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公开(公告)号:US20210071041A1
公开(公告)日:2021-03-11
申请号:US16959539
申请日:2019-02-26
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Vasav Sahni , David T. Amos , Jason D. Clapper , John W. McAllister , Zhong Chen , Pierre R. Bieber , Jacob P. Johnson , Albert I. Everaerts
IPC: C09J7/38 , C08F110/10 , C08L51/06 , C08K5/01
Abstract: An adhesive composition are articles are described. The adhesive composition comprises a polyisobutylene polymer component; up to 20 wt.-% of a polyolefin copolymer comprising polymerized units of an acidic monomer; and optionally, at least one tackifier. The polyolefin copolymer typically comprises C2-C4 alkylene units. The polyolefin copolymer comprises polymerized units of a carboxylic acid, or unsaturated derivative thereof. In some embodiments, the polyolefin copolymer has a melting temperature ranging from 50 to 150° C. In some embodiments, the polyolefin copolymer has an acid number of less than 40, 35, 30, or 25 mgKOH/g.
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公开(公告)号:US20190249044A1
公开(公告)日:2019-08-15
申请号:US16392332
申请日:2019-04-23
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jason D. Clapper , Arlin L. Weikel , Thu-Van T. Tran , Kevin M. Lewandowski , David A. Gries , Daniel J. Renninger
IPC: C09J133/08 , C09J7/38 , C09J7/10 , C08F230/08 , C08L33/10 , C08K3/36 , C08L33/08
CPC classification number: C09J133/08 , C08F230/08 , C08K3/36 , C08L33/08 , C08L33/10 , C09J7/10 , C09J7/385 , C09J2423/00 , C09J2433/00 , C09J2433/006 , Y10T428/2848 , Y10T428/2891 , Y10T428/31692 , Y10T428/31938 , C08L23/20
Abstract: This disclosure relates to viscoelastic damping materials and constructions which may demonstrate low temperature performance and adhesion and which may be used in making vibration damping composites. Viscoelastic damping materials and constructions may include polymers or copolymers of monomers according to formula I: CH2═CHR1—COOR2 [I] wherein R1 is H, CH3 or CH2CH3 and R2 is a branched alkyl group containing 12 to 32 carbon atoms.
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公开(公告)号:US10351649B2
公开(公告)日:2019-07-16
申请号:US15638469
申请日:2017-06-30
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jason D. Clapper , Dennis E. Vogel , Ann R. H. Fornof , Babu N. Gaddam
IPC: C08F220/18 , C08F220/26 , C08F220/28 , C09J133/04 , C09J4/00 , C08J3/28 , C09J5/00 , C09J5/06 , C09J133/08 , C09J7/38 , C09J133/06 , C09J133/10 , C08F222/10
Abstract: A composition is described comprising a polymer. The polymer comprises polymerized units derived from a cleavable crosslinking monomer. The cleavable crosslinking monomer comprises at least two free-radically polymerizable groups and at least one group having the formula —O—C(R2)(R3)—O—, wherein R2 and R3 are independently hydrogen, alkyl, or aryl. The composition has a Tg no greater than 50° C. In some embodiments, the composition has a storage modulus greater than 3×105 Pa at 25° C. and 1 Hz and may be characterized as a non-tacky polymer. In other embodiments, the composition is a pressure sensitive adhesive. Upon cleavage of at least a portion of the polymerized monomeric units derived from the cleavable crosslinking monomer, the composition exhibits a change in at least one physical property. In another embodiment, the composition comprises a polymer and fragments. The fragments comprise the reaction product of a free-radically polymerizable group bonded to a polymer chain and a pendent hydroxyl group. The composition has a Tg no greater than 50° C. Also described are articles, comprising the composition described herein (i.e. before and/or after cleavage); as well as methods of making the composition and methods of making articles.
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公开(公告)号:US20180370084A1
公开(公告)日:2018-12-27
申请号:US16061828
申请日:2016-12-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Evan Koon Lun Yuuji Hajime , Jason D. Clapper , Kurt J. Halverson , Myungchan Kang
CPC classification number: B29C35/0266 , B29C35/0805 , B29C59/16 , B29C59/18 , B29C61/02 , B29C71/04 , B29C2035/0827 , B29C2035/0844 , B29C2035/085 , B29C2035/0877 , B81C2201/0154
Abstract: Three-dimensional polymeric article (100) having first (101) and second (102) opposed major surfaces, a first dimension perpendicular to a second dimension, a thickness orthogonal to the first and second dimensions, and a plurality of alternating first (107) and second (109) polymeric regions along the first or second dimensions, wherein the first (107) and second (108) regions extend at least partially across the second dimension, wherein the first regions (107) are in a common plane (115) and wherein some of the second regions (108) project outwardly from the plane (115) in a first direction (generally perpendicular from the plane), and some of the second regions (108) project outwardly from the plane (115) in a second direction that is generally 180 degrees from the first direction, where the first regions (107) have a first crosslink density, wherein the second regions (108) have a second crosslink density, and wherein the second crosslink density of the second regions (108) are less than the first crosslink density of the first regions (107). Embodiments of the articles are useful for example, for providing a dual-sided, textured wrapping film such that greater grip is realized both on an item wrapped by the film and the wrapped item itself.
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公开(公告)号:US20180265748A1
公开(公告)日:2018-09-20
申请号:US15761997
申请日:2016-09-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Ross E. Behling , Jason D. Clapper , Albert I. Everaerts , Chun-Yi Ting , Mark F. Ellis , Karl E. Benson , Jianhui Xia
IPC: C09J7/38 , C08F220/18 , C08J3/24 , C09J7/40
CPC classification number: C09J7/385 , C08F220/18 , C08F265/04 , C08F2220/1825 , C08F2220/1841 , C08F2220/1858 , C08F2220/1891 , C08F2810/20 , C08J3/24 , C08J2333/10 , C09J7/405 , C09J2203/326 , C09J2205/114 , C09J2433/00 , C08F216/36 , C08F220/56 , C08F220/20 , C08F2220/301 , C08F220/34
Abstract: Curable adhesive compositions are provided that can be cured using ultraviolet or visible light radiation. These curable adhesive compositions, which contain a curable (meth)acrylate copolymer, have a creep compliance that is less than 5(10−4) inverse Pascals at 25° C., a creep compliance that is greater than 1(10−3) inverse Pascals at 70° C., and a shear storage modulus greater than 40 kiloPascals when measured at 25° C. at a frequency of 1 radian/second.
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公开(公告)号:US20180231891A1
公开(公告)日:2018-08-16
申请号:US15745737
申请日:2016-09-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jason D. Clapper , Dennis E. Vogel , Ann R. Fornof , Andrew R. Davis , Babu N. Gaddam
IPC: G03F7/20 , C09J133/08 , C08F220/18 , C08F230/00 , C09J143/00 , C08J5/18 , C08J3/28 , C09J7/38
Abstract: A pattern article comprising a copolymer having polymerized units derived from a cleavable crosslinking monomer, to which a pattern is imparted by the release of incipient acid from a thermal acid generator or photoacid generator. The selective release of the acid provides a pattern of high crosslink density and low crosslink density as result of the incipient acid cleaving a portion of the crosslinks.
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公开(公告)号:US10035328B2
公开(公告)日:2018-07-31
申请号:US15034293
申请日:2014-11-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jason D. Clapper , Serkan Yurt , Christopher J. Campbell
IPC: B32B7/12 , C09J4/06 , C09J133/06 , G02F1/1335 , B32B23/04 , B32B23/08 , B32B27/08 , B32B27/30 , B32B27/36 , C08K3/22
CPC classification number: B32B7/12 , B32B23/04 , B32B23/08 , B32B27/08 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2255/26 , B32B2307/412 , B32B2307/416 , B32B2307/42 , B32B2307/732 , B32B2419/00 , B32B2457/20 , B32B2551/00 , C08F8/30 , C08F220/18 , C08K3/22 , C08K2201/011 , C08L33/08 , C09J4/00 , C09J4/06 , C09J133/066 , C09J133/08 , G02F1/133528 , G02F2202/28 , C08F2220/1891 , C08F220/20 , C08F2220/1875 , C08F222/20 , C08F265/06
Abstract: The disclosure describes a curable composition comprising a) a solute (meth) acryloyl oligomer having a plurality of pendent, ethylenically unsaturated, free-radically polymerizable functional groups and nucleophilic, hydrophilic groups, a Mw of 5 k to 30 k. a Tg
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公开(公告)号:US20180162078A1
公开(公告)日:2018-06-14
申请号:US15578150
申请日:2016-07-05
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Evan Koon Lun Yuuji Hajime , Jason D. Clapper , Kurt J. Halverson , Myungchan Kang
CPC classification number: B29C71/0072 , B24D11/00 , B29C61/02 , B29C71/02 , B29C2071/022 , B29K2023/00 , C08J7/06 , C08J2307/02 , C08J2323/02 , C08J2323/08 , C08J2327/06 , C09J5/00 , C09J7/385
Abstract: Article comprising a polymeric substrate having a first major surface comprising a plurality of particles (e.g., clay particles, graphite particles, boron nitride particles, carbon particles, molybdenum disulfide particles, bismuth oxychloride particles, and combinations thereof) attached thereto. Articles described herein are useful, for example, for a tamper evident surface.
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公开(公告)号:US20180118982A1
公开(公告)日:2018-05-03
申请号:US15570786
申请日:2016-04-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Christopher J. Campbell , Albert I. Everaerts , Ross E. Behling , Thomas P. Klun , Jason D. Clapper , Jonathan J. O'Hare , Karl K. Stensvad , Glen A. Jerry , Daniel H. Carlson
IPC: C09J9/00 , C09J133/26 , C09J175/06 , C09J5/00
CPC classification number: C09J9/00 , B05C5/02 , B05D1/26 , C08F220/18 , C08F290/067 , C08G18/246 , C08G18/4238 , C08G18/755 , C09J5/00 , C09J133/08 , C09J133/26 , C09J175/06 , C09J175/16 , C09J2201/622 , C09J2433/00 , C09J2475/00 , C08G18/672 , C08G18/42 , C08F2220/1858 , C08F2220/1825 , C08F220/56 , C08F220/20
Abstract: A viscoelastic adhesive composition is provided, wherein at a dispensing temperature of between 35° C. and 120° C., the viscoelastic adhesive composition can be discretely dispensed and has a tan delta of at least 1 as determined by dynamic mechanical analysis at a frequency of 1 Hz and a complex viscosity of less than 5×103 Pascal-sec at a complex viscosity of less than 5×103Pascal-sec at a frequency of about 10 radians s−1. Such adhesives have been found useful in forming optical assemblies for producing display panels used in a variety of electronic devices.
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公开(公告)号:US09908837B2
公开(公告)日:2018-03-06
申请号:US14769850
申请日:2014-03-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Joshua L. Colby , Aaron E. Hutt , Terence D. Spawn , Jason D. Clapper , Tabitha A. Clem
IPC: C07C1/24 , C07C11/02 , C07C67/04 , C07C69/54 , C08F220/06 , C08F220/18 , C09J133/08
CPC classification number: C07C67/04 , C07C1/24 , C07C2531/08 , C07C2531/10 , C08F220/18 , C09J133/08 , C07C69/54 , C07C11/02 , C08F2220/1825 , C08F220/06
Abstract: Polymers, particularly those used in pressure-sensitive adhesives, are prepared from a mixture of structural isomers of a secondary alkyl (meth)acrylate monomer. The mixture is made by dehydrating a biobased C2-C22 alcohol with a first acid catalyst using a continuous process to form a mixture of olefins, and reacting (meth)acrylic acid with at least some of the mixture of olefins in the presence of a second acid catalyst. The adhesives are characterized by exhibiting an overall balance of adhesive and cohesive characteristics, and containing biobased material.
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