Electrochemical plating methods
    42.
    发明授权
    Electrochemical plating methods 有权
    电化学镀方法

    公开(公告)号:US09496145B2

    公开(公告)日:2016-11-15

    申请号:US14219940

    申请日:2014-03-19

    Abstract: An electrochemical process for applying a conductive film onto a substrate having a seed layer includes placing the substrate into contact with an electrochemical plating bath containing cobalt or nickel, with the plating bath having pH of 4.0 to 9.0. Electric current is conducted through the bath to the substrate. The cobalt or nickel ions in the bath deposit onto the seed layer. The plating bath may contain cobalt chloride and glycine. The electric current may range from 1-50 milli-ampere per square cm. After completion of the electrochemical process, the substrate may be removed from the plating bath, rinsed and dried, and then annealed at a temperature of 200 to 400 C to improve the material properties and reduce seam line defects. The plating and anneal process may be performed through multiple cycles.

    Abstract translation: 用于将导电膜施加到具有种子层的基底上的电化学方法包括将基底与包含钴或镍的电化学镀浴接触,镀浴的pH为4.0至9.0。 电流通过熔池传导到基板。 浴中的钴或镍离子沉积到种子层上。 电镀浴可能含有氯化钴和甘氨酸。 电流可以为1-50毫安每平方厘米。 电化学工艺完成后,可以将基板从镀液中除去,漂洗并干燥,然后在200-400℃的温度下退火,以改善材料性能并减少接缝线缺陷。 电镀和退火工艺可以通过多个循环进行。

    METHOD FOR ELECTROCHEMICALLY DEPOSITING METAL ON A REACTIVE METAL FILM
    44.
    发明申请
    METHOD FOR ELECTROCHEMICALLY DEPOSITING METAL ON A REACTIVE METAL FILM 审中-公开
    在金属膜上电化学沉积金属的方法

    公开(公告)号:US20150348826A1

    公开(公告)日:2015-12-03

    申请号:US14292385

    申请日:2014-05-30

    Abstract: In accordance with one embodiment of the present disclosure, a method for depositing metal on a reactive metal film on a workpiece includes obtaining a workpiece including a dielectric surface; forming a barrier layer on the dielectric surface; depositing a seed layer on the barrier layer, wherein the barrier and seed stack includes at least one metal having a standard electrode potential of less than 0.34 V; and depositing a metallization layer on the seed layer using a diluted acid bath in a pH range of about 1 to about 5 and a current density in the range of about 10 mA/cm2 to about 30 mA/cm2.

    Abstract translation: 根据本公开的一个实施例,用于在工件上的反应性金属膜上沉积金属的方法包括获得包括电介质表面的工件; 在电介质表面上形成阻挡层; 在阻挡层上沉积种子层,其中所述势垒和种子堆叠包括至少一种具有小于0.34V的标准电极电位的金属; 以及使用在约1至约5的pH范围内的电流密度和约10mA / cm 2至约30mA / cm 2范围内的电流密度的稀酸浴,在种子层上沉积金属化层。

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