公开(公告)号：US09714208B2

公开(公告)日：2017-07-25

申请号：US13760472

申请日：2013-02-06

Applicant: The Procter & Gamble Company

Inventor： Janette Villalobos ,  Juan Estaban Velasquez ,  Jane Ellen Godlewski ,  Dimitris Ioannis Collias

IPC: C07C51/377 ,  C07C51/48 ,  B01J27/18 ,  B01J27/187 ,  B01J27/25 ,  C07C51/09 ,  C07C57/04 ,  A61F13/534 ,  C08F2/10 ,  B01J27/16 ,  B01J27/185 ,  B01J27/186 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J35/02 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  C07C51/44 ,  A61F13/53

CPC classification number: C07C51/48 ,  A61F13/53 ,  A61F13/534 ,  A61F2013/530489 ,  A61F2013/530496 ,  B01J27/16 ,  B01J27/1806 ,  B01J27/1811 ,  B01J27/1817 ,  B01J27/1853 ,  B01J27/1856 ,  B01J27/186 ,  B01J27/187 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J27/25 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/04 ,  B01J37/08 ,  C07C51/09 ,  C07C51/377 ,  C07C51/44 ,  C07C57/04 ,  C08F2/10

Abstract: Methods for catalytically dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed condensed phosphates.

公开(公告)号：US09687825B1

公开(公告)日：2017-06-27

申请号：US15193399

申请日：2016-06-27

Applicant: Chevron U.S.A. Inc.

Inventor： Kandaswamy Jothimurugesan ,  Mark Muraoka

IPC: B01J27/188 ,  B01J23/75 ,  B01J37/02 ,  B01J37/08 ,  B01J35/10 ,  C10G2/00

CPC classification number: B01J27/188 ,  B01J23/75 ,  B01J23/8913 ,  B01J23/894 ,  B01J35/023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/024 ,  B01J37/08 ,  B01J37/10 ,  B01J37/28 ,  C10G2/332 ,  C10G2/333

Abstract: A process to make a Fischer-Tropsch catalyst with improved hydrothermal stability, comprising: a. contacting a crystalline oxide material with a solution of a tungsten and a phosphorus to make a tungsten-phosphorus modified support; b. calcining the tungsten-phosphorus modified support at a temperature less than or equal to 750° C. to make a calcined tungsten-phosphorus modified support that has the improved hydrothermal stability and that can be used to support a Co-loaded Fischer-Tropsch catalyst. A Co-loaded Fischer-Tropsch catalyst having improved hydrothermal stability and higher C5+ hydrocarbon productivity is also provided. A Fischer-Tropsch synthesis process is provided, comprising contacting a gaseous mixture comprising a carbon monoxide and a hydrogen with the Co-loaded Fischer-Tropsch catalyst having the improved hydrothermal stability and higher C5+ productivity, at a pressure of from 0.1 to 3 MPa and at a reaction temperature of from 180 to 260° C., thereby producing a product comprising C5+ hydrocarbons.

公开(公告)号：US09630901B2

公开(公告)日：2017-04-25

申请号：US13760527

申请日：2013-02-06

Applicant: The Procter & Gamble Company

Inventor： Jane Ellen Godlewski ,  Janette Villalobos ,  Dimitris Ioannis Collias ,  Axel Meyer ,  Peter Dziezok ,  Juan Estaban Velasquez

IPC: A61F13/15 ,  C07C51/48 ,  B01J27/18 ,  B01J27/187 ,  B01J27/25 ,  C07C51/377 ,  C07C51/09 ,  C07C57/04 ,  A61F13/534 ,  C08F2/10 ,  B01J27/16 ,  B01J27/185 ,  B01J27/186 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J35/02 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  C07C51/44 ,  A61F13/53

CPC classification number: C07C51/48 ,  A61F13/53 ,  A61F13/534 ,  A61F2013/530489 ,  A61F2013/530496 ,  B01J27/16 ,  B01J27/1806 ,  B01J27/1811 ,  B01J27/1817 ,  B01J27/1853 ,  B01J27/1856 ,  B01J27/186 ,  B01J27/187 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J27/25 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/04 ,  B01J37/08 ,  C07C51/09 ,  C07C51/377 ,  C07C51/44 ,  C07C57/04 ,  C08F2/10

Abstract: Bio-based glacial acrylic acid, produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof and having impurities of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof, is polymerized to poly(acrylic acid) or superabsorbent polymer using the same processes as petroleum-derived glacial acrylic acid.

公开(公告)号：US09586884B2

公开(公告)日：2017-03-07

申请号：US14780678

申请日：2014-03-28

Applicant: Agency for Science, Technology and Research ,  Nanyang Technological University

Inventor： Kanaparthi Ramesh ,  Armando Borgna ,  Yi Ling Eileen Goh ,  Timothy John White

IPC: C07C45/38 ,  B01J27/00 ,  B01J27/198 ,  B01J23/50 ,  B01J27/18 ,  B01J27/188 ,  B01J35/10

CPC classification number: C07C45/38 ,  B01J23/50 ,  B01J27/1806 ,  B01J27/1817 ,  B01J27/188 ,  B01J27/198 ,  B01J35/1014 ,  C07C47/06

Abstract: The present invention provides the use of a metal-doped hydroxyapatite catalyst for highly selective conversion of an alcohol to an aldehyde at low temperatures. More specifically, the invention provides the use of a silver-doped hydroxyapatite catalyst for the highly selective oxidative dehydrogenation of ethanol to acetaldehyde. The present invention also provides the method for converting ethanol to acetaldehyde using a silver-doped hydroxyapatite catalyst.

Abstract translation: 本发明提供了金属掺杂的羟基磷灰石催化剂在低温下将醇高效地转化为醛的用途。 更具体地说，本发明提供了使用掺杂银的羟基磷灰石催化剂用于将乙醇高度选择性氧化脱氢成乙醛。 本发明还提供了使用掺银羟基磷灰石催化剂将乙醇转化为乙醛的方法。

公开(公告)号：US20170001924A1

公开(公告)日：2017-01-05

申请号：US14970108

申请日：2015-12-15

Applicant: HINDUSTAN PETROLEUM COPORATION LTD.

Inventor： RAMAN RAVISHANKAR ,  SAFINAZ SAIF ,  PEDDY VENKATACHALLAPATHY RAO ,  VENKATESWARLU CHOUDARY NETTEM ,  SRIGANESH GANDHAM

IPC: C07C5/27 ,  B01J27/188 ,  B01J21/18 ,  B01J37/08 ,  B01J23/42 ,  B01J23/755 ,  B01J27/19 ,  B01J37/04

CPC classification number: C07C5/2783 ,  B01J21/18 ,  B01J23/002 ,  B01J23/42 ,  B01J23/755 ,  B01J27/188 ,  B01J27/19 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C01B32/192 ,  C01B32/198 ,  C01B32/23 ,  C07C2521/18 ,  C07C2523/42 ,  C07C2523/755 ,  C07C2527/188 ,  C07C2527/19 ,  C07C9/16 ,  B01J2523/51 ,  B01J2523/69 ,  B01J2523/847 ,  B01J2523/68

Abstract: A catalyst composition is provided for isomerization of paraffins comprising of at least one heteropoly acid and reduced graphene oxide. Further provided are a process for preparation of the catalyst composition and a process for isomerization of paraffins using the catalytic composition.

Abstract translation: 提供催化剂组合物用于异构化包含至少一种杂多酸和还原型石墨烯氧化物的链烷烃。 还提供了使用催化剂组合物制备催化剂组合物的方法和烷烃异构化方法。

公开(公告)号：US09364816B2

公开(公告)日：2016-06-14

申请号：US13394971

申请日：2010-08-24

Applicant: Sona Eijsbouts-Spickova ,  Marcel Adriaan Jansen

Inventor： Sona Eijsbouts-Spickova ,  Marcel Adriaan Jansen

IPC: B01J27/19 ,  B01J27/185 ,  B01J37/02 ,  B01J23/888 ,  B01J23/88 ,  B01J37/08 ,  C10G49/04 ,  C10G45/04 ,  C10G45/08 ,  B01J27/14 ,  B01J27/188 ,  B01J37/00 ,  B01J37/03

CPC classification number: B01J23/888 ,  B01J23/88 ,  B01J27/1853 ,  B01J27/19 ,  B01J37/0203 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/08 ,  C10G45/04 ,  C10G45/08 ,  C10G49/04

Abstract: This invention provides processes for forming solution compositions, which processes comprises bringing together, in an aqueous medium, i) at least one phosphorus compound; ii) at least one Group VI metal compound; and iii) at least one Group VIII metal compound, such that a solution having a Group VI metal concentration of more than about 5.6 mol/L is formed. Also provided are compositions formed by such processes, processes for forming catalyst compositions from these compositions, and catalyst compositions formed by these processes.

Abstract translation: 本发明提供了形成溶液组合物的方法，该方法包括在水性介质中使i）至少一种磷化合物; ii）至少一种VI族金属化合物; 和iii）至少一种VIII族金属化合物，使得形成具有大于约5.6mol / L的VI族金属浓度的溶液。 还提供了通过这些方法形成的组合物，由这些组合物形成催化剂组合物的方法，以及由这些方法形成的催化剂组合物。

公开(公告)号：US20160074843A1

公开(公告)日：2016-03-17

申请号：US14791999

申请日：2015-07-06

Applicant: TIANJIN UNIVERSITY

Inventor： Yongdan LI ,  Rui MA ,  Xiaolei MA ,  Wenyue HAO

IPC: B01J27/24 ,  B01J27/19 ,  B01J27/188 ,  B01J27/22 ,  C07C67/00 ,  C07C37/54 ,  C07C1/20 ,  B01J23/28 ,  C07C29/00

CPC classification number: B01J27/24 ,  B01J23/28 ,  B01J23/88 ,  B01J23/888 ,  B01J23/8993 ,  B01J27/188 ,  B01J27/19 ,  B01J27/22 ,  C07C1/20 ,  C07C29/00 ,  C07C37/54 ,  C07C67/00 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2521/18 ,  C07C2527/188 ,  C07C2527/19 ,  C07C2527/22 ,  C07C2527/24 ,  C07C39/00

Abstract: A subgroup VI element to prepare a catalyst for the production of organic chemicals and fuels from lignin with the involvement of solvent molecules. The catalytic reaction use a catalyst composed of a molybdenum or tungsten compound as the active phase, with mixing a kind of lignin, a catalyst, and a reactive solvent. An inert or reductive gas such as H2, N2 or Ar is used to purge or fill the reaction vessel. The temperature is above 200° C., the reaction time is sufficient. The liquid product is separated and analyzed; a catalytic process with a very high product yield, up to 90% if calculated accounting the parts from lignin of the product molecules, or up to over 100% if calculated as the mass products. The product includes aromatic compounds, esters, alcohols, monophenols and benzyl alcohols in different ratios according to the composition, the solvent and the other reaction conditions.

Abstract translation: 一种VI族元素，用于在溶剂分子的作用下制备用于从木质素生产有机化学物质和燃料的催化剂。 催化反应使用由钼或钨化合物组成的催化剂作为活性相，混合一种木质素，催化剂和反应性溶剂。 使用惰性或还原性气体如H 2，N 2或Ar来吹扫​​或填充反应容器。 温度高于200℃，反应时间就足够了。 液体产品被分离和分析; 如果计算产品分子的木质素部分计算，则产品产量非常高的催化过程高达90％，如果以质量产品计算则达到超过100％。 该产品根据组成，溶剂和其它反应条件，包括不同比例的芳族化合物，酯，醇，单酚和苄醇。

公开(公告)号：US09227179B2

公开(公告)日：2016-01-05

申请号：US13849829

申请日：2013-03-25

Applicant: SHELL OIL COMPANY

Inventor： Karl Marvin Krueger ,  Puneet Gupta

IPC: B01J27/057 ,  B01J27/19 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/188 ,  B01J37/02 ,  C10G45/08 ,  B01J27/02

CPC classification number: B01J27/0573 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/188 ,  B01J27/19 ,  B01J37/0201 ,  B01J37/0207 ,  C10G45/08

Abstract: A hydroprocessing catalyst composition that comprises a support material and a selenium component and which support material further includes at least one hydrogenation metal component. The hydroprocessing catalyst is prepared by incorporating a selenium component into a support particle and, after calcination thereof, incorporating at least one hydrogenation metal component into the selenium-containing support. The metal-incorporated, selenium-containing support is calcined to provide the hydroprocessing catalyst composition.

Abstract translation: 一种加氢处理催化剂组合物，其包括载体材料和硒组分，并且所述载体材料还包含至少一种氢化金属组分。 加氢处理催化剂通过将硒组分掺入载体颗粒中并在其煅烧之后将至少一种氢化金属组分并入含硒载体中来制备。 将含金属的含硒载体煅烧以提供加氢处理催化剂组合物。

公开(公告)号：US09145342B2

公开(公告)日：2015-09-29

申请号：US14136404

申请日：2013-12-20

Applicant: ASAHI KASEI CHEMICALS CORPORATION

Inventor： Tatsuo Yamaguchi ,  Hiroyuki Noda ,  Toru Watanabe ,  Shunya Kirino

IPC: C07C1/24 ,  B01J21/04 ,  B01J23/04 ,  B01J27/188 ,  B01J35/10 ,  C07C29/04 ,  B01D3/00

CPC classification number: B01J19/18 ,  B01D3/009 ,  B01J19/0066 ,  B01J21/04 ,  B01J23/04 ,  B01J27/188 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/108 ,  B01J2219/185 ,  C07C1/24 ,  C07C29/04 ,  C07C2521/04 ,  C07C2523/04 ,  Y02P20/582 ,  C07C11/09 ,  C07C31/12

Abstract: An object of the present invention is to provide, for the production of isobutene, a high-yielding, highly-selective, and long-term stable production process of isobutene from TBA. With respect to the production of TBA, an object of the present invention is to provide a TBA production process in which, through long-term stable maintenance of a high reaction activity, long-term continuous operation is enabled and the productivity is improved. The present invention discloses a process for producing isobutene that employs a dehydration temperature of from 200 to 450° C. in use of an alumina catalyst that contains a Na content of 0.6% by weight or less in terms of NaO2 and a Na content of 0.4% by weight in terms of NaO2, and has a specific surface area of from 200 to 600 m2/g.

Abstract translation: 本发明的目的是提供异丁烯从TBA生产高产，高选择性和长期稳定的异丁烯的生产方法。 关于TBA的生产，本发明的目的是提供一种TBA制备方法，其中通过长期稳定地维持高反应活性，能够实现长期连续操作并提高生产率。 本发明公开了一种使用脱水温度为200〜450℃的异丁烯的制造方法，其中使用的氧化铝催化剂含有以NaO 2计Na值为0.6重量％以下且Na含量为0.4的Na 以NaO 2换算，其比表面积为200〜600m2 / g。

公开(公告)号：US09126185B2

公开(公告)日：2015-09-08

申请号：US13623194

申请日：2012-09-20

Applicant: Matthew Laskoski

Inventor： Matthew Laskoski

IPC: C08G73/06 ,  C08F8/32 ,  C08G65/00 ,  B01J27/188 ,  B01J23/30 ,  C08L79/02 ,  A62D3/38 ,  B01J37/03 ,  B01J23/28 ,  B01J27/199 ,  B01J35/00 ,  B01J37/02 ,  A62D3/30 ,  A62D101/02

CPC classification number: C08J9/36 ,  A62D3/30 ,  A62D3/38 ,  A62D2101/02 ,  B01J23/28 ,  B01J23/30 ,  B01J27/188 ,  B01J27/199 ,  B01J35/002 ,  B01J37/0209 ,  B01J37/031 ,  C08G73/0694 ,  C08J2325/06 ,  C08J2345/00 ,  C08L79/02

Abstract: A composition for the destruction of chemical warfare agents and toxic industrial chemicals having a polyoxometalate (POM) attached to an amine, carboxylic acid, or ammonium substituted porous polymer. Also disclosed is a method for attaching a POM to an amine, carboxylic acid, or ammonium substituted porous polymer by (1) dissolving the POM in water or an organic solvent, adding the functionalized porous polymer, whereby the POM ionically attaches to the amine, carboxylic acid or ammonium group, or (2) heating the POM and functionalized polymer in the presence of a dehydrating agent whereby an imide bond is produced between the POM and the functionality on the porous polymer.

Abstract translation: 用于破坏化学战剂和毒性工业化学品的组合物，其具有连接到胺，羧酸或铵取代的多孔聚合物上的多金属氧酸盐（POM）。 还公开了通过（1）将POM溶解在水或有机溶剂中，将POM连接到胺，羧酸或铵取代的多孔聚合物上的方法，加入官能化的多孔聚合物，由此POM离子键连接到胺上， 羧酸或铵基团，或（2）在脱水剂存在下加热POM和官能化聚合物，由此在POM和多孔聚合物上的官能度之间产生酰亚胺键。