Method for Regenerating Semi-Regenerated Reforming Catalyst
    11.
    发明申请
    Method for Regenerating Semi-Regenerated Reforming Catalyst 有权
    再生半再生催化剂的再生方法

    公开(公告)号:US20160279626A1

    公开(公告)日:2016-09-29

    申请号:US15081234

    申请日:2016-03-25

    Abstract: A method for regenerating semi-regenerated reforming catalyst comprises adjusting the reaction temperature to 250-480° C.; introducing sulfur-containing naphtha into the reforming reactor, so that the sulfur content in the catalyst is 0.32-0.8 mass %; then stopping introducing the raw materials into the reforming reactor; subjecting the catalyst to coke-burning, oxychlorination and reduction. Another method for regenerating semi-regenerated reforming catalyst comprises coke-burning the spent catalyst; introducing sulfate ions thereinto; then performing oxychlorination and reduction. There is still another method for regenerating a platinum-rhenium reforming catalyst, comprising coke-burning the spent catalyst; introducing sulfur and chlorine by impregnation; then drying, calcinating and reducing. The catalysts regenerated by said methods can be used without presulfurization and have excellent regeneration performance.

    Abstract translation: 再生再生重整催化剂的方法包括将反应温度调节至250-480℃; 将含硫的石脑油引入重整反应器中,使得催化剂中的硫含量为0.32-0.8质量%; 然后停止将原料引入重整反应器; 对催化剂进行焦烧,氧氯化和还原。 再生再生重整催化剂的另一种方法包括焦炭燃烧废催化剂; 向其中引入硫酸根离子; 然后进行氧氯化和还原。 还有另一种再生铂 - 铼重整催化剂的方法,包括焦炭燃烧废催化剂; 通过浸渍引入硫和氯; 然后干燥,煅烧和还原。 通过所述方法再生的催化剂可以在没有预硫化的情况下使用并且具有优异的再生性能。

    PROCESS FOR PREPARING A SPENT CATALYST FOR PRECIOUS METALS RECOVERY
    14.
    发明申请
    PROCESS FOR PREPARING A SPENT CATALYST FOR PRECIOUS METALS RECOVERY 有权
    制备用于重金属回收的催化剂的方法

    公开(公告)号:US20160115566A1

    公开(公告)日:2016-04-28

    申请号:US14521195

    申请日:2014-10-22

    Abstract: A process is provided for preparing a spent noble metal fixed-bed catalyst for precious metals recovery, comprising: a) adding the catalyst to a caustic solution to wash the spent catalyst and to make a wash slurry having an alkaline pH, wherein the spent catalyst has been in contact with chloroaluminate ionic liquid catalyst, and wherein the spent catalyst comprises from 5 to 35 wt % chloride; and b) filtering the wash slurry and collecting: i) a filter cake having from at least 70 wt % of the chloride in the spent catalyst removed and having the noble metals retained, and ii) a wash filtrate. Also provided is a filter cake comprising a washed consolidated cake having 40 to 75 wt % solids, a cake moisture content from 25 to less than 60 wt %, 0.1 to 1.5 wt % total noble metals, and a residual chloride content of from zero to less than 4 wt %.

    Abstract translation: 提供了一种制备用于贵金属回收的废贵金属固定床催化剂的方法,包括:a)将催化剂加入苛性碱溶液中以洗涤废催化剂并制备具有碱性pH的洗涤浆液,其中废催化剂 已经与氯铝酸盐离子液体催化剂接触,并且其中废催化剂包含5至35重量%的氯化物; 和b)过滤洗涤浆液并收集:i)从除去的废催化剂中除去至少70重量%的氯化物并且保留贵金属的滤饼,和ii)洗涤滤液。 还提供了一种滤饼,其包括洗涤的固结滤饼,其具有40至75重量%的固体,饼状水分含量为25至小于60重量%,总贵金属为0.1至1.5重量%,残留氯含量为0至 小于4重量%。

    PROCESSES FOR THE CONTINUOUS REGENERATION OF A CATALYST
    15.
    发明申请
    PROCESSES FOR THE CONTINUOUS REGENERATION OF A CATALYST 有权
    连续再生催化剂的方法

    公开(公告)号:US20150290636A1

    公开(公告)日:2015-10-15

    申请号:US14252237

    申请日:2014-04-14

    Applicant: UOP LLC

    Abstract: A process for regenerating a catalyst used in a reaction zone. In a regeneration zone, the catalyst may be cooled before passing into a chloride rich zone. The regeneration zone may also receive a heated ambient oxygen in a catalyst heating zone. The regeneration zone may also receive recovered chloride from a chloride recovering zone which removes and recovers chloride from regeneration gas taken from the regeneration zone. Heated ambient oxygen may also be introduced into a chlorination zone.

    Abstract translation: 用于再生反应区中使用的催化剂的方法。 在再生区中,催化剂可以在进入富氯化物区之前被冷却。 再生区也可以在催化剂加热区中接受加热的环境氧。 再生区还可以从氯化物回收区接收回收的氯化物,其从再生区取出并从再生气体中回收氯化物。 加热的环境氧也可以被引入氯化区。

    Process for producing acetic acid
    16.
    发明授权
    Process for producing acetic acid 有权
    生产乙酸的方法

    公开(公告)号:US09073843B2

    公开(公告)日:2015-07-07

    申请号:US13994275

    申请日:2011-12-01

    CPC classification number: C07C51/12 B01J23/464 B01J27/13 C07C51/44 C07C53/08

    Abstract: A process for producing acetic acid by: a reaction step for continuously allowing methanol to react with carbon monoxide in the presence of a catalyst system comprising a metal catalyst, an ionic iodide, and methyl iodide in a carbonylation reactor, a flash distillation step for continuously feeding a flasher with a reaction mixture from the reactor and evaporating a volatile component at least containing product acetic acid, methyl acetate, and methyl iodide by flash distillation to separate the volatile component and a liquid catalyst mixture at least containing the metal catalyst and the ionic iodide, and an acetic acid collection step for separating a stream containing acetic acid from the volatile component to collect acetic acid; wherein, in the flash distillation step, the flash distillation is conducted under the condition that the concentration of methyl acetate in the liquid catalyst mixture is not less than 0.6% by weight.

    Abstract translation: 一种生产乙酸的方法,该方法是:在羰基化反应器中,在包含金属催化剂,离子碘化物和甲基碘的催化剂体系的存在下,连续使甲醇与一氧化碳反应的反应步骤,连续的闪蒸步骤 用来自反应器的反应混合物进料闪蒸器并通过闪蒸蒸发至少含有产物乙酸,乙酸甲酯和甲基碘的挥发性组分,以分离挥发性组分和至少含有金属催化剂和离子的液体催化剂混合物 碘化物和乙酸收集步骤,用于从含挥发性成分中分离含有乙酸的物流以收集乙酸; 其中,在闪蒸步骤中,在液体催化剂混合物中乙酸甲酯的浓度不小于0.6重量%的条件下进行闪蒸。

    Selective hydrogenation catalyst and methods of making and using same
    17.
    发明授权
    Selective hydrogenation catalyst and methods of making and using same 有权
    选择性氢化催化剂及其制备和使用方法

    公开(公告)号:US08633127B2

    公开(公告)日:2014-01-21

    申请号:US12710781

    申请日:2010-02-23

    Abstract: A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

    Abstract translation: 一种包含负载氢化催化剂的组合物,其包含钯和有机磷化合物,所述负载氢化催化剂能够将高度不饱和烃选择性氢化为不饱和烃。 一种制备选择性氢化催化剂的方法,包括使载体与含钯​​化合物接触以形成负载钯的组合物,使钯负载的组合物与有机磷化合物接触以形成催化剂前体,还原催化剂前体以形成催化剂。 将高度不饱和烃选择性氢化为不饱和烃富集组合物的方法,包括在适于氢化至少一部分高度不饱和烃进料的条件下使包含钯和有机磷化合物的负载催化剂与包含高度不饱和烃的进料接触以形成 不饱和烃富集组合物。

    DIRECT CONVERSION OF OLEFIN TO OLEFIN OXIDE BY MOLECULAR OXYGEN
    18.
    发明申请
    DIRECT CONVERSION OF OLEFIN TO OLEFIN OXIDE BY MOLECULAR OXYGEN 有权
    通过分子氧直接转化烯烃到氧化烯

    公开(公告)号:US20130296586A1

    公开(公告)日:2013-11-07

    申请号:US13979393

    申请日:2012-01-18

    CPC classification number: B01J27/13 B01J27/0576 C07D301/03 C07D301/08

    Abstract: The present invention relates to a direct conversion of olefin to olefin oxide, which are important and versatile intermediates used in the production of a large variety of valuable consumer products such as polyurethane foams, polymers, alkylene glycol, cosmetics, food emulsifiers and as fumigants and insecticides. More specifically, the present invention provides a process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a halogen compound additive and a catalyst comprising copper, ruthenium or both thereof.

    Abstract translation: 本发明涉及烯烃直接转化为烯烃氧化物,其是用于生产大量有价值的消费品如聚氨酯泡沫,聚合物,亚烷基二醇,化妆品,食品乳化剂和作为熏蒸剂的重要且通用的中间体,以及 杀虫剂。 更具体地说,本发明提供了一种制备烯烃氧化物的方法,其包括在卤素化合物添加剂和包含铜,钌或其二者的催化剂的存在下使烯烃与氧反应。

    CATALYST FOR CONVERSION OF HYDROCARBONS
    20.
    发明申请
    CATALYST FOR CONVERSION OF HYDROCARBONS 有权
    碳氢化合物转化催化剂

    公开(公告)号:US20130261363A1

    公开(公告)日:2013-10-03

    申请号:US13547351

    申请日:2012-07-12

    Abstract: One embodiment is a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, an alkali or alkaline-earth metal, a lanthanide-series metal, and a support. Generally, an average bulk density of the catalyst is about 0.300 to about 1.00 gram per cubic centimeter. The catalyst has a platinum content of less than about 0.375 wt %, a tin content of about 0.1 to about 2 wt %, a potassium content of about 100 to about 600 wppm, and a cerium content of about 0.1 to about 1 wt %. The lanthanide-series metal can be distributed at a concentration of the lanthanide-series metal in a 100 micron surface layer of the catalyst less than two times a concentration of the lanthanide-series metal at a central core of the catalyst.

    Abstract translation: 一个实施方案是用于石脑油催化重整的催化剂。 催化剂可以具有包括铂,钯,铑,钌,锇和铱中的一种或多种的贵金属,碱金属或碱土金属,镧系金属和载体。 通常,催化剂的平均体积密度为约0.300至约1.00克/立方厘米。 催化剂的铂含量小于约0.375重量%,锡含量为约0.1至约2重量%,钾含量为约100至约600wppm,铈含量为约0.1至约1重量%。 镧系元素金属可以在催化剂的100微米表面层中以镧系元素金属的浓度分布,其量小于催化剂中心核心处的镧系金属浓度的两倍。

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