公开(公告)号：US20160220987A1

公开(公告)日：2016-08-04

申请号：US14870848

申请日：2015-09-30

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Wenyih F. Lai ,  Christine N. Elia ,  Jane C. Cheng ,  Shifang L. Luo ,  Hari Nair ,  Joshua I. Cutler ,  Doron Levin

IPC: B01J29/80 ,  C07C6/06 ,  B01J35/10

CPC classification number: B01J29/80 ,  B01J8/04 ,  B01J29/22 ,  B01J29/24 ,  B01J29/44 ,  B01J29/46 ,  B01J29/67 ,  B01J29/68 ,  B01J29/74 ,  B01J29/7446 ,  B01J29/7453 ,  B01J29/7461 ,  B01J29/7476 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/76 ,  B01J29/7646 ,  B01J29/7653 ,  B01J29/7661 ,  B01J29/7676 ,  B01J29/7684 ,  B01J29/7692 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1033 ,  B01J35/1052 ,  B01J35/108 ,  B01J37/0201 ,  B01J37/18 ,  B01J37/30 ,  B01J2208/027 ,  B01J2229/186 ,  B01J2229/42 ,  C01B39/265 ,  C07C4/18 ,  C07C6/126 ,  C07C15/06 ,  C07C2521/04 ,  C07C2529/18 ,  C07C2529/22 ,  C07C2529/24 ,  C07C2529/26 ,  C07C2529/40 ,  C07C2529/44 ,  C07C2529/46 ,  C07C2529/80 ,  C07C2529/87 ,  Y02P20/52

Abstract: Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a first zeolite having a constraint index of 3 to 12, a second zeolite comprising a mordenite zeolite synthesized from TEA or MTEA, at least one first metal of Group 10 of the IUPAC Periodic Table, and at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m2/g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

Abstract translation: 公开了一种催化剂组合物及其在用于转化含有C8 +芳族烃的原料以产生轻芳香族产物（包括苯，甲苯和二甲苯）的方法中的用途。 所述催化剂组合物包括约束指数为3至12的第一沸石，包含由TEA或MTEA合成的丝光沸石的第二沸石，IUPAC元素周期表第10族的至少一种第一金属和至少一种第 IUPAC周期表第11至15组，其中所述丝光沸石具有大于30m 2 / g的中孔表面积，并且所述丝光沸石包括由初级微晶构成的附聚物，其中所述初级晶体具有平均初晶尺寸， TEM小于80nm，纵横比小于2。

公开(公告)号：US20150017083A1

公开(公告)日：2015-01-15

申请号：US14379069

申请日：2013-02-14

Applicant: ECOCAT OY

Inventor： Teuvo Maunula

IPC: B01J23/10 ,  B01D53/86 ,  B01J27/24

CPC classification number: B01J23/10 ,  B01D53/8628 ,  B01D53/9418 ,  B01D53/9468 ,  B01D2255/2022 ,  B01D2255/2027 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/209 ,  B01D2255/30 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9025 ,  B01J23/002 ,  B01J23/02 ,  B01J23/30 ,  B01J27/053 ,  B01J27/24 ,  B01J29/061 ,  B01J29/088 ,  B01J29/126 ,  B01J29/146 ,  B01J29/166 ,  B01J29/405 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/655 ,  B01J29/67 ,  B01J29/68 ,  B01J29/69 ,  B01J29/7057 ,  B01J29/7415 ,  B01J29/7615 ,  B01J29/7815 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0246 ,  B01J2229/42 ,  B01J2523/00 ,  F01N3/106 ,  F01N3/2066 ,  F01N3/2892 ,  F01N13/0097 ,  F01N2240/20 ,  F01N2510/0684 ,  F01N2610/02 ,  Y02T10/24 ,  B01J2523/3706 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/48 ,  B01J2523/55 ,  B01J2523/69

Abstract: A catalyst coating for use in a hydrolysis catalyst (H-catalyst) for the reduction of nitrogen oxides, a manufacturing method for such a coating, a catalyst structure and its use are described. The H-catalyst includes alkaline compounds, which are capable of adsorbing HNCO and/or nitrogen oxides and which include alkali and alkaline earth metals, lanthanum and/or yttrium and/or hafnium and/or prasedium and/or gallium, and/or zirconium for promoting reduction, such as for promoting the hydrolysis of urea and the formation of ammonia and/or the selective reduction of nitrogen oxides.

Abstract translation: 描述了用于还原氮氧化物的水解催化剂（H-催化剂）的催化剂涂层，这种涂层的制造方法，催化剂结构及其用途。 所述H催化剂包括能够吸附HNCO和/或氮氧化物并且包括碱金属和碱土金属，镧和/或钇和/或铪和/或镨和/或镓和/或锆的碱性化合物 用于促进还原，例如用于促进尿素的水解和氨的形成和/或氮氧化物的选择性还原。

公开(公告)号：US08815763B2

公开(公告)日：2014-08-26

申请号：US13116087

申请日：2011-05-26

Applicant: Steven Bruce Dawes ,  Steven Bolaji Ogunwumi

Inventor： Steven Bruce Dawes ,  Steven Bolaji Ogunwumi

IPC: B01J29/04 ,  B01J29/064 ,  B01J29/072 ,  B01J29/18 ,  B01J29/24 ,  B01J29/40 ,  B01J29/46 ,  B01J29/65 ,  B01J29/68 ,  B01J37/02 ,  B01J29/72 ,  B01J29/85 ,  B01J29/06 ,  B01J37/00 ,  B01J37/08 ,  B01J23/745

CPC classification number: B01J29/072 ,  B01J23/745 ,  B01J29/061 ,  B01J29/24 ,  B01J29/46 ,  B01J29/68 ,  B01J29/7215 ,  B01J29/723 ,  B01J29/85 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/10 ,  B01J2229/42 ,  C07H19/16

Abstract: A method of manufacturing a catalyst body which includes: soaking at least part of a fired zeolite-based body in a transition metal oxide solution; removing the body from the transition metal oxide solution; exposing the body to a humidified atmosphere at one or more temperatures above 20° C.; then drying the body; and calcining the body.

Abstract translation: 一种催化剂体的制造方法，其特征在于，将过渡金属氧化物溶液中的至少一部分烧成的沸石类体系浸渍; 从过渡金属氧化物溶液中去除体; 在高于20℃的一个或多个温度下将身体暴露于潮湿的气氛中; 然后干燥身体; 并烧身体。

公开(公告)号：US20130149220A1

公开(公告)日：2013-06-13

申请号：US13525461

申请日：2012-06-18

Applicant: DANIEL SWALLOW ,  ANDREW FRANCIS CHIFFEY ,  PAUL RICHARD PHILLIPS

Inventor： DANIEL SWALLOW ,  ANDREW FRANCIS CHIFFEY ,  PAUL RICHARD PHILLIPS

IPC: B01D53/94

CPC classification number: B01J23/40 ,  B01D39/00 ,  B01D53/94 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/944 ,  B01D53/9472 ,  B01D53/9477 ,  B01D2255/102 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2258/012 ,  B01J23/002 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J23/63 ,  B01J23/6562 ,  B01J23/72 ,  B01J23/74 ,  B01J23/755 ,  B01J29/00 ,  B01J29/0333 ,  B01J29/0356 ,  B01J29/072 ,  B01J29/106 ,  B01J29/14 ,  B01J29/24 ,  B01J29/46 ,  B01J29/56 ,  B01J29/63 ,  B01J29/68 ,  B01J29/76 ,  B01J29/7615 ,  B01J29/763 ,  B01J29/7661 ,  B01J29/80 ,  B01J29/84 ,  B01J29/87 ,  B01J29/89 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0201 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/0248 ,  F01N3/035 ,  F01N3/0814 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/106 ,  F01N3/2073 ,  Y02A50/2341 ,  Y02T10/24 ,  Y10S502/52712 ,  B01J2523/00 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48

Abstract: An exhaust system, and a catalyzed substrate for use in an exhaust system, is disclosed. The exhaust system comprises a lean NO trap and the catalyzed substrate. The catalyzed substrate has a first zone, having a platinum group metal loaded on a support, and a second zone, having copper or iron loaded on a zeolite. The first zone or second zone additionally comprises a base metal oxide or a base metal loaded on an inorganic oxide. Also provided are methods for treating an exhaust gas from an internal combustion engine using the exhaust system. The exhaust system is capable of storing NH3 generated in rich purging, reacting the NH3 with slip NOX, controlling H2S released from NO trap desulfation, and oxidizing slip hydrocarbons and carbon monoxide. When the catalyzed substrate is a filter substrate, it is also capable of removing soot from exhaust system.

Abstract translation: 公开了一种排气系统和用于排气系统的催化底物。 排气系统包括贫NO阱和催化底物。 催化底物具有装载在载体上的铂族金属的第一区和负载在沸石上的铜或铁的第二区。 第一区域或第二区域另外包含负载在无机氧化物上的贱金属氧化物或贱金属。 还提供了使用排气系统处理来自内燃机的废气的方法。 排气系统能够储存丰富吹扫中产生的NH 3，使NH3与滑移NOX反应，控制从NO捕集器脱硫释放的H2S，以及氧化滑动烃和一氧化碳。 当催化底物是过滤基材时，它也能够从排气系统中除去烟尘。

公开(公告)号：US20110294655A1

公开(公告)日：2011-12-01

申请号：US13116087

申请日：2011-05-26

Applicant: Steven Bruce Dawes ,  Steven Bolaji Ogunwumi

Inventor： Steven Bruce Dawes ,  Steven Bolaji Ogunwumi

IPC: B01J37/08 ,  B01J37/10 ,  B01J35/04 ,  B01J29/18 ,  B01J29/65 ,  B01J29/04 ,  B01J29/40

CPC classification number: B01J29/072 ,  B01J23/745 ,  B01J29/061 ,  B01J29/24 ,  B01J29/46 ,  B01J29/68 ,  B01J29/7215 ,  B01J29/723 ,  B01J29/85 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/10 ,  B01J2229/42 ,  C07H19/16

Abstract: A method of manufacturing a catalyst body which includes: soaking at least part of a fired zeolite-based body in a transition metal oxide solution; removing the body from the transition metal oxide solution; exposing the body to a humidified atmosphere at one or more temperatures above 20° C.; then drying the body; and calcining the body.

Abstract translation: 一种催化剂体的制造方法，其特征在于，将过渡金属氧化物溶液中的至少一部分烧成的沸石类体系浸渍; 从过渡金属氧化物溶液中去除体; 在高于20℃的一个或多个温度下将身体暴露于潮湿的气氛中; 然后干燥身体; 并烧身体。

公开(公告)号：US20110056187A1

公开(公告)日：2011-03-10

申请号：US12991202

申请日：2009-04-18

Applicant: Michael Seyler ,  Nicola Soeger ,  Katja Adelmann ,  Gerald Jeske

Inventor： Michael Seyler ,  Nicola Soeger ,  Katja Adelmann ,  Gerald Jeske

IPC: F01N3/18

CPC classification number: B01D53/9418 ,  B01D53/945 ,  B01D2251/2062 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9205 ,  B01J29/072 ,  B01J29/68 ,  B01J35/04 ,  B01J37/0246 ,  F01N3/035 ,  F01N3/103 ,  F01N3/106 ,  F01N3/2066 ,  F01N13/0097 ,  F01N2370/04 ,  F01N2510/063 ,  F01N2610/02 ,  Y02T10/22 ,  Y02T10/24

Abstract: The invention relates to a process for treating diesel engine exhaust gases comprising nitrogen oxides (NOx) and hydrocarbons (HC) by selective catalytic reduction of the nitrogen oxides with ammonia or a compound decomposable to ammonia as a reducing agent over an SCR catalyst based on a molecular sieve. The properties of the catalyst used are such that the hydrocarbons present in the exhaust gas are kept away from the catalytically active sites in the catalyst over which the reactions take place by the molecular sieve-like action of the zeolite present in the catalyst. This prevents HC-related degradation and aging effects of the SCR catalyst and achieves a considerable improvement in nitrogen oxide conversions in HC-containing exhaust gas.

Abstract translation: 本发明涉及一种通过使用氨或可分解为氨的化合物作为还原剂的氮氧化物（NOx）和碳氢化合物（HC）来处理柴油机废气的方法，所述方法基于SCR催化剂，基于 分子筛。 使用的催化剂的性质使得存在于排气中的烃保留在催化剂中的催化活性位点，通过催化剂中存在的沸石的分子筛样作用发生反应。 这可防止SCR催化剂的HC相关的降解和老化作用，并且实现了含HC废气中氮氧化物转化率的显着提高。

公开(公告)号：US20100143224A1

公开(公告)日：2010-06-10

申请号：US12706655

申请日：2010-02-16

Applicant: Hong-Xin Li ,  William E. Cormier ,  Bjorn Moden

Inventor： Hong-Xin Li ,  William E. Cormier ,  Bjorn Moden

IPC: B01D53/56 ,  B01D53/92

CPC classification number: B01D53/8628 ,  B01D53/9418 ,  B01D2255/20738 ,  B01D2255/50 ,  B01D2258/012 ,  B01J29/146 ,  B01J29/166 ,  B01J29/24 ,  B01J29/26 ,  B01J29/46 ,  B01J29/48 ,  B01J29/68 ,  B01J29/69 ,  B01J29/7215 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/88 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J37/0246 ,  F01N3/0222 ,  Y02A50/2325 ,  Y02T10/20

Abstract: There is disclosed iron-containing aluminosilicate zeolites having both framework iron and iron cations on the ion-exchange sites. There is also disclosed a direct synthesis method of making an iron-containing aluminosilicate zeolite, which does not require the use of an intermediate step, such as ion-exchange or impregnation. In addition, there is disclosed a method of using the iron-containing aluminosilicate zeolite disclosed herein in a selective catalytic reduction reaction, typically in the presence of ammonia, to reduce or remove nitric oxides from exhaust emissions.

Abstract translation: 公开了在离子交换位点具有骨架铁和铁阳离子的含铁硅铝酸盐沸石。 还公开了制造含铁铝硅酸盐沸石的直接合成方法，其不需要使用中间步骤，例如离子交换或浸渍。 此外，公开了一种使用本文所公开的含铁硅铝酸盐沸石在选择性催化还原反应（通常在氨存在下）以从废气排放物中还原或除去一氧化氮的方法。

公开(公告)号：US07700512B2

公开(公告)日：2010-04-20

申请号：US11360391

申请日：2006-02-24

Applicant: Saeko Kurachi

Inventor： Saeko Kurachi

IPC: B01J29/068 ,  B01J29/44 ,  B01J29/67

CPC classification number: H01M8/0662 ,  B01J29/064 ,  B01J29/068 ,  B01J29/076 ,  B01J29/44 ,  B01J29/46 ,  B01J29/67 ,  B01J29/68 ,  C01B3/583 ,  C01B2203/044 ,  C01B2203/047 ,  H01M8/0668 ,  Y02P70/56

Abstract: A carbon monoxide selective oxidizing catalyst includes a carrier of ferrierite or ZSM-5 that supports a metal component of platinum (Pt) alone or platinum and at least one type of transition metal. Alternatively, a carbon monoxide selective oxidizing catalyst includes a carrier whose maximum pore diameter ranges from 0.55 to 0.65 nanometers (nm) that supports a metal component of platinum (Pt) alone or platinum and at least one type of transition metal.

Abstract translation: 一氧化碳选择氧化催化剂包括支持铂（Pt）或铂的金属组分和至少一种类型的过渡金属的镁碱沸石或ZSM-5的载体。 或者，一氧化碳选择氧化催化剂包括其最大孔径范围为0.55至0.65纳米（nm）的载体，其载体为铂（Pt）或铂的金属组分和至少一种类型的过渡金属。

公开(公告)号：US06716783B2

公开(公告)日：2004-04-06

申请号：US10321184

申请日：2002-12-17

Applicant: Kevin C. Ott ,  Noline C. Clark ,  Mark T. Paffett

Inventor： Kevin C. Ott ,  Noline C. Clark ,  Mark T. Paffett

IPC: B01J2906

CPC classification number: B01D53/9418 ,  B01D2251/2062 ,  B01D2251/208 ,  B01D2255/2073 ,  B01D2255/20746 ,  B01D2255/50 ,  B01J29/06 ,  B01J29/061 ,  B01J29/072 ,  B01J29/076 ,  B01J29/68 ,  B01J29/69 ,  B01J2229/16 ,  B01J2229/37 ,  B01J2229/38 ,  Y02T10/24

Abstract: The present invention provides a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material by contacting the gas stream under conditions effective to catalytically reduce the nitrogen oxides with a catalyst comprising a aluminum-silicate type material and a minor amount of a metal, the catalyst characterized as having sufficient catalytic activity so as to reduce the nitrogen oxides by at least 60 percent under temperatures within the range of from about 200° C. to about 400° C.

公开(公告)号：US20030165415A1

公开(公告)日：2003-09-04

申请号：US10321184

申请日：2002-12-17

Inventor： Kevin C. Ott ,  Noline C. Clark ,  Mark T. Paffett

IPC: B01D053/56 ,  B01J029/06 ,  B01J008/00

CPC classification number: B01D53/9418 ,  B01D2251/2062 ,  B01D2251/208 ,  B01D2255/2073 ,  B01D2255/20746 ,  B01D2255/50 ,  B01J29/06 ,  B01J29/061 ,  B01J29/072 ,  B01J29/076 ,  B01J29/68 ,  B01J29/69 ,  B01J2229/16 ,  B01J2229/37 ,  B01J2229/38 ,  Y02T10/24

Abstract: The present invention provides a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material by contacting the gas stream under conditions effective to catalytically reduce the nitrogen oxides with a catalyst comprising a aluminum-silicate type material and a minor amount of a metal, the catalyst characterized as having sufficient catalytic activity so as to reduce the nitrogen oxides by at least 60 percent under temperatures within the range of from about 200null C. to about 400null C.