Carbon nanofibers encapsulating metal cobalt, and production method therefor
    76.
    发明授权
    Carbon nanofibers encapsulating metal cobalt, and production method therefor 有权
    封装金属钴的碳纳米纤维及其制备方法

    公开(公告)号:US09505622B2

    公开(公告)日:2016-11-29

    申请号:US14342881

    申请日:2012-09-28

    摘要: This carbon nanofiber is produced by a vapor phase reaction of a carbon oxide-containing raw material gas using a metal oxide powder including a Co oxide as a catalyst, wherein at least one type selected from metal cobalt, carbon-containing cobalt metals, and cobalt-carbon compounds is contained (encapsulated) in the fiber in a wrapped state. This method for producing a carbon nanofiber includes: producing a carbon nanofiber by a vapor phase reaction of a carbon oxide-containing raw material gas using a mixed powder of a Co oxide and a Mg oxide as a catalyst, wherein a mixed powder of CoO and MgO, which is obtained by hydrogen-reducing a mixed powder of Co3O4 and MgO using a reduction gas having a hydrogen concentration in which metal cobalt is not generated, is used as the catalyst.

    摘要翻译: 该碳纳米纤维通过使用包含作为催化剂的Co氧化物的金属氧化物粉末的含碳氧化物的原料气体的气相反应而制造,其中,选自金属钴,含碳钴金属和钴中的至少一种 碳化合物以包裹的状态包含(包封)在纤维中。 该碳纳米纤维的制造方法包括:使用Co氧化物和Mg氧化物的混合粉末作为催化剂,通过含碳氧化物的原料气体的气相反应制造碳纳米纤维,其中将CoO和 使用通过使用不产生金属钴的氢浓度的还原气体来还原Co 3 O 4和MgO的混合粉末而获得的MgO作为催化剂。

    Solvent-based methods for production of graphene nanoribbons
    77.
    发明授权
    Solvent-based methods for production of graphene nanoribbons 有权
    用于生产石墨烯纳米带的基于溶剂的方法

    公开(公告)号:US09493355B2

    公开(公告)日:2016-11-15

    申请号:US14345016

    申请日:2012-09-14

    摘要: The present invention provides methods of preparing functionalized graphene nanoribbons. Such methods include: (1) exposing a plurality of carbon nanotubes (CNTs) to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to an electrophile to form functionalized graphene nanoribbons (GNRs). The methods may also include a step of exposing the opened CNTs to a protic solvent to quench any reactive species on them. Additional methods include preparing unfunctionalized GNRs by: (1) exposing a plurality of CNTs to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to a protic solvent to form unfunctionalized GNRs.

    摘要翻译: 本发明提供了制备官能化石墨烯纳米带的方法。 这些方法包括:(1)在非质子溶剂的存在下将多个碳纳米管(CNT)暴露于碱金属源以将其打开; 和(2)将开放的CNT暴露于亲电子试剂以形成官能化的石墨烯纳米带(GNR)。 所述方法还可以包括将开放的CNT暴露于质子溶剂以淬灭其上的任何反应性物质的步骤。 另外的方法包括:通过以下步骤制备未官能化的GNR:(1)在非质子溶剂存在下将多个CNT暴露于碱金属源以打开它们; 和(2)将开放的CNT暴露于质子溶剂以形成未官能化的GNR。

    Hierarchical carbon nano and micro structures
    80.
    发明授权
    Hierarchical carbon nano and micro structures 有权
    分层碳纳米微结构

    公开(公告)号:US09221684B2

    公开(公告)日:2015-12-29

    申请号:US14114819

    申请日:2012-05-03

    申请人: Michael De Volder

    发明人: Michael De Volder

    摘要: Disclosed are methods for fabricating pyrolysed carbon nanostructures. An example method includes providing a substrate, depositing a polymeric material, subjecting the polymeric material to a plasma etching process to form polymeric nanostructures, and pyrolysing the polymeric nanostructures to form carbon nanostructures. The polymeric material comprises either compounds with different plasma etch rates or compounds that can mask a plasma etching process. The plasma etching process may be an oxygen plasma etching process.

    摘要翻译: 公开了制备热解碳纳米结构的方法。 示例性方法包括提供基底,沉积聚合物材料,使聚合物材料进行等离子体蚀刻工艺以形成聚合物纳米结构,以及热解聚合物纳米结构以形成碳纳米结构。 聚合物材料包括具有不同等离子体蚀刻速率的化合物或可掩蔽等离子体蚀刻工艺的化合物。 等离子体蚀刻工艺可以是氧等离子体蚀刻工艺。