公开(公告)号：US07205256B2

公开(公告)日：2007-04-17

申请号：US10399576

申请日：2001-09-03

申请人： Takeshi Kijima ,  Hiroshi Ishiwara

发明人： Takeshi Kijima ,  Hiroshi Ishiwara

IPC分类号： B01J21/06 ,  B01J32/00 ,  B32B18/00 ,  H01L29/00

CPC分类号： B82Y30/00 ,  C01B13/14 ,  C01B13/32 ,  C01B33/20 ,  C01G23/003 ,  C01G25/006 ,  C01G29/00 ,  C01G29/006 ,  C01G35/006 ,  C01P2002/02 ,  C01P2002/34 ,  C01P2002/50 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2002/85 ,  C01P2004/64 ,  C01P2004/80 ,  C01P2006/40 ,  H01L21/02142 ,  H01L21/02161 ,  H01L21/02197 ,  H01L21/02282 ,  H01L21/02356 ,  H01L21/31691 ,  Y10S502/514 ,  Y10S502/525

摘要： An oxide material characterized by that it has a perovskite structure comprising an oxide represented by ABO3, (Bi2O2)2+ (Am−1BmO3m+1)2− wherein A represents one kind or two or more kinds of ions selected from the group consisting of Li+, Na+, K+, Pb2+, Ca2+, Sr2+, Ba2+, Bi3+, Y3+, Mn3+ and La3+, B represents one kind or two or more kinds of ions selected from the group consisting of Ru3+, Fe3+, Ti4+, Zr4+, Cu4+, Nb5+, Ta5+, V5+, W6+ and Mo6+, and m represents a natural number of 1 or more, LnBa2Cu3O7, Z2Ba2Can−1CunO2n+4 or ZBa2Can−1CunO2n+3, wherein Ln represents one kind or two or more kinds of ions selected from the group consisting of Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, Z represents one kind or two or more kinds of ions selected from the group consisting of Bi, Tl and Hg, and n represents a natural number of from 1 to 5; and a catalytic substance containing one or more kinds of elements selected from the group consisting of Si, Ge and Sn.

公开(公告)号：US07199079B2

公开(公告)日：2007-04-03

申请号：US11039032

申请日：2005-01-20

申请人： Yuichi Matsuo ,  Atsushi Furukawa ,  Norihiko Suzuki ,  Kazunori Kiguchi

发明人： Yuichi Matsuo ,  Atsushi Furukawa ,  Norihiko Suzuki ,  Kazunori Kiguchi

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC分类号： B01D53/945 ,  B01D2255/1023 ,  B01D2255/206 ,  B01D2255/402 ,  B01J23/002 ,  B01J23/10 ,  B01J23/14 ,  B01J23/20 ,  B01J23/34 ,  B01J23/63 ,  B01J23/6484 ,  B01J23/6562 ,  B01J23/83 ,  B01J23/894 ,  B01J35/002 ,  B01J37/0018 ,  B01J37/0201 ,  B01J2523/00 ,  Y02A50/2324 ,  Y02T10/22 ,  Y10S502/525 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/824 ,  B01J2523/56 ,  B01J2523/17 ,  B01J2523/47 ,  B01J2523/11 ,  B01J2523/32 ,  B01J2523/3725 ,  B01J2523/27 ,  B01J2523/72 ,  B01J2523/375 ,  B01J2523/35 ,  B01J2523/42

摘要： A purification catalyst for exhaust gas enhances the activities of the precious metals, preventing decrease of activities at high temperature, and exhibiting a satisfactory performance during operation. In the purification catalyst of the present invention, Pd is supported by an aluminum composite oxide having a perovskite structure, the aluminum composite oxide is LnAl1−xMxO3 in which Ln is a rare-earth element, and the element M in the LnAl1−xMxO3 is one of elements in groups 1 to 5 and groups 12 to 14.

摘要翻译： 用于废气的净化催化剂增强贵金属的活性，防止高温下的活性降低，并且在操作期间表现出令人满意的性能。 在本发明的纯化催化剂中，Pd由具有钙钛矿结构的铝复合氧化物负载，铝复合氧化物为LnAl 1-x M x O O > 3 其中Ln是稀土元素，并且LnAl 1-x M x O 3 3中的元素M 是组1至5和组12至14中的元素之一。

公开(公告)号：US07014825B2

公开(公告)日：2006-03-21

申请号：US10360385

申请日：2003-02-06

申请人： Stephen J. Golden

发明人： Stephen J. Golden

IPC分类号： B01J8/00 ,  B01J8/02 ,  C01B31/00 ,  C01B31/18 ,  C01B21/00

CPC分类号： B01J23/8892 ,  B01D53/944 ,  B01D53/945 ,  B01J23/002 ,  B01J23/83 ,  B01J2523/00 ,  F01N3/206 ,  F01N3/281 ,  F01N3/2828 ,  F01N2370/02 ,  F01N2510/06 ,  F01N2610/02 ,  Y02A50/2324 ,  Y02A50/2341 ,  Y02T10/22 ,  Y10S502/525 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/72 ,  B01J2523/821 ,  B01J2523/822 ,  B01J2523/824 ,  B01J2523/847 ,  B01J2523/23 ,  B01J2523/845 ,  B01J2523/17 ,  B01J2523/828 ,  B01J2523/842 ,  B01J2523/25 ,  B01J2523/67 ,  B01J2523/13 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/3725

摘要： Perovskite-type catalyst consists essentially of a metal oxide composition and methods of using them are provided. The metal oxide composition is represented by the general formula Aa−xBxMOb, in which A is a mixture of elements originally in the form of single phase mixed lanthanides collected from bastnasite; B is a divalent or monovalent cation; M is at least one element selected from the group consisting of elements of an atomic number of from 23 to 30, 40 to 51, and 73 to 80; a is 1 or 2; b is 3 when a is 1 or b is 4 when a is 2; and x is a number defined by 0≦x

摘要翻译： 钙钛矿型催化剂基本上由金属氧化物组合物组成，并且提供使用它们的方法。 金属氧化物组合物由通式A表示，其中A是原始形式的元素的混合物 从膨润土收集的单相混合镧系元素; B是二价或一价阳离子; M为选自23至30,40至51和73至80的原子序数的元素中的至少一种元素; a是1或2; 当a为1时，b为3，当a为2时，b为4; x是由0 <= x <0.5定义的数字。 还提供了制备和使用钙钛矿型催化剂的方法。 钙钛矿型催化剂可用于减少来自机动车辆的废气中的氮氧化物，氧化一氧化碳和氧化碳氢化合物。 提供了这种使用的方法。

公开(公告)号：US20050249653A1

公开(公告)日：2005-11-10

申请号：US10520068

申请日：2003-07-03

申请人： Hirohisa Tanaka ,  Kimiyoshi Kaneko

发明人： Hirohisa Tanaka ,  Kimiyoshi Kaneko

IPC分类号： F01N3/10 ,  B01D53/94 ,  B01J23/00 ,  B01J23/63 ,  B01J23/89 ,  B01J37/02 ,  C01B13/32 ,  C01G49/00 ,  C01G53/00 ,  C01G55/00 ,  C01F17/00

CPC分类号： C01G51/006 ,  B01D53/945 ,  B01J23/002 ,  B01J23/63 ,  B01J37/0215 ,  B01J2523/00 ,  C01G49/0018 ,  C01G49/0054 ,  C01G49/009 ,  C01G53/006 ,  C01P2002/34 ,  C01P2002/54 ,  C01P2006/12 ,  C01P2006/80 ,  Y02T10/22 ,  Y10S502/525 ,  B01J2523/18 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/72 ,  B01J2523/821 ,  B01J2523/828 ,  B01J2523/3712 ,  B01J2523/824 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/822 ,  B01J2523/23 ,  B01J2523/3718 ,  B01J2523/22 ,  B01J2523/25 ,  B01J2523/3725 ,  B01J2523/36 ,  B01J2523/847 ,  B01J2523/17 ,  B01J2523/827 ,  B01J2523/24

摘要： To provide a highly safe and hygienic method for industrially efficiently producing a perovskite-type composite oxide at low temperatures in heat treatment, in which the resulting perovskite-type composite oxide can maintain the catalytic activity of a noble metal at a high level over a long time, in a method for producing a perovskite-type composite oxide, a perovskite-type composite oxide is produced by mixing organometal salts of all elementary components constituting the perovskite-type composite oxide to prepare a precursor of the perovskite-type composite oxide, or mixing one or more organometal salts of part of the elementary components constituting the perovskite-type composite oxide with the other elementary components prepared as alkoxides of the respective elements, a coprecipitate of salts of the respective elements or a citrate complex of the respective elements to prepare a precursor of the perovskite-type composite oxide, and heat-treating the precursor of the perovskite-type composite oxide.

摘要翻译： 为了提供在热处理中在低温下工业上有效生产钙钛矿型复合氧化物的高度安全和卫生的方法，其中所得到的钙钛矿型复合氧化物可以使贵金属在长时间内保持高水平的催化活性 时间，在钙钛矿型复合氧化物的制造方法中，通过混合构成钙钛矿型复合氧化物的所有元素组分的有机金属盐来制备钙钛矿型复合氧化物，制备钙钛矿型复合氧化物的前体，或 将构成钙钛矿型复合氧化物的部分元素的一种或多种有机金属盐与作为各元素的醇盐制备的其它元素组分，各元素的盐的共沉淀物或各元素的柠檬酸络合物进行混合， 钙钛矿型复合氧化物的前体，并对钙钛矿的前体进行热处理 型复合氧化物。

公开(公告)号：US20050223891A1

公开(公告)日：2005-10-13

申请号：US11092345

申请日：2005-03-29

申请人： Yongxian Zeng ,  Divyanshu Acharya ,  Satish Tamhankar ,  Narayanan Ramprasad ,  Ramakrishnan Ramachandran ,  Frank Fitch ,  Donald MacLean ,  Jerry Lin ,  Richard Clarke

发明人： Yongxian Zeng ,  Divyanshu Acharya ,  Satish Tamhankar ,  Narayanan Ramprasad ,  Ramakrishnan Ramachandran ,  Frank Fitch ,  Donald MacLean ,  Jerry Lin ,  Richard Clarke

IPC分类号： B01D53/04 ,  C01B13/02 ,  F23C9/00 ,  F23L7/00 ,  B01D53/22 ,  B01D59/12

CPC分类号： B01D53/04 ,  B01D53/047 ,  B01D2253/10 ,  B01D2256/12 ,  B01D2257/102 ,  B01D2259/40001 ,  C01B13/0259 ,  C01B2210/0046 ,  F23C9/00 ,  F23C2202/30 ,  F23L7/007 ,  F23L2900/07001 ,  Y02E20/322 ,  Y02E20/344 ,  Y02P20/124 ,  Y10S502/525

摘要： Production of oxygen-enriched gas streams is disclosed herein. Air streams contact an oxygen-selective mixed conductor particularly a perovskite material whereby oxygen is retained or adsorbed on the perovskite and can be employed in a variety of processes such as in combusting a fuel gas, heat recovery and boiler related operations.

摘要翻译： 本文公开了富氧气流的生产。 空气流接触氧选择性混合导体，特别是钙钛矿材料，由此氧气保留或吸附在钙钛矿上，可用于燃烧燃气，热回收和锅炉相关操作等各种工艺。

公开(公告)号：US20050201918A1

公开(公告)日：2005-09-15

申请号：US10708565

申请日：2004-03-11

申请人： John Gordon ,  Hachiya Toshinori ,  Shekar Balagopal ,  Sai Bhavaraju

发明人： John Gordon ,  Hachiya Toshinori ,  Shekar Balagopal ,  Sai Bhavaraju

IPC分类号： B01J21/18 ,  C25B9/00 ,  C25B11/00 ,  C25B11/03 ,  C25B11/04 ,  C25B13/00 ,  C25C7/00 ,  C25C7/02 ,  C25C7/04 ,  C25D17/00 ,  C25D17/12 ,  H01M2/14 ,  H01M4/00 ,  H01M4/86 ,  H01M4/90 ,  H01M4/96

CPC分类号： C25B11/0463 ,  C23C18/1216 ,  C23C18/1254 ,  C23C18/127 ,  C23C18/1275 ,  H01M4/8875 ,  H01M4/9016 ,  H01M4/96 ,  H01M8/08 ,  Y10S502/525 ,  Y10S516/901

摘要： An improved gas diffusion electrode composed of a perovskite-type oxide dispersed in a mixture of carbon black and a hydrophobic binder polymer. An improved catalyst for use in the electrochemical reduction of oxygen comprising a perovskite-type compound having alpha and beta sites, and having a greater molar ratio of cations at the beta site. A particularly good reduction catalyst is a neodymium calcium manganite. An improved method of dispersing the catalysts with carbon in a reaction layer of the electrode improves performance of the electrode and the oxygen reduction process. This is provided by adding carbon black to an aqueous solution of metal salts before it is heated to a gel and then to a char and then calcined. Optionally, a quantity of the desired oxide catalyst can be premixed with a portion the carbon before adding the carbon to an aqueous solution of the metal salts to be heated. The amount of premixed metal oxide is chosen in conjunction with the amount of metal salts to provide the desired molar ratio after heating and calcining of the aqueous solution.

摘要翻译： 改进的气体扩散电极，其由分散在炭黑和疏水性粘合剂聚合物的混合物中的钙钛矿型氧化物组成。 用于电化学还原氧的改进的催化剂包括具有α和β位点的钙钛矿型化合物，并且在β位具有更大的阳离子摩尔比。 特别好的还原催化剂是钕钙锰矿。 将电催化剂用碳分散在电极的反应层中的改进方法提高了电极的性能和氧还原过程。 这是通过在金属盐的水溶液加热至凝胶然后加入炭然后煅烧之前将炭黑加入到水溶液中而提供的。 任选地，一定量的所需氧化物催化剂可以在将碳添加到待加热的金属盐的水溶液中之前与碳的一部分预混合。 联合金属盐的量选择预混合金属氧化物的量，以便在加热和煅烧水溶液之后提供所需的摩尔比。

公开(公告)号：US06673691B2

公开(公告)日：2004-01-06

申请号：US10256358

申请日：2002-09-26

申请人： Wei-Wei Zhuang ,  Sheng Teng Hsu

发明人： Wei-Wei Zhuang ,  Sheng Teng Hsu

IPC分类号： G11C1100

CPC分类号： H01L27/101 ,  G11C11/5685 ,  G11C13/0007 ,  G11C2213/31 ,  H01L45/04 ,  H01L45/1233 ,  H01L45/147 ,  H01L45/1641 ,  Y10S502/525

摘要： A method of changing the resistance of a perovskite metal oxide thin film device with a resistance-change-producing pulse includes changing the resistance of the device by varying the duration of a resistance-change-producing pulse.

摘要翻译： 通过电阻变化产生脉冲改变钙钛矿金属氧化物薄膜器件的电阻的方法包括通过改变电阻变化产生脉冲的持续时间来改变器件的电阻。

公开(公告)号：US06372686B1

公开(公告)日：2002-04-16

申请号：US09710378

申请日：2000-11-10

申请人： Stephen J. Golden

发明人： Stephen J. Golden

IPC分类号： B01J2300

CPC分类号： B01J23/8892 ,  B01D53/945 ,  B01J23/002 ,  B01J23/83 ,  B01J2523/00 ,  Y02T10/22 ,  Y10S502/525 ,  B01J2523/17 ,  B01J2523/3706 ,  B01J2523/72 ,  B01J2523/847 ,  B01J2523/24 ,  B01J2523/821 ,  B01J2523/67 ,  B01J2523/845 ,  B01J2523/23 ,  B01J2523/842 ,  B01J2523/824 ,  B01J2523/13 ,  B01J2523/822 ,  B01J2523/828 ,  B01J2523/25

摘要： Perovskite-type catalyst consists essentially of a metal oxide composition is provided. The metal oxide composition is represented by the general formula Aa-xBxMOb, in which A is a mixture of elements originally in the form of single phase mixed lanthanides collected from bastnasite; B is a divalent or monovalent cation; M is at least one element selected from the group consisting of elements of an atomic number of from 23 to 30, 40 to 51, and 73 to 80; a is 1 or 2; b is 3 when a is 1 or b is 4 when a is 2; and x is a number defined by 0≦x

公开(公告)号：US5977017A

公开(公告)日：1999-11-02

申请号：US797578

申请日：1997-02-07

申请人： Stephen J. Golden

发明人： Stephen J. Golden

IPC分类号： B01J23/76 ,  B01D53/94 ,  B01J23/00 ,  B01J23/26 ,  B01J23/34 ,  B01J23/54 ,  B01J23/78 ,  B01J23/83 ,  B01J23/889 ,  B01J23/89 ,  F01N3/10 ,  B01J23/32 ,  B01J23/40 ,  B01J23/58

CPC分类号： B01J23/8892 ,  B01D53/945 ,  B01J23/002 ,  B01J23/83 ,  B01J2523/00 ,  Y02T10/22 ,  Y10S502/525

摘要： A perovskite-type catalyst consists essentially of a metal oxide composition. The metal oxide composition is represented by the general formula A.sub.1-x B.sub.x MO.sub.3, in which A is a mixture of elements originally in the form of single phase mixed lanthanides collected from bastnasite; B is a divalent or monovalent cation; M is at least one element selected from the group consisting of elements of an atomic number of from 23 to 30, 40 to 51, and 73 to 80; a is 1 or 2; b is 3 when a is 1 or b is 4 when a is 2; and x is a number defined by 0.ltoreq.x

摘要翻译： 钙钛矿型催化剂基本上由金属氧化物组合物组成。 金属氧化物组合物由通式A1-xBxMO3表示，其中A是原始以从bastnasite收集的单相混合镧系元素形式的元素的混合物; B是二价或一价阳离子; M为选自23至30,40至51和73至80的原子序数的元素中的至少一种元素; a是1或2; 当a为1时，b为3，当a为2时，b为4; 并且x是由0

公开(公告)号：US5906958A

公开(公告)日：1999-05-25

申请号：US731241

申请日：1996-10-11

申请人： Sang-cheol Park ,  Chan-ho Pak

发明人： Sang-cheol Park ,  Chan-ho Pak

IPC分类号： B01D53/94 ,  B01J23/656 ,  B01J23/32

CPC分类号： B01J23/6562 ,  B01D53/9422 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2042 ,  B01D2255/2073 ,  B01D2255/91 ,  Y10S502/525

摘要： A catalyst for purifying exhaust gases of an automobile engine including a carrier coprecipitated with a material absorbing oxides of nitrogen (NO.sub.x) and an active noble metal wherein the material absorbing oxides of nitrogen is at least one of barium manganese oxide (BaMnO.sub.3) and calcium manganese oxide (CaMnO.sub.3). The carrier coprecipitated with BaMnO.sub.3 or CaMnO.sub.3 shows superior capacity for absorbing oxides of nitrogen. Consequently, a catalyst according to the present invention can effectively purify engine exhaust, even in a lean burn environment.

摘要翻译： 一种用于净化汽车发动机废气的催化剂，其包括与吸收氮氧化物（NOx）和活性贵金属的材料共沉淀的载体，其中吸收氮的氧化物的材料是钡锰氧化物（BaMnO 3）和钙锰 氧化物（CaMnO3）。 与BaMnO3或CaMnO3共沉淀的载体显示出优异的吸收氮氧化物的能力。 因此，根据本发明的催化剂即使在贫燃环境中也能有效地净化发动机排气。