Abstract:
This invention relates to articles made of polyester, preferably polyethylene terephthalate (PET), having coated directly to at least one of the surfaces thereof one or more layers of thermoplastic material with good gas-barrier characteristics, and novel methods of making such articles. Preferably the barrier-coated articles take the form of preforms coated by at least one layer of barrier material and the containers blow-molded therefrom. Such barrier-coated containers are preferably of the type to hold beverages such as soft drinks, beer or juice. The preferred barrier materials have a lower permeability to oxygen and carbon dioxide than PET as well as key physical properties similar to PET. The materials and methods provide that the barrier layers have good adherence to PET, even during and after the blow molding process to form containers from preforms. Preferred barrier coating materials include poly(hydroxyamino ethers). In one preferred method, preforms are injection molded then barrier-coated immediately thereafter.
Abstract:
Coated articles may comprise one or more coating layers, including water resistant coatings. A method comprises applying such coating layers by treating the article substrate by one or more methods selected from flame treatment, corona treatment, ionized air treatment, plasma air treatment and plasma arc treatment and dip, spray or flow coating. Additionally, a method comprises injection molding a first substrate material to form an article, treating the article surface by one or more methods selected from flame treatment, corona treatment, ionized air treatment, plasma air treatment and plasma arc treatment, and overmolding the article substrate with one or more barrier materials.
Abstract:
Articles are coated by applying a coating composition of a high Tg phenoxy-type material having a Tg of at least about 75° C. to at least a portion of a surface of an article, and forming a dried/cured coating of the high Tg phenoxy-type material on the article surface, where the coating has the high Tg phenoxy-type material and a PHAE; or the article surface comprises a coating includes a PHAE; or the coating has the high Tg phenoxy-type material and a PHAE, and the article surface includes a coating layer of a PHAE.
Abstract:
Coated articles are formed by applying a first aqueous solution or dispersion of a thermoplastic resin on a surface of an article and at least one IR curing catalyst to form a film, where at least a portion of the first aqueous solution or dispersion is a thermoplastic epoxy resin. The film is exposed to IR radiation in an amount sufficient to at least partially cure the film, and a substantially cured and/or dried thermoplastic epoxy coating is formed.
Abstract:
In preferred embodiments methods and apparatuses can produce articles that have formable material. The articles may be mono and multilayer. The articles can be formed by various methods.
Abstract:
Articles are coated by applying a coating composition of a high Tg phenoxy-type material having a Tg of at least about 75° C. to at least a portion of a surface of an article, and forming a dried/cured coating of the high Tg phenoxy-type material on the article surface, where the coating has the high Tg phenoxy-type material and a PHAE; or the article surface comprises a coating includes a PHAE; or the coating has the high Tg phenoxy-type material and a PHAE, and the article surface includes a coating layer of a PHAE.
Abstract:
A seamless collapsible container has a molded finish, configured and adapted for sealing with a closure and, optionally, for attachment to a dispensing apparatus, and a seamless, blow molded body portion, comprising an inner surface, an outer surface, and a wall, where the wall is sufficiently thin to allow the body portion to collapse, and the molded finish and at least an inner layer of the body portion together comprise a seamless, single piece of thermoplastic material. The seamless collapsible container may be used in such applications as a bag-in-box, a carton liner, and a beverage pouch.
Abstract:
Preferred embodiments relate to methods and apparatus for making articles made of polyester, preferably virgin polyethylene terephthalate (PET), having coated directly to at least one of the surfaces thereof one or more layers of recycled or post-consumer PET and one or more layers of a material with good gas-barrier characteristics, preferably silicon oxide. Preferably, the recycled PET layer comprises about 25% to about 50% of the entire material content. Preferably the articles take the form of preforms and the containers are blow-molded therefrom and the barrier layer is subsequently applied. The preferred barrier materials have a lower permeability to oxygen and carbon dioxide than PET. In addition, the neck of the preforms and bottles is at least partially in the crystalline state and the body is primarily in the amorphous or semi-crystalline state. This structure in a preform enables the preform to be easily blow molded by virtue of the amorphous material in the body, while being able to have dimensional stability in hot-fill applications.
Abstract:
Disclosed is a preferred mold design for producing plastic, injection molded preforms, which may be blow-molded into a container of a final, desired shape. A preferred mold includes a combination of hardened material components and high heat transfer material components to provide a mold having good wear characteristics, for a sufficiently long useful life, and to enable rapid cooling of the injected preform, in order to reduce the cycle time of an injection and cooling cycle. In some arrangements, the hardened materials may form a portion of the preform cavity thereby slowing the rate of cooling in those areas and inducing a semi-crystalline or crystalline structure in the cooled preform.
Abstract:
Preferred embodiments relate to methods and apparatus for making articles made of polyester, preferably virgin polyethylene terephthalate (PET), having coated directly to at least one of the surfaces thereof one or more layers of recycled or post-consumer PET and one or more layers of a material with good gas-barrier characteristics, preferably silicon oxide. Preferably, the recycled PET layer comprises about 25% to about 50% of the entire material content. Preferably the articles take the form of preforms and the containers are blow-molded therefrom and the barrier layer is subsequently applied. The preferred barrier materials have a lower permeability to oxygen and carbon dioxide than PET. In addition, the neck of the preforms and bottles is at least partially in the crystalline state and the body is primarily in the amorphous or semi-crystalline state. This structure in a preform enables the preform to be easily blow molded by virtue of the amorphous material in the body, while being able to have dimensional stability in hot-fill applications.