摘要:
In a first processing chamber, a feedstock may be combined with plasma from, for example, three plasma torches to form a first fluid mixture. Each torch may have a working gas including water vapor, oxygen, and carbon dioxide. The first fluid mixture may be cooled and may contact a first heat exchange device. The output fluid from the first heat exchange device may be separated into one or more components. A syngas may be derived from the one or more components and have a ratio of carbon monoxide to hydrogen of about 1:2. The syngas may be transferred to a catalyst bed to be converted into one or more fluid fuels.
摘要:
A chemical conversion process includes a synthesis step (10) that takes, as input, reactants that include at least dihydrogen and carbon monoxide and that gives, as output, a synthetic compound such as an engine fuel, water and overhead gases, a step of recovering all or some of the overhead gases resulting from the synthesis step and a step of producing dihydrogen, in particular electrochemically (14), by a conversion of the overhead gases recovered in the recovering step.
摘要:
The present invention is directed to a process for the production of hydrocarbon product from two different hydrocarbonaceous feedstocks comprising the steps of preparing a feed syngas having a hydrogen/carbon monoxide [H2/CO] molar feed ratio suitable for Fischer-Tropsch synthesis, wherein the feed syngas is prepared by combining a first syngas having a H2/CO molar ratio below the molar feed ratio and a second syngas having a H2/CO molar ratio above the molar feed ratio; the first syngas is prepared from a liquid hydrocarbon comprising feedstock as the sole source of carbon in a first syngas manufacturing process comprising a non-catalytic partial oxidation step; the second syngas is prepared from a methane comprising feedstock as the sole source of carbon in a second syngas manufacturing process comprising a heat exchange reforming step and an auto-thermal reforming step; and the first and second syngas manufacturing processes are operated in parallel.
摘要:
Described are methods of cultivating autotrophic microorganisms, particularly microalgae or diatoms, in a bioreactor by entraining a culture of the microorganisms in a tenuous, gelated, thixotrophic carrier medium having nutrients therefor and moving the medium along a passage at a sufficiently slow speed to enable laminar flow which in cross section is closed and which has transparent walls through which the culture is irradiated to enable photosynthesis. The method includes effecting convective turnover of the culture and medium as they flow along the passage by differentially heating the medium laterally relative to the flow direction so as to produce a generally helical flow of the culture and medium. Also described are processing methods, both physical and chemical, performed underground e.g. in drillholes, to utilize decavitation energy under ambient elevated pressures, including processes to implement lysis of the micro-organisms, producing methanol, syngas synthesis, Haber ammonia synthesis, Fischer-Tropsch reactions, supercritical reactions, dimethyl ether synthesis, and nitric acid synthesis.
摘要:
Conversion of synthesis gas to propylene is enhanced via a stepped process wherein a Fischer-Tropsch reaction is first carried out, followed by recovery of propylene produced thereby and then use of product ethylene and unreacted syngas in a hydroformylation reaction to produce propanol, which is then dehydrated to form additional propylene. The process enables significant enhancement of propylene yield that is efficient and makes use of ethylene that is a byproduct of Fischer-Tropsch processes that are employed primarily for production of higher olefms, such as hexene and octene. Thus, it can be carried out in conjunction with already on-line Fischer-Tropsch facilities.
摘要:
Processes and systems for forming ethanol from methanol. The process involves carbonylating the methanol to form acetic acid and hydrogenating the acetic acid to form ethanol. In a first aspect, at least some hydrogen for the hydrogenating step is derived from a tail gas stream formed in the carbonylation step. In a second aspect, at least some carbon monoxide for the carbonylation step is derived from a vapor stream in the hydrogenation system. In a third aspect, a syngas stream is separated to form a hydrogen stream and a carbon monoxide stream, and the hydrogen stream is methanated to remove residual carbon monoxide prior to being introduced into the hydrogenation system.
摘要:
A method for preparing a catalyst comprising (i) preparing a calcined shaped calcium aluminate catalyst support, (ii) treating the calcined shaped calcium aluminate support with water, and then drying the support, (iii) impregnating the dried support with a solution containing one or more metal compounds and drying the impregnated support, (iv) calcining the dried impregnated support, to form metal oxide on the surface of the support and (v) optionally repeating steps (ii), (iii) and (iv) on the metal oxide coated support. The method provides an eggshell catalyst in which the metal oxide is concentrated in an outer layer on the support.
摘要:
Techniques, systems and material are disclosed for thermochemical regeneration of biomass into renewable engineered fuel, storage of the renewable engineered fuel, respeciation of the renewable engineered fuel and transport. In one aspect, a method includes generating low density hydrogen fuel from biomass dissociation at a first location of a low elevation. The low density hydrogen fuel is self-transported in a pipeline to a second location at a higher elevation than the first location by traveling from the first location to the second location without adding energy of pressure. A high density hydrogen carrier is generated at the second location of higher elevation by reacting the low density hydrogen fuel with at least one of a carbon donor, a nitrogen donor and an oxygen donor harvested from industrial waste. The high density hydrogen carrier is delivered to a third location of a lower elevation than the second location while providing pressure or kinetic energy.
摘要:
Methods for converting of syngas to higher molecular weight products using Fischer-Tropsch synthesis, and methods for optimizing the catalyst systems in the synthesis, are disclosed. In one embodiment, the methods use cobalt/ruthenium Fischer-Tropsch catalysts in combination with an olefin isomerization catalyst, which isomerizes double bonds in C4+ olefins as they are formed. In another embodiment, the methods use Fischer-Tropsch catalysts that may or may not be cobalt/ruthenium catalysts, in combination with olefin isomerization catalysts which are acidic enough to isomerize the C4+ olefins but not too acidic to cause rapid coking. A benefit of using the relatively less acidic zeolites is that the ratio of iso-paraffins to aromatics is increased relative to when more acidic zeolites are used. Also, the relatively less acidic zeolites do not coke as readily as the relatively more acidic zeolites. The methods can advantageously be optimized using combinatorial chemistry, in which a database of combinations of catalyst systems and, optionally, reaction conditions, which provide various product streams, are generated. As market conditions vary and/or product requirements change, conditions suitable for forming desired products can be identified with little or no downtime.
摘要:
Composite metal membranes are disclosed that contain an intermetallic diffusion barrier separating a hydrogen-permeable base metal and a hydrogen-permeable coating metal. The barrier is a thermally stable inorganic proton conductor.