WHITE NANOZYME TEST STRIP AND ITS PREPARATION METHOD AND APPLICATION

    公开(公告)号:US20240302287A1

    公开(公告)日:2024-09-12

    申请号:US18136348

    申请日:2023-04-19

    发明人: Lei HAN Yucui ZHANG

    IPC分类号: G01N21/78

    CPC分类号: G01N21/78 G01N2021/7759

    摘要: A white nanozymes test strip includes a substrate, an organic developer, and a manganese-based metal-organic framework nanozyme is provided, the manganese-based metal-organic framework nanozymes and the organic developer are fixed on the substrate. The present invention uses a white nanozymes test strip as described above, which is inexpensive, simple to prepare and high stability, can resist the interference of oxygen, and the test results are easier to observe, solving the problem that the color development results of colored nanomaterials are not easy to observe, thus improving the detection sensitivity.

    Receptor and method for removing oxoanions from aqueous phase

    公开(公告)号:US12077455B2

    公开(公告)日:2024-09-03

    申请号:US17436780

    申请日:2020-03-06

    摘要: A receptor for the simultaneous removal of oxoanions and their counterions from aqueous phase, particularly containing radioactive wastes, containing amide groups specifically coordinating the oxoanions, as well as moieties specifically coordinating cations, according to the present invention is characterised in that it contains within one molecule domains binding oxoanions and domains binding cations, preferably adapting a molecular structure of a general formula: (I) wherein Z this is a group containing crown ether, preferably a benzocrown group, X is any substituent, including the Y—Z grouping, and Y is any substituent or 0 (i.e. a direct bond between N and Z), where the oxoanion binding domain is a squaramide unit coordinating the oxoanions through amide groups, and squaramide contains additional substituents that increase or decrease the acidity of its amide protons, compared to unsubstituted squaramide, whereas the counter ion binding domain is a crown ether of a size adjusted to the type of binding cation, which forms part of at least one of the aforementioned substituents of squaramide, where the receptor has the ability to remove oxoanions and their counterions from aqueous phase to another water-immiscible phase, preferably to organic phase, and has the ability to form soluble complexes in at least one of the aforementioned phases. The invention considers also a method of removing oxoanions in the form of inorganic salts from aqueous phase, using receptors of the invention in the form of organic molecules containing amide groups, according to the invention is characterised in that it uses the aforementioned receptors for simultaneous binding of oxoanions and their counterions in aqueous phase, preferably acidic when using the receptor with substituents increasing acidity of squaramide protons, or alkaline when using the receptor with substituents decreasing acidity of squaramide protons. A sensor for detecting oxoanions according to the invention is characterised in that it uses the aforementioned receptors, dissolved or suspended in an organic solvent or in a mixture of organic solvents, forming coloured complexes in contact with the phase containing given oxoanions. The preparation for removing oxoanions from aqueous solutions, particularly containing radioactive waste at the stage preceding their disposal by vitrification, is characterised in that it contains the receptor according to the invention, dissolved or suspended in the water-immiscible phase, and the appropriate amount of counterion facilitating extraction. A process of utilisation of aqueous solutions by vitrification, particularly solutions containing radioactive waste, is characterised in that vitrification step is preceded by the step of oxoanions removal, preferably sulfate(VI) anions, by the method according to the invention, using the receptors according to the invention, preferably using the preparation according to the invention.