Dehydrogenation Catalyst for Formic Acid, Method for Producing Hydrogen, and Method for Producing Deuterium Gas or Deuterated Hydrogen
    20.
    发明申请
    Dehydrogenation Catalyst for Formic Acid, Method for Producing Hydrogen, and Method for Producing Deuterium Gas or Deuterated Hydrogen 有权
    甲酸脱氢催化剂,生产氢气的方法,以及氘气或氘化氢的制备方法

    公开(公告)号:US20150166337A1

    公开(公告)日:2015-06-18

    申请号:US14374012

    申请日:2013-01-25

    摘要: To provide a catalyst for dehydrogenation of formic acid which allows hydrogen, heavy hydrogen gas or heavy-hydrogenated hydrogen containing no carbon monoxide to be produced through dehydrogenation of formic acid in a highly efficient manner.A catalyst for dehydrogenation of formic acid, including: a multinuclear metal complex represented by the following Formula (1), a tautomer or stereoisomer thereof, or a salt thereof, where M1 and M2 denote transition metals and may be the same as or different from each other; Q1 to Q6 each independently denote carbon or nitrogen; R1 to R6 each independently denote, for example, a hydrogen atom, an alkyl group, a phenyl group, a nitro group, a halogen group, a sulfonate group (sulfo group); L1 and L2 each independently denote an aromatic anionic ligand or an aromatic ligand, and may be substituted by one or more substituents; Y1 and Y2 each independently denote any ligand or are absent; and m denotes a positive integer, 0, or a negative integer.

    摘要翻译: 提供甲酸脱氢催化剂,其允许通过以高效的方式使甲酸脱氢生产氢,重氢气或不含一氧化碳的重氢氢。 一种用于甲酸脱氢的催化剂,包括:由下式(1)表示的多核金属络合物,其互变异构体或立体异构体或其盐,其中M1和M2表示过渡金属,并且可以相同或不同 彼此; Q1至Q6各自独立地表示碳或氮; R 1〜R 6各自独立地表示例如氢原子,烷基,苯基,硝基,卤素基,磺酸酯基(磺基)等。 L1和L2各自独立地表示芳族阴离子配体或芳族配体,并且可以被一个或多个取代基取代; Y1和Y2各自独立地表示任何配体或不存在; m表示正整数,0表示负整数。