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公开(公告)号:US20240191147A1
公开(公告)日:2024-06-13
申请号:US18506264
申请日:2023-11-10
申请人: PHILLILPS 66 COMPANY
发明人: Jinfeng Lai , Leonard Nyadong
CPC分类号: C10G47/22 , C10G11/00 , C10G45/00 , G01N24/08 , G01N33/2835 , C10G2300/1059 , C10G2400/30
摘要: Processes for rapidly and accurately predicting the fouling potential of a heavy petroleum fraction in a commercial refinery, informing the selection of one or more interventions to prevent or decrease the rate of said fouling. The process utilizes several specialized 13C Nuclear Magnetic Resonance procedures to more accurately quantify tertiary and quaternary bridgehead aromatic carbon in the heavy petroleum fraction This permits more accurate calculation of a Condensation Index for the heavy petroleum fraction to more accurately predict fouling potential of the fraction. When the condensation index is at or above a threshold value, the process implements one or more responses to improve operational efficiency of the commercial refinery.
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公开(公告)号:US20190249093A1
公开(公告)日:2019-08-15
申请号:US15896718
申请日:2018-02-14
CPC分类号: C10G53/04 , B01D3/10 , B01D3/14 , B01D11/0203 , C10G7/06 , C10G9/34 , C10G31/08 , C10G2300/1059 , C10G2300/1074 , C10G2400/04 , C10L1/08
摘要: A method for producing a diesel having improved cold flow properties, the method comprising the steps of introducing a crude oil to a distillation column, separating the crude oil in the distillation unit to produce a light gas oil, and a light vacuum gas oil, where the light gas oil has a T95% cut point in the range between 300 deg C. and 340 deg C., where the light vacuum gas oil has a T95% cut point in the range between 400 deg C. and 430 deg C., processing the light vacuum gas oil in the supercritical water unit to produce an upgraded vacuum gas oil, separating the upgraded vacuum gas oil in the fractionator to produce an upgraded light fraction, an upgraded light gas oil, and upgraded heavy fraction, introducing the upgraded light gas oil into a diesel pool, and blending the light gas oil into the diesel pool.
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公开(公告)号:US20180320093A1
公开(公告)日:2018-11-08
申请号:US16031783
申请日:2018-07-10
IPC分类号: C10G69/04 , C10G65/04 , B01J23/883 , C10G45/58 , C10G73/02 , C10G45/44 , B01J21/04 , C10M101/02 , C10G65/12 , C09D11/033 , B01J23/888 , C10G69/02 , C10G47/20 , B01J37/20 , C09K3/00 , C10G45/64 , C10G45/02 , C10G47/18 , C10G65/08 , B01J23/882
CPC分类号: C10G69/04 , B01J21/04 , B01J23/882 , B01J23/883 , B01J23/888 , B01J37/20 , C09D11/033 , C09K3/00 , C10G45/02 , C10G45/44 , C10G45/58 , C10G45/64 , C10G47/18 , C10G47/20 , C10G65/043 , C10G65/08 , C10G65/12 , C10G69/02 , C10G73/02 , C10G2300/1059 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2400/10 , C10G2400/18 , C10M101/02 , C10M2203/1006 , C10M2203/1065 , C10N2220/022 , C10N2220/023 , C10N2220/031 , C10N2230/40 , C10N2230/43 , C10N2240/40
摘要: A method for producing hydrocarbon solvents having a sulfur content of less than 10 ppm, aromatic hydrocarbon content of less than 500 ppm, an initial boiling point higher than or equal to 300° C. and final boiling point lower than or equal to 500° C., for a fraction interval of a maximum of 100° C., and pour point lower than −25° C. according to the standard ASTM D5950, comprising of the following steps of: dewaxing of a hydrocarbon fraction having initial boiling point higher than 300° C. derived from the distillation of a gas oil fraction, hydrodearomatisation of all or part of the dewaxed effluent, in the presence of a catalyst comprising nickel on an alumina base, at a pressure ranging from 60 to 200 bar and a temperature ranging from 80° C. to 250° C., recovery of the dewaxed and dearomatised fraction, distillation in fractions of the dewaxed and dearomatised fraction, recovery of at least one 300° C.+ fraction having pour point lower than −25° C., this fraction having a distillation interval lower than 100° C.
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公开(公告)号:US09920259B2
公开(公告)日:2018-03-20
申请号:US14816531
申请日:2015-08-03
申请人: SHELL OIL COMPANY
IPC分类号: C10G45/08 , C10G45/06 , B01J31/02 , B01J21/04 , B01J23/75 , B01J23/755 , B01J23/88 , B01J23/882 , B01J23/883 , B01J27/19 , B01J35/02 , B01J35/10 , B01J37/02
CPC分类号: C10G45/08 , B01J21/04 , B01J23/75 , B01J23/755 , B01J23/88 , B01J23/882 , B01J23/883 , B01J27/19 , B01J31/02 , B01J31/0201 , B01J31/0235 , B01J35/026 , B01J35/1019 , B01J35/1042 , B01J35/1066 , B01J37/0203 , B01J37/0207 , C10G45/06 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/1088 , C10G2300/301
摘要: A composition having a substantial or material absence of or no phosphorous and comprising a support material, a metal compound and either a hydrocarbon oil or a polar additive or a combination of both a hydrocarbon oil and polar additive. The polar additive has particularly defined properties including having a dipole moment of at least 0.45. The composition is useful in the hydroprocessing of hydrocarbon feedstocks, and it is especially useful in the hydrotreating of vacuum gas oils and petroleum resid feedstocks.
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公开(公告)号:US09856422B2
公开(公告)日:2018-01-02
申请号:US13989154
申请日:2011-11-23
CPC分类号: C10G21/16 , C07C51/48 , C07C211/63 , C10G19/02 , C10G21/27 , C10G21/28 , C10G2300/1033 , C10G2300/104 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/203 , Y02P20/582 , C07C63/36
摘要: The present invention relates to a process for the removal of naphthenic acids from crude oils and crude oil distillates by use of supported basic ionic liquids.
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公开(公告)号:US09815750B2
公开(公告)日:2017-11-14
申请号:US14466444
申请日:2014-08-22
CPC分类号: C07C4/06 , B01J29/061 , B01J29/405 , B01J37/28 , B01J2229/37 , C07C2529/06 , C07C2529/40 , C07C2529/85 , C07C2529/87 , C10G2300/1033 , C10G2300/1044 , C10G2300/1048 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/301 , C10G2400/30
摘要: A catalyst for producing monocyclic aromatic hydrocarbons, used for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil having a 10 volume % distillation temperature of at least 140° C. and an end point temperature of not more than 400° C., wherein the catalyst contains a crystalline aluminosilicate, gallium and/or zinc, and phosphorus, the molar ratio between silicon and aluminum (Si/Al ratio) in the crystalline aluminosilicate is not more than 100, the molar ratio between the phosphorus supported on the crystalline aluminosilicate and the aluminum of the crystalline aluminosilicate (P/Al ratio) is not less than 0.01 and not more than 1.0, and the amount of gallium and/or zinc is not more than 1.2% by mass based on the mass of the crystalline aluminosilicate.
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公开(公告)号:US09765262B2
公开(公告)日:2017-09-19
申请号:US13429047
申请日:2012-03-23
申请人: Othman A. Taha , M. Rashid Khan
发明人: Othman A. Taha , M. Rashid Khan
CPC分类号: C10G11/187 , C10G11/05 , C10G2300/1059 , C10G2300/107 , C10G2300/301 , C10G2400/20 , G05B13/027 , G05B17/02
摘要: Petroleum oil is catalytically cracked by contacting oil with catalyst mixture consisting of a base cracking catalyst containing an stable Y-type zeolite and small amounts of rare-earth metal oxide, and an additive containing a shape-selective zeolite, in an FCC apparatus having a regeneration zone, a separation zone, and a stripping zone. Production of light-fraction olefins is maximized by applying appropriate process control, monitoring, and optimizing systems. Mathematical process models, including neural networks, statistical models and finite impulse models are used in conjunction with advanced controllers and optimizing routines to calculate optimal settings for various parameters. Process model and historical data to test a predictive system can provide early warning of potential performance degradation and equipment failure in the FCC unit, decreasing overall operating costs and increasing plant safety.
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公开(公告)号:US09701914B2
公开(公告)日:2017-07-11
申请号:US11983078
申请日:2007-11-07
申请人: M. Rashid Khan , Othman A. Taha
发明人: M. Rashid Khan , Othman A. Taha
CPC分类号: C10G11/187 , B01J23/10 , B01J29/084 , B01J29/40 , B01J29/80 , C10G11/05 , C10G2300/1033 , C10G2300/1044 , C10G2300/1059 , C10G2300/1074 , C10G2300/4006 , C10G2300/4081 , C10G2400/20 , G05D21/02
摘要: With an aim to optimize propylene production, petroleum oil such as gas oil is catalytically cracked by contacting the oil with catalyst mixture consisting of a base cracking catalyst containing an stable Y-type zeolite and small amounts of rare-earth metal oxide, and an additive containing a shape-selective zeolite, in a down-flow type fluid catalytic cracking apparatus having a regeneration zone, a separation zone, and a stripping zone, wherein conversion of hydrocarbon occurs under relatively severe conditions. According to this fluid catalytic cracking process, the production of light-fraction olefins such as propylene is maximized by applying appropriate process control, monitoring, and optimizing systems. Process model and historical data to test a predictive system can provide early warning of potential performance degradation and equipment failure in the FCC unit.
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公开(公告)号:US09644156B2
公开(公告)日:2017-05-09
申请号:US15082717
申请日:2016-03-28
IPC分类号: C10G67/12 , C10G67/04 , C10G67/06 , C10G67/14 , C10G69/14 , C10G27/04 , C10G45/02 , C10G67/16 , C10G27/12 , C10G45/08
CPC分类号: C10G67/14 , C10G27/04 , C10G27/12 , C10G45/02 , C10G45/08 , C10G67/16 , C10G69/14 , C10G2300/1055 , C10G2300/1059 , C10G2300/202 , C10G2400/04
摘要: Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A first fraction contains refractory organosulfur compounds, which boil at or above the target cut point temperature. A second fraction boiling below the target cut point temperature is substantially free of refractory sulfur-containing compounds. The second fraction is contacted with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. The first fraction is contacted with an oxidizing agent and an active metal catalyst in an oxidation reaction zone to convert the refractory organosulfur compounds to oxidized organosulfur compounds. The oxidized organosulfur compounds are removed, producing a stream containing an ultra-low level of organosulfur compounds. The two streams can be combined to obtain a full range hydrocarbon product having an ultra-low level of organosulfur compounds.
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公开(公告)号:US09617485B2
公开(公告)日:2017-04-11
申请号:US14481952
申请日:2014-09-10
发明人: Hasan Dindi , Thanh Gia Ta , Vincent Adam Kuperavage, Jr. , Alan Howard Pulley , Scott Louis Webster
CPC分类号: C10G65/12 , C10G45/02 , C10G45/08 , C10G47/00 , C10G47/06 , C10G47/20 , C10G47/36 , C10G2300/1059 , C10G2300/802 , C10G2400/04
摘要: A process for the hydroprocessing of a gas oil (GO) hydrocarbon feed to provide high yield of a diesel fraction. The process comprises a liquid-full hydrotreating reaction zone followed by a liquid-full hydrocracking reaction zone. A refining zone may be integrated with the hydrocracking reaction zone. Ammonia and other gases formed during the hydrotreatment are removed in a separation step prior to hydrocracking.
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