公开(公告)号：US11517963B2

公开(公告)日：2022-12-06

申请号：US17039472

申请日：2020-09-30

申请人： Shoei Chemical Inc.

发明人： Patrick Haben

IPC分类号： C01B19/04 ,  B22F9/24 ,  B22F1/16 ,  B22F1/054 ,  C01B19/00 ,  B82Y30/00 ,  B82Y40/00

摘要： In a method for producing nanoparticles of copper selenide, a flowable copper precursor is formed by combining a copper starting material and a ligand, and a flowable selenium precursor is formed by suspending a selenium starting material in a liquid. Then a flowable copper-selenium mixture including a lower-polarity solvent is formed by combining the flowable copper precursor and the flowable selenium precursor. The flowable copper-selenium mixture is conducted through at least one heating unit, and the nanoparticles of copper selenide are isolated in an oxygen-depleted environment. The isolation includes combining a solution containing the nanoparticles of copper selenide and a deoxygenated, higher-polarity solvent to precipitate the nanoparticles.

公开(公告)号：US10557215B2

公开(公告)日：2020-02-11

申请号：US15859955

申请日：2018-01-02

申请人： JX NIPPON MINING & METALS CORPORATION

发明人： Kouji Murakami ,  Akira Noda

IPC分类号： C30B29/48 ,  C30B33/02 ,  C01B19/04 ,  C30B11/02

摘要： Provided are a high resistance CdTe-based compound single crystal with miniaturized Te precipitates and a method for producing the same. According to one embodiment of the present invention, a CdTe based compound single crystal is provided including a precipitate having a particle size of less than 0.1 μm obtained from an analysis by a light scattering tomography method. In the CdTe based compound single crystal, resistivity may be 1×107 Ωcm or more. In addition, in the CdTe based compound single crystal, a precipitate having a particle size of 0.1 μm or more obtained from the analysis by the light scattering tomography method is not detected. In the CdTe based compound single crystal, the precipitate may be a Te precipitate.

公开(公告)号：US20180370800A1

公开(公告)日：2018-12-27

申请号：US16015582

申请日：2018-06-22

申请人： Nanosys, Inc.

发明人： Austin SMITH ,  David OLMEIJER ,  Jared LYNCH ,  Minghu TU ,  Charles HOTZ

IPC分类号： C01B25/08 ,  C01B19/04 ,  G02F1/015 ,  H01L33/06 ,  H01L51/50 ,  C08L63/00 ,  C08L81/02 ,  C08L75/04 ,  C08K5/3432

摘要： The present disclosure provides nanostructure compositions and methods of producing nanostructure compositions. The nanostructure compositions comprise at least one population of nanostructures, at least one reactive diluent, at least one anaerobic stabilizer, and optionally at least one organic resin. The present disclosure also provides nanostructure films comprising a nanostructure layer and methods of making nanostructure films.

公开(公告)号：US10099938B2

公开(公告)日：2018-10-16

申请号：US14567900

申请日：2014-12-11

申请人： Samsung Electronics Co., Ltd.

发明人： Yoon Chul Son ,  Byungki Ryu ,  Sang Mock Lee

IPC分类号： C01B19/00 ,  C01B19/04 ,  H01B1/08 ,  H01B1/10 ,  C01G23/04 ,  H01L31/0224 ,  H01L51/52

摘要： According to example embodiments, a transparent electrically conductive film including a compound that has a two-dimensional electron gas layer, and has a product of an absorption coefficient (α) for light having a wavelength of about 550 nm at 25° C. and a resistivity value (ρ) thereof of less than or equal to about 30 Ω/sq is provided. The electrically conductive film may be a layered crystal structure of the compound.

公开(公告)号：US10053364B2

公开(公告)日：2018-08-21

申请号：US14832385

申请日：2015-08-21

申请人： Sunshine PV Corporation

发明人： William Weijen Hou ,  Sheng Han Li ,  Tzu Pin Chen

IPC分类号： C01B19/04 ,  C01B19/00 ,  B05D3/00 ,  B05D7/00 ,  H01L31/032 ,  H01L31/18 ,  H01L21/02

CPC分类号： C01B19/04 ,  B05D3/007 ,  B05D7/50 ,  C01B19/007 ,  H01L21/02422 ,  H01L21/02491 ,  H01L21/0256 ,  H01L21/02562 ,  H01L21/02568 ,  H01L21/02614 ,  H01L21/02667 ,  H01L31/0322 ,  H01L31/0326 ,  H01L31/1828 ,  H01L31/1836 ,  H01L31/1872 ,  Y02E10/541 ,  Y02E10/543 ,  Y02P70/521

摘要： The present invention provides a heat treatment method, particularly a heat treatment method in which a protective layer is directly applied onto a precursor to ensure that the precursor on each portion of the substrate is treated based on substantially the same conditions so that the quality of the prepared product layer is improved. The method of the present invention comprises: (1) providing a substrate; (2) applying a precursor onto the surface of the substrate; (3) covering the precursor-applied substrate with a protective layer to bring the substrate and the protective layer into direct contact; (4) placing the substrate obtained from step (3) into a heat chamber for heat treatment; and (5) removing the protective layer. A product prepared by said heat treatment method is also provided.

公开(公告)号：US20180142109A1

公开(公告)日：2018-05-24

申请号：US15816574

申请日：2017-11-17

申请人： Saint Louis University

发明人： Irma KULJANISHVILI ,  Rui DONG ,  Logan MOORE

IPC分类号： C09D11/037 ,  C01G39/06 ,  C01G41/00 ,  C01B19/04 ,  C23C14/22

CPC分类号： C09D11/037 ,  C01B19/04 ,  C01G39/006 ,  C01G39/06 ,  C01G41/00 ,  C01G41/006 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/04 ,  C01P2004/62 ,  C23C14/22 ,  C23C16/30

摘要： The present disclosure provides methods of preparing heterostructures of two or more transition metal dichalcogenides on a surface in a pattern in which the method does not require a mask or blocking agent to create a pattern on the surface. Also provided herein are ink compositions which are used in the methods described herein and include precursor materials that generate these transition metal dichalcogenides.

公开(公告)号：US20170288225A1

公开(公告)日：2017-10-05

申请号：US15450961

申请日：2017-03-06

申请人： SUMITOMO RUBBER INDUSTRIES, LTD. ,  NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

发明人： Tatsuya KUBO ,  Akihiro YAMANO ,  Naoto YAMASHITA ,  Masahiro YANAGIDA

IPC分类号： H01M4/58 ,  H01M4/62 ,  H01M4/04 ,  C01B17/20 ,  C08J3/24 ,  C01B17/42 ,  C01B17/22 ,  C01G49/12 ,  C01B19/04 ,  H01M10/0525 ,  C01G9/08

CPC分类号： H01M4/5815 ,  C01B17/20 ,  C01B17/22 ,  C01B17/42 ,  C01B19/04 ,  C01G9/08 ,  C01G49/12 ,  C08J3/247 ,  C08J2309/00 ,  H01M4/0471 ,  H01M4/1397 ,  H01M4/362 ,  H01M4/62 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/028

摘要： An object of the present invention is to provide a novel sulfur-based positive electrode active material for a lithium-ion secondary battery which is excellent in cyclability and can largely improve a charging and discharging capacity, a positive electrode comprising the positive electrode active material and a lithium-ion secondary battery made using the positive electrode. The sulfur-based positive electrode active material is obtainable by subjecting a starting material comprising a polymer, sulfur and an organometallic compound dispersed in a form of fine particles to heat-treatment under a non-oxidizing atmosphere, wherein the particles of metallic sulfide resulting from sulfurization of the organometallic compound are dispersed in the heat-treated material, and particle size of the metallic sulfide particles is not less than 10 nm and less than 100 nm.

公开(公告)号：US09650248B2

公开(公告)日：2017-05-16

申请号：US15176313

申请日：2016-06-08

申请人： Toyota Motor Engineering & Manufacturing North America, Inc. ,  The University of Manitoba

发明人： Michael Paul Rowe ,  Elizabeth Marie Skoropata ,  Johan Alexander van Lierop

IPC分类号： C01B6/04 ,  H01F3/00 ,  C01B6/23 ,  C01B19/04 ,  C01B6/21 ,  H01F1/03

CPC分类号： C01B6/23 ,  C01B6/21 ,  C01B19/04 ,  H01F1/0311 ,  H01F3/00

摘要： Reagent complexes have two or more elements, formally in oxidation state zero, complexed with a hydride molecule. Complexation with the hydride molecule may be evidenced by shifts to lower binding energies, of one or more electrons in each of the two or more elements, as observed by x-ray photoelectron spectroscopy. The reagents can be useful for the synthesis of multi-element nanoparticles. Preparation of the reagents can be achieved by ball-milling a mixture that includes powders of two or more elements and a hydride molecule.

公开(公告)号：US09393539B2

公开(公告)日：2016-07-19

申请号：US14130333

申请日：2012-07-02

申请人： Yadong Yin ,  Zhenda Lu

发明人： Yadong Yin ,  Zhenda Lu

IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J25/00 ,  B01J29/00 ,  B01J31/00 ,  B01J13/22 ,  B82Y30/00 ,  C01B33/18 ,  C01B19/04 ,  C01F17/00 ,  C01G49/08 ,  C09C1/24

CPC分类号： B01J13/22 ,  B82Y30/00 ,  C01B19/04 ,  C01B33/18 ,  C01F17/0031 ,  C01G49/08 ,  C01P2002/82 ,  C01P2002/84 ,  C01P2004/04 ,  C01P2004/32 ,  C09C1/24

摘要： A process that allows convenient production of multifunctional composite particles by direct self-assembly of hydrophobic nanoparticles on host nanostructures containing high density surface thiol groups is present. Hydrophobic nanoparticles of various compositions and combinations can be directly assembled onto the host surface through the strong coordination interactions between metal cations and thiol groups. The resulting structures can be further conveniently overcoated with a layer of normal silica to stabilize the assemblies and render them highly dispersible in water for biomedical applications. As the entire fabrication process does not involve complicated surface modification procedures, the hydrophobic ligands on the nanoparticles are not disturbed significantly so that they retain their original properties such as highly efficient luminescence. Multifunctional nonspherical nanostructures can be produced by using mercapto-silica coated nano-objects of arbitrary shapes as hosts for immobilizing functional nanoparticles. Multilayer structures can be achieved by repeating the mercapto-silica coating and nanoparticle immobilization processes.

摘要翻译： 存在通过在包含高密度表面硫醇基团的主体纳米结构上直接自组装疏水性纳米粒子来方便地生产多功能复合颗粒的方法。 各种组合物和组合的疏水性纳米颗粒可以通过金属阳离子和硫醇基团之间的强配位相互作用直接组装到宿主表面上。 所得到的结构可以进一步方便地用一层普通二氧化硅涂覆，以稳定组件并使其高度分散在用于生物医学应用的水中。 由于整个制造过程不涉及复杂的表面改性方法，所以纳米颗粒上的疏水性配体不会受到明显的干扰，因此它们保留了它们的初始特性，如高效发光。 可以通过使用任意形状的巯基二氧化硅涂覆的纳米物体作为固定功能性纳米粒子的主体来制备多功能非球形纳米结构。 可以通过重复巯基二氧化硅涂层和纳米颗粒固定方法来实现多层结构。

公开(公告)号：US20160097140A1

公开(公告)日：2016-04-07

申请号：US14872731

申请日：2015-10-01

申请人： CORNELL UNIVERSITY

发明人： Richard D. Robinson ,  Obafemi Otelaja

IPC分类号： C25D13/02 ,  C25D3/22 ,  C25D3/30 ,  C01G3/12 ,  C25D3/26 ,  C25D3/34 ,  C25D3/54 ,  C01B19/04 ,  C25D13/12 ,  C25D3/12

CPC分类号： C25D13/02 ,  C01B19/007 ,  C01G3/12 ,  C01P2002/72 ,  C01P2002/85 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2006/40 ,  C01P2006/80 ,  C25D13/12

摘要： A facile room-temperature method for assembling colloidal copper sulfide (Cu2-xS) nanoparticles into highly electrically conducting calcogenide material layer films utilizes ammonium sulfide for connecting the nanoparticles, while simultaneously effecting templating surfactant ligand removal. The foregoing process steps transform an as-deposited insulating films into a highly conducting films (i.e., having a conductivity at least about 75 S·cm−1). The methodology is anticipated as applicable to copper chalcogenides other than copper sulfide, as well as metal chalcogenides other than copper chalcogenides. The comparatively high conductivities reported are attributed to better interparticle coupling through the ammonium sulfide treatment. This approach presents a scalable room temperature route for fabricating comparatively highly conducting nanoparticle assemblies for large area electronic and optoelectronic applications.

摘要翻译： 将胶体硫化铜（Cu2-xS）纳米粒子组装成高导电性的化学物质层膜的简便的室温方法利用硫化铵连接纳米粒子，同时进行模板表面活性剂配体去除。 上述工艺步骤将沉积的绝缘膜转变成高导电膜（即，具有至少约75S·cm-1的导电率）。 该方法预期适用于硫化铜以外的硫属硫族化物，以及除硫属硫族化物以外的金属硫族化物。 报告的较高电导率归因于通过硫化铵处理的更好的颗粒间偶联。 该方法提供了用于制造用于大面积电子和光电子应用的相对高导电性纳米颗粒组件的可扩展室温路线。