摘要:
The present invention is concerned with novel polar solvents and novel electrolytic compositions comprising such solvents, and having a high range of stability, as required for applications in the field of electrochemistry. The present solvents have a highly polar amide function, and preferably combine with a salt soluble in the solvent and having an anion with a delocalized charge, and at least one polymer, to form an electrolytic composition.
摘要:
The invention relates to ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention includes an anionic portion combined with at least one cationic portion Mm+ in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic load is carried by a pentacyclical nucleus of tetrazapentalene derivative bearing electroattractive substituents. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorant, and the catalysis of various chemical reactions.
摘要:
The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine, a modified olivine, or the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.
摘要:
The invention concerns novel ionic compounds with low melting point whereof the onium type cation having at least a heteroatom such as N, O, S or P bearing the positive charge and whereof the anion includes, wholly or partially, at least an ion imidide such as (FX1O)N−(OX2F) wherein X1 and X2 are identical or different and comprise SO or PF, and their use as solvent in electrochemical devices. Said composition comprises a salt wherein the anionic charge is delocalised, and can be used, inter alia, as electrolyte.
摘要:
The present invention describes the synthesis of new fluorinated elastomers with very low glass transition temperatures (Tg), a good resistance to bases, gasoline and other carburants and good workability properties, these elastomers contain hexafluoropropene (HFP), perfluoro(4-methyl-3,6-dioxaoct-7-ene) sulfonyl fluoride (PFSO2F), vinylidene fluoride (VDF) and/or at least one fluorinated alkene and/or one vinyl perfluorinated ether. In a precise case, they are prepared by radical polymerisation of HFP and PFSO2F or by radical terpolymerisation HFP, PFSO2F and VDF in the presence of different organic initiator, such as peroxides, peresters or diazo compounds.
摘要:
Process for the preparation of electrodes from a porous material making it possible to obtain electrodes that are useful in electrochemical systems and that have at least one of the following properties: a high capacity in mnAh/gram, a high capaciaty in mAh/liter, a good capacity for cycling, a low rate of self discharge, and a good environmental tolerance.
摘要:
The present invention concerns electrode materials capable of redox reactions by electrons and alkaline ions exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, super capacitors and light modulating system of the super capacitor type.
摘要:
The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine, a modified olivine, or the rhombohedral NASICON structure and the polyanion (PO4)3− as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.
摘要翻译:本发明涉及用作碱离子二次(可再充电)电池,特别是锂离子电池中的电极的材料。 本发明提供了具有有序橄榄石,改性橄榄石或菱方NASICON结构的过渡金属化合物和作为至少一种成分的聚阴离子(PO 3 SO 3)3 - 用作碱电池可充电电池的电极材料。
摘要:
The invention relates to an ionic compound corresponding to the formula [R1X1(Z1)-Q−X2(Z2)—R2]m Mm+ in which Mm+ is a cation of valency m, each of the groups Xi is S=Z3, S=Z4, P—R3 or P—R4; Q is N, CR5, CCN or CSO2R5, each of the groups Zi is ═O, ═NC≡N, ═C(C≡N)2, ═NS(=Z)2R6 or ═C[S(=Z)2R6]2, each of the groups Ri, is Y, YO—, YS—, Y2N— or F, Y represents a monovalent organic radical or alternatively Y is a repeating unit of a polymeric frame. The compounds are useful for producing ion conducting materials or electrolytes, as catalysts and for doping polymers.
摘要翻译:本发明涉及对应于下式的离子化合物:其中R 1,R 2,R 2,R 3, > X 2(Z 2) - R 2 - - - - - (2)]]>其中m + 其中M +是阳离子的阳离子,每个基团X 1是S = Z 3,S = Z 4 PR 3,PR 3,PR 4,PR 3, Q是N,CR 5,CCN或CSO 2 R 5,每个基团Z 1是 - O,-NC≡N,-C(C≡N)2,-NS(= Z)2 R 6或-C [ S(= Z)2个基团,其中每个基团R i是Y,YO - ,YS-,Y 2 N或F,Y表示一价有机基团,或者Y是聚合物框架的重复单元。 这些化合物可用于生产离子导电材料或电解质,作为催化剂和掺杂聚合物。