摘要:
The present invention is directed towards a composition for decontaminating surfaces contaminated with toxic chemicals/substances, comprising at least one type of metal oxyhydroxide such as zirconium hydroxide, Zr(OH)4, optionally with added water for hydration of the solid, mixed into a carrier liquid used for application to a contaminated surface.
摘要:
A method for decontamination of a toxic substance is disclosed. The method includes fabricating a plurality of nanomotors, and putting the plurality of nanomotors in contact with a contaminant solution comprising the toxic substance. Fabricating the plurality of nanomotors includes preparing a mesoporous silica template, forming the plurality of nanomotors within the mesoporous silica template, and separating the plurality of nanomotors from the mesoporous silica template. The mesoporous silica template includes a plurality of channels, where each channel of the plurality of channels have a diameter less than about 50 nm and a length of less than about 100 nm, and each nanomotor of the plurality of nanomotors is formed within a channel of the plurality of channels. Putting the plurality of nanomotors in contact with the contaminant solution includes adding hydrogen peroxide (H2O2) and the plurality of nanomotors to the contaminant solution.
摘要:
A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.
摘要:
Disclosed herein are non-wild-type organophosphorus acid anhydrolases having two site mutations, methods of production, and methods of use to effectively degrade toxic chemicals such as ((RS)-Propan-2-yl methylphosphonofluoridate) (Sarin) and other organophosphorus compounds.
摘要:
Provided is a mutated hyperthermophilic PTE having a lactonase activity derived from a hyperthermophilic phosphotriesterase corresponding to the consensus sequence of SEQ ID NO: 1, the mutated PTE including the at least one mutation chosen amongst 55 putative positions and the mutated PTE having enhanced properties. Also provided are compositions including the mutated hyperthermophilic PTE and the uses thereof, notably as bioscavenger of organophosphate compounds or as quorum quencher of the bacteria using lactones to communicate.
摘要:
The invention provides reactive sorbents and methods of making and using the same in order to decontaminate surfaces contaminated with toxic agents, such as chemical warfare agents and/or industrial toxins. The reactive sorbents are of two general types, one of which comprises dehydroxylated aluminum oxide and the other comprises porous carbon impregnated with a reactive solution, so that both sorbents take up and then detoxify toxic agents.
摘要:
A method is disclosed for the enzymatic degradation of polyester amides. The method involves mixing polyester amides with esterase or protease enzymes in aqueous solution.
摘要:
Methods and apparatus for high efficiency generation of electricity and low oxides of nitrogen (NO.sub.x) emissions are provided. The electricity is generated from combustion of hydrogen-rich gases produced in waste conversion units using ultra lean fuel to air ratios in the range of 0.4-0.7 relative to stoichiometric operation in internal combustion engine-generators or ultra lean operation in gas turbines to ensure minimal production of pollutants such as NO.sub.x. The ultra lean operation also increases the efficiency of the internal combustion engine. High compression ratios (r=12 to 15) can also be employed to further increase the efficiency of the internal combustion engine. Supplemental fuel, such as natural gas or diesel oil, may be added directly to the internal combustion engine-generator or gas turbine for combustion with the hydrogen-rich gases produced in waste conversion unit. In addition, supplemental fuel may be reformed into a hydrogen-rich gas in a plasma fuel converter and then introduced into the internal combustion engine-generator or a gas turbine for combustion along with supplemental fuel and the hydrogen-rich gases produced in waste conversion unit. The preferred embodiment of the waste conversion unit is a fully integrated tunable arc plasma-joule heated melter with a common molten pool and power supply circuits which can be operated simultaneously without detrimental interaction with one another. In this embodiment, the joule heated melter is capable of maintaining the material in a molten state with sufficient electrical conductivity to allow rapid restart of a transferred arc plasma.
摘要:
Methods and apparatus for treating waste are provided. Waste is converted in an arc plasma-joule heated melter system utilizing one or more arc plasma electrodes and a plurality of joule heating electrodes. The arc plasma electrode(s) can be configured for operation utilizing AC or DC power, or for switching between AC and DC power. The arc plasma electrodes can also be configured for independent arc voltage and arc current control. The joule heating circuits are configured for simultaneous operation with the arcing electrodes, but without detrimental interaction with the arcing electrodes. The systems provide stable, non-leachable products and a gaseous fuel. The gaseous fuel can be utilized in a combustion or non-combustion process to generate electricity.
摘要:
A method of preventing thermite reactions during the high temperature incineration (slag temperature greater than 1200.degree. C.) of waste material streams containing aluminum and iron (steel) by mixing a low melting SiO.sub.2 containing material such as water glass or a mixture of sand with NaHCO.sub.3 or Na.sub.2 CO.sub.3 with the waste material.