COBALT CATALYSTS
    97.
    发明申请
    COBALT CATALYSTS 有权
    钴催化剂

    公开(公告)号:US20110054048A1

    公开(公告)日:2011-03-03

    申请号:US12942551

    申请日:2010-11-09

    IPC分类号: C07C1/04 C07C209/48 C07C27/04

    摘要: Catalysts comprising cobalt on a titania support are produced by mixing together particles of a solid titania support and an aqueous solution of cobalt ammine carbonate, and heating to an elevated temperature sufficient to effect decomposition of the cobalt ammine carbonate and precipitation of a cobalt species onto said support. The catalysts are useful in hydrogenation and Fischer-Tropsch reactions.

    摘要翻译: 包含二氧化钛载体上的钴的催化剂通过将固体二氧化钛载体的颗粒和碳酸氨铜的水溶液混合在一起并加热到足以实现碳酸钴铵分解的高温并将钴物质沉淀到所述 支持。 催化剂可用于氢化和费 - 托反应。

    Catalysts
    98.
    发明申请
    Catalysts 有权
    催化剂

    公开(公告)号:US20110028575A1

    公开(公告)日:2011-02-03

    申请号:US12937491

    申请日:2009-04-03

    IPC分类号: C07C1/04 B01J31/04

    摘要: A process for preparing a cobalt based Fischer-Tropsch synthesis catalyst precursor includes introducing a multi-functional carboxylic acid having the general formula (1) HOOC—C*R1C*R2—COOH (1) or a precursor thereof, where C* in each of C*Ri and C*R2 is a sp2 carbon, and R1 and R2 are the same or different, and are each selected from the group consisting of hydrogen and an organic group, into and/or onto a particulate catalyst support. The ratio of the quantity of multifunctional carboxylic acid used relative to the support surface area is at least 0.3 μmol carboxylic acid/m2 of support surface area. Simultaneously with the introduction of the carboxylic acid into and/or onto the catalyst support, or subsequent thereto, a cobalt compound is introduced into and/or onto the catalyst support. The impregnated support is calcined to obtain the cobalt based Fischer-Tropsch synthesis catalyst precursor.

    摘要翻译: 一种制备钴基费 - 托合成催化剂前体的方法包括引入具有通式(1)HOOC-C * R1C * R2-COOH(1)或其前体的多官能羧酸,其中C C * R 1和C * R 2是sp 2碳,并且R 1和R 2相同或不同,并且各自选自氢和有机基团,并且在颗粒催化剂载体上和/或之上。 所使用的多官能羧酸的量相对于载体表面积的比例为至少0.3μmol羧酸/ m2的载体表面积。 在将羧酸引入催化剂载体或/或其后的同时,将钴化合物引入催化剂载体和/或催化剂载体上。 将浸渍的载体煅烧以获得基于钴的费 - 托合成催化剂前体。