OXAZOLINE COMPOUND, SYNTHESIS METHOD THEREFOR AND APPLICATION THEREOF

    公开(公告)号:US20220240509A1

    公开(公告)日:2022-08-04

    申请号:US17621900

    申请日:2020-09-24

    申请人: NANKAI UNIVERSITY

    摘要: Disclosed are an oxazoline compound, a synthesis method therefor and an application thereof. The oxazoline compound has a structure represented by formula (I), wherein in the formula (I), R is selected from groups represented by formula (I-1), formula (I-2), and formula (I-3), where an oxazoline derivative having a novel molecular structure is obtained by introducing a nitrogen heterocycle, an ether bond or a sulfonate structure into the oxazoline compound. The oxazoline derivative is useful in the field of agricultural protection, and has higher acaricidal activity than etoxazole, can inhibit the synthesis of chitin from mites, and can effectively control the embryogenesis and development of eggs of Tetranychus cinnabarinus, as well as the ecdysis process from larvae to adults, and therefore has a significant effect in killing mite eggs and larvae.

    A diphenylamine-linked chiral bis(oxazoline) ligand without C2-symmetry, synthesis method and application thereof

    公开(公告)号:US20220227719A1

    公开(公告)日:2022-07-21

    申请号:US17614752

    申请日:2020-04-30

    摘要: The present invention discloses a diphenylamine-linked chiral bis(oxazoline) ligand without C2-symmetry of formula 3 and its synthesis method and application in an asymmetric catalytic reaction, wherein C2-symmetry is lost by introducing different groups into the diphenylamine backbone to realize precise control of “electronic effect” of the ligand backbone. An anthranilic acid derivative and an orthochlorobenzoic acid derivative are used as starting materials to prepare a compound of formula 1, and then the compound of formula 1 is reacted with a chiral amino alcohol compound to prepare a β-bishydroxy amide compound of formula 2, and the compound of formula 2 is further subjected to condensation to obtain the diphenylamine-linked chiral bis(oxazoline) ligand without C2-symmetry of formula 3. The present invention also provides an application of a catalyst formed by coordination of the diphenylamine-linked chiral bis(oxazoline) ligand without C2-symmetry with copper salt, zinc salt, nickel salt, iron salt or rhodium salt, in an asymmetric catalytic reaction.

    Polymers and Lubricating Compositions Containing Polymers

    公开(公告)号:US20210214498A1

    公开(公告)日:2021-07-15

    申请号:US17149016

    申请日:2021-01-14

    摘要: A polymer comprising units having the structure (I): wherein x is 2 or 3, wherein L is (CH2)y, where y is an integer from 1 to 10, or wherein L is CH(CH3)CH2S(CH2)z, where z is an integer from 1 to 5; wherein [Q] is absent or is a polymerised moiety consisting of units having the structure (II): wherein R is a hydrocarbyl group, or a hydrocarbyl group containing one or more heteroatoms, wherein R may be linear, branched or cyclic, saturated or unsaturated, and wherein R has from 1 to 30 carbon atoms; wherein [Q] either consists of identical units of structure (II), or wherein [Q] consists of more than one different units of structure (II), differing in group R; and wherein X is a halogen or another chain terminating group. The polymers may find use as additives in lubricating compositions where they provide friction improvement and wear reduction.