02
Applicant: UT-BATTELLE, LLC
Inventor： Chaitanya K. Narula , Brian H. Davison , Martin Keller
IPC: C07C1/22 , B01J29/48 , B01J29/46 , C12P7/06 , C12P7/08 , C12P7/10 , C10G3/00 , B01J37/02 , B01J29/06 , B01J29/072 , B01J29/076 , B01J35/02 , B01J35/04 , C12P7/16 , B01J29/14 , B01J29/16 , B01J29/68 , B01J29/69 , B01J29/76 , B01J29/78
CPC classification number: C10G3/49 , B01J29/061 , B01J29/072 , B01J29/076 , B01J29/143 , B01J29/146 , B01J29/163 , B01J29/166 , B01J29/46 , B01J29/48 , B01J29/68 , B01J29/69 , B01J29/7615 , B01J29/7661 , B01J29/7669 , B01J29/7692 , B01J29/7815 , B01J29/7861 , B01J29/7869 , B01J29/7892 , B01J35/023 , B01J35/04 , B01J37/0246 , B01J2229/183 , B01J2229/186 , C07C1/22 , C10G3/45 , C10G2300/1011 , C10G2300/1014 , C10G2300/4006 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C12P7/06 , C12P7/08 , C12P7/10 , C12P7/16 , Y02E50/10 , Y02E50/16 , Y02E50/17 , Y02P30/20
Abstract: A method for converting an alcohol to a hydrocarbon, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein said alcohol can be produced by a fermentation process, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said hydrocarbon.
Abstract translation: 一种将醇转化为烃的方法，所述方法包括使所述醇与金属负载的沸石催化剂在至少100℃和至多550℃的温度下接触，其中所述醇可以通过发酵 所述金属是带正电荷的金属离子，并且所述金属负载的沸石催化剂是催化活性的，用于将所述醇转化成所述烃。
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4.发明申请ZEOLITE-BASED SCR CATALYSTS AND THEIR USE IN DIESEL ENGINE EMISSION TREATMENT 审中-公开基于沸石的SCR催化剂及其在柴油发动机排放处理中的应用公开(公告)号：US20150238944A1
公开(公告)日：2015-08-27
申请号：US14662946
申请日：2015-03-19
Applicant: UT-Battelle, LLC
Inventor： Chaitanya K. Narula , Xiaofan Yang
CPC classification number: B01J29/46 , B01D53/9418 , B01D2255/206 , B01D2255/2063 , B01D2255/207 , B01D2255/20738 , B01D2255/20761 , B01D2255/209 , B01D2255/504 , B01D2258/012 , B01J23/825 , B01J23/83 , B01J29/405 , B01J37/009 , B01J37/0203 , B01J37/088 , B01J2229/186 , C01B39/02 , C01B39/026 , C01B39/06 , C01B39/36 , Y02T10/24
Abstract: A catalyst comprising a zeolite loaded with copper ions and at least one trivalent metal ion other than Al+3, wherein the catalyst decreases NOx emissions in diesel exhaust. The trivalent metal ions are selected from, for example, trivalent transition metal ions, trivalent main group metal ions, and/or trivalent lanthanide metal ions. In particular embodiments, the catalysts are selected from Cu—Fe-ZSM5, Cu—La-ZSM-5, Fe—Cu—La-ZSM5, Cu—Sc-ZSM-5, and Cu—In-ZSM5. The catalysts are placed on refractory support materials and incorporated into catalytic converters.
Abstract translation: 一种催化剂，其包含负载有铜离子的沸石和除Al + 3以外的至少一种三价金属离子，其中所述催化剂减少柴油机废气中的NOx排放。 三价金属离子选自例如三价过渡金属离子，三价主族金属离子和/或三价镧系元素金属离子。 在具体实施方案中，催化剂选自Cu-Fe-ZSM5，Cu-La-ZSM-5，Fe-Cu-La-ZSM5，Cu-Sc-ZSM-5和Cu-In-ZSM5。 将催化剂置于耐火载体材料上并加入催化转化器中。
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5.发明申请CATALYTIC CONVERSION OF ALCOHOLS HAVING AT LEAST THREE CARBON ATOMS TO HYDROCARBON BLENDSTOCK 有权具有至少三个碳原子的酒精的催化转化为烃混合物公开(公告)号：US20150011813A1
公开(公告)日：2015-01-08
申请号：US14321012
申请日：2014-07-01
Applicant: UT-BATTELLE, LLC
Inventor： Chaitanya K. Narula , Brian H. Davison
IPC: C07C1/22
CPC classification number: C10G3/49 , C10G3/00 , C10G3/45 , C10G45/44 , C10G50/00 , C10G2400/02 , C10G2400/20 , C10G2400/22
Abstract: A method for producing a hydrocarbon blendstock, the method comprising contacting at least one saturated acyclic alcohol having at least three and up to ten carbon atoms with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein the metal is a positively-charged metal ion, and the metal-loaded zeolite catalyst is catalytically active for converting the alcohol to the hydrocarbon blendstock, wherein the method directly produces a hydrocarbon blendstock having less than 1 vol % ethylene and at least 35 vol % of hydrocarbon compounds containing at least eight carbon atoms.
Abstract translation: 一种制备烃共混物料的方法，该方法包括使至少一种具有至少三个至多十个碳原子的饱和无环醇与金属负载的沸石催化剂在至少100℃和至多550℃的温度下接触 C.其中金属是带正电荷的金属离子，并且负载金属的沸石催化剂具有催化活性，用于将醇转化成烃共混物，其中该方法直接生产具有小于1体积％乙烯的烃共混物， 至少35vol％的含有至少8个碳原子的烃化合物。
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Patent Agency Ranking
6.发明授权公开(公告)号：US09944861B2
公开(公告)日：2018-04-17
申请号：US14878663
申请日：2015-10-08
Applicant: UT-BATTELLE, LLC
Inventor： Chaitanya K. Narula , Brian H. Davison
CPC classification number: C10G3/49 , C10G3/00 , C10G3/45 , C10G45/44 , C10G50/00 , C10G2400/02 , C10G2400/20 , C10G2400/22
Abstract: A method for producing a hydrocarbon blendstock, the method comprising contacting at least one saturated acyclic alcohol having at least three and up to ten carbon atoms with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein the metal is a positively-charged metal ion, and the metal-loaded zeolite catalyst is catalytically active for converting the alcohol to the hydrocarbon blendstock, wherein the method directly produces a hydrocarbon blendstock having less than 1 vol % ethylene and at least 35 vol % of hydrocarbon compounds containing at least eight carbon atoms.
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公开(公告)号：US09694352B2
公开(公告)日：2017-07-04
申请号：US15278785
申请日：2016-09-28
Applicant: UT-Battelle, LLC
Inventor： Chaitanya K. Narula , Xiaofan Yang
IPC: B01D53/56 , B01J29/76 , B01J29/068 , B01J29/072 , B01J29/06 , B01J29/064 , B01D53/94 , C01B39/06 , B01J29/78 , C01B39/46 , B01J29/70 , C01B39/02 , B01D53/86
CPC classification number: B01J29/76 , B01D53/8628 , B01D53/8631 , B01D53/9418 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2258/012 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/7049 , B01J29/7065 , B01J29/763 , B01J29/783 , B01J35/04 , B01J2229/183 , B01J2229/186 , C01B39/02 , C01B39/026 , C01B39/06 , C01B39/065 , C01B39/46 , Y02T10/24
Abstract: A catalyst composition includes a heterobimetallic zeolite characterized by a chabazite structure loaded with copper ions and at least one trivalent metal ion other than Al3+. The catalyst composition decreases NOx emissions in diesel exhaust and is suitable for operation in a catalytic converter.
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公开(公告)号：US09475039B2
公开(公告)日：2016-10-25
申请号：US14662954
申请日：2015-03-19
Applicant: UT-Battelle, LLC
Inventor： Chaitanya K. Narula , Xiaofan Yang
IPC: B01J29/06 , B01J29/76 , B01J29/068 , B01J29/072 , B01J29/064 , B01D53/94 , C01B39/06 , B01J29/78 , B01J29/70 , C01B39/02
CPC classification number: B01J29/76 , B01D53/8628 , B01D53/8631 , B01D53/9418 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2258/012 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/7049 , B01J29/7065 , B01J29/763 , B01J29/783 , B01J35/04 , B01J2229/183 , B01J2229/186 , C01B39/02 , C01B39/026 , C01B39/06 , C01B39/065 , C01B39/46 , Y02T10/24
Abstract: A catalyst composition includes a heterobimetallic zeolite characterized by a chabazite structure loaded with copper ions and at least one trivalent metal ion other than Al3+. The catalyst composition decreases NOx emissions in diesel exhaust and is suitable for operation in a catalytic converter.
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公开(公告)号：US09278892B2
公开(公告)日：2016-03-08
申请号：US14263257
申请日：2014-04-28
Applicant: UT-BATTELLE, LLC
Inventor： Chaitanya K. Narula , Brian H. Davison , Martin Keller
IPC: B01J29/06 , C07C1/20 , C07C1/22 , B01J29/18 , C07C1/24 , C07C2/66 , C07C2/86 , B01J29/08 , B01J29/40 , B01J29/80 , C07C2/64 , C12P7/06 , B01J35/00 , B01J29/48 , B01J29/46 , B01J29/70 , B01J29/76 , B01J29/78
CPC classification number: C07C1/22 , B01J29/061 , B01J29/084 , B01J29/088 , B01J29/18 , B01J29/40 , B01J29/405 , B01J29/46 , B01J29/48 , B01J29/7049 , B01J29/76 , B01J29/78 , B01J29/80 , B01J35/0006 , B01J2229/18 , B01J2229/186 , C07C1/24 , C07C2/64 , C07C2/66 , C07C2/864 , C07C2529/072 , C07C2529/076 , C07C2529/08 , C07C2529/14 , C07C2529/18 , C07C2529/40 , C07C2529/48 , C07C2529/70 , C12P7/06 , Y02E50/17 , Y02P20/52 , Y02P30/20 , C07C11/04 , C07C15/073
Abstract: A method for converting an alcohol to a hydrocarbon fraction having a lowered benzene content, the method comprising: converting said alcohol to a hydrocarbon fraction by contacting said alcohol, under conditions suitable for converting said alcohol to said hydrocarbon fraction, with a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon fraction, and contacting said hydrocarbon fraction with a benzene alkylation catalyst, under conditions suitable for alkylating benzene, to form alkylated benzene product in said hydrocarbon fraction. Also described is a catalyst composition useful in the method, comprising a mixture of (i) a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon, and (ii) a benzene alkylation catalyst, in which (i) and (ii) may be in a mixed or separated state. A reactor for housing the catalyst and conducting the reaction is also described.
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公开(公告)号：US09190697B2
公开(公告)日：2015-11-17
申请号：US13886542
申请日：2013-05-03
Applicant: UT-Battelle, LLC
Inventor： Chaitanya K. Narula , Claus Daniel
IPC: H01M4/88 , H01M10/0562 , B82Y30/00 , C04B35/495 , C04B35/626 , H01M10/052 , C01G33/00 , H01B1/08 , H01M10/0525
CPC classification number: H01M10/0562 , B82Y30/00 , C01G33/00 , C01G33/006 , C01P2002/72 , C01P2006/40 , C04B35/495 , C04B35/6264 , C04B2235/3201 , C04B2235/3203 , C04B2235/3227 , C04B2235/3251 , C04B2235/3286 , C04B2235/441 , C04B2235/5454 , H01B1/08 , H01M10/052 , H01M10/0525 , H01M2300/0071 , Y02E60/122 , Y02P70/54
Abstract: A composition comprised of nanoparticles of lithium ion conducting solid oxide material, wherein the solid oxide material is comprised of lithium ions, and at least one type of metal ion selected from pentavalent metal ions and trivalent lanthanide metal ions. Solution methods useful for synthesizing these solid oxide materials, as well as precursor solutions and components thereof, are also described. The solid oxide materials are incorporated as electrolytes into lithium ion batteries.
Abstract translation: 由锂离子传导固体氧化物材料的纳米颗粒组成的组合物，其中固体氧化物材料由锂离子组成，以及选自五价金属离子和三价镧系金属离子的至少一种金属离子。 还描述了用于合成这些固体氧化物材料的溶液方法，以及前体溶液及其组分。 固体氧化物材料作为电解质掺入锂离子电池中。
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