Hydrothermally stable catalyst for improved lean NOx reduction
    15.
    发明授权
    Hydrothermally stable catalyst for improved lean NOx reduction 有权
    水热稳定的催化剂用于改善贫氧NOx的还原

    公开(公告)号:US06645448B2

    公开(公告)日:2003-11-11

    申请号:US09982583

    申请日:2001-10-18

    Abstract: Certain metal-exchanged SUZ-4 zeolites have been prepared that have catalytic activity for the reduction of NOx in the exhaust of a hydrocarbon or alcohol fueled engine operated under fuel lean conditions. Initially the SUZ-4 zeolite contains alkali metal cations such as Li+, Na+, K+ and/or Cs+. These alkali metal cation-containing zeolites are partially exchanged with at least one of copper (II), silver (I), iron (III) or cobalt (II) ions. The resulting partially exchanged SUZ-4 zeolites display such activity and are stable under extreme hydrothermal aging conditions.

    Abstract translation: 已经制备了一些金属交换的SUZ-4沸石,其具有催化活性,用于在燃料贫乏条件下运行的烃或醇燃料发动机的排气中还原NOx。 最初,SUZ-4沸石含有碱金属阳离子如Li +,Na +,K +和/或Cs +。 这些含碱金属阳离子的沸石与铜(II),银(I),铁(III)或钴(II)离子中的至少一种部分交换。 得到的部分交换的SUZ-4沸石显示出这种活性,并且在极端的水热老化条件下是稳定的。

    METHOD OF PREPARING AN STT-TYPE ZEOLITE FOR USE AS A CATALYST IN SELECTIVE CATALYTIC REDUCTION REACTIONS
    20.
    发明申请
    METHOD OF PREPARING AN STT-TYPE ZEOLITE FOR USE AS A CATALYST IN SELECTIVE CATALYTIC REDUCTION REACTIONS 审中-公开
    制备用于选择性催化还原反应中催化剂的STT型沸石的方法

    公开(公告)号:US20170043294A9

    公开(公告)日:2017-02-16

    申请号:US14669197

    申请日:2015-03-26

    Abstract: A method of preparing a crystalline STT-type zeolite that has a mole ratio greater than about 15:1 of a tetravalent element oxide to a trivalent element oxide is disclosed along with a gas treatment system that incorporates the STT-type zeolite and a process for treating a gas using the STT-type zeolite. The method generally comprises forming an aqueous mixture comprising a tetravalent element oxide source, a trivalent element oxide source, a source of alkali metal, and an organic structure directing agent; maintaining the mixture under conditions that crystallize crystals of a STT-type zeolite; and recovering the crystals The STT-type zeolite crystals exhibit x-ray diffraction 2-theta degree peaks at: 8.26, 8.58, 9.28, 9.54, 10.58, 14.52, 15.60, 16.43, 17.13, 17.74, 18.08, 18.46, 19.01, 19.70, 20.12, 20.38, 20.68, 21.10, 21.56, 22.20, 22.50, 22.78, 23.36, 23.76, 23.99, 24.54, 24.92, 25.16, 25.58, 25.80, 26.12, 26.94, 27.38, 27.92, 28.30, 28.60, 29.24, 29.48, 30.08, 30.64, 31.20, 31.46, 31.80, 32.02, 32.60, 33.60, and 34.43.

    Abstract translation: 公开了一种将四价元素氧化物与三价元素氧化物的摩尔比大于约15:1的结晶STT型沸石与含有STT型沸石的气体处理系统一起制备, 使用STT型沸石处理气体。 该方法通常包括形成包含四价元素氧化物源,三价元素氧化物源,碱金属源和有机结构导向剂的含水混合物; 在使STT型沸石的晶体结晶的条件下保持混合物; 并回收晶体STT型沸石晶体在8.26,8.58,9.28,9.54,10.58,14.52,15.60,16.43,17.13,17.74,18.08,18.46,19.01,19.70℃下显示x射线衍射2θ度峰, 20.12,20.38,20.68,21.10,21.56,22.20,22.50,22.78,23.36,23.76,23.99,24.54,24.92,25.16,25.58,25.80,26.12,26.94,27.38,27.92,28.30,28.60,29.24,29.48,30.08, 30.64,31.20,31.46,31.80,32.02,32.60,33.60,和34.43。

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