公开(公告)号：US09346674B2

公开(公告)日：2016-05-24

申请号：US11260472

申请日：2005-10-28

Applicant: Myoung-Ki Min ,  Chan-Hee Park ,  Hye-A Kim ,  Chan Kwak ,  Ho-Jin Kweon

Inventor： Myoung-Ki Min ,  Chan-Hee Park ,  Hye-A Kim ,  Chan Kwak ,  Ho-Jin Kweon

IPC: H01M4/90 ,  B82Y30/00 ,  B01J21/18 ,  B01J23/42 ,  B01J37/16 ,  H01M4/86 ,  H01M4/92 ,  H01M8/10 ,  B01J33/00 ,  B01J35/00

CPC classification number: B82Y30/00 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J33/00 ,  B01J35/006 ,  B01J37/16 ,  H01M4/8605 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0217 ,  H01M8/1007 ,  Y02E60/523 ,  Y02P70/56

Abstract: The catalyst for a fuel cell of the present invention includes a compound including at least one element selected from the group consisting of silicon, aluminum, and titanium, and a catalytic metal.

公开(公告)号：US20160136632A1

公开(公告)日：2016-05-19

申请号：US14854191

申请日：2015-09-15

Applicant: University of South Carolina

Inventor： John Monnier ,  John Regalbuto ,  Kerry O'Connell

IPC: B01J35/02 ,  B01J23/52 ,  C01B3/40 ,  C07C17/02 ,  C01B17/50 ,  B01J23/42 ,  B01J23/40

CPC classification number: B01J35/026 ,  B01J23/40 ,  B01J23/42 ,  B01J23/52 ,  B01J23/70 ,  B01J23/89 ,  B01J35/0006 ,  B01J35/008 ,  B01J37/08 ,  B01J37/16 ,  C01B3/40 ,  C01B17/502 ,  C01B2203/0238 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  C07C17/08 ,  Y02P20/142 ,  Y02P20/52 ,  C07C21/06

Abstract: Supported, bimetallic catalyst systems are provided. The supported, bimetallic catalyst system can include a support defining a surface; a core metal positioned on the surface of the support; and a shell metal positioned on the core metal to form a core-shell particle on the surface of the support. The core metal has a surface free energy that is higher than a surface free energy of the shell metal. Methods are also provided for the formation of such supported, bimetallic catalyst systems, as well as the use of such supported, bimetallic catalyst systems in chemical processes.

Abstract translation: 提供了支持的双金属催化剂体系。 负载的双金属催化剂体系可以包括限定表面的载体; 位于支撑体表面上的芯金属; 以及位于所述芯金属上的壳金属，以在所述支撑体的表面上形成核 - 壳颗粒。 核心金属具有高于壳金属的表面自由能的表面自由能。 还提供了用于形成这种负载的双金属催化剂体系的方法，以及在化学方法中使用这种负载的双金属催化剂体系。

公开(公告)号：US20160121302A1

公开(公告)日：2016-05-05

申请号：US14897940

申请日：2014-06-12

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA ,  CATALER CORPORATION

Inventor： Akira MORIKAWA ,  Kae KONISHI ,  Toshitaka TANABE ,  Akihiko SUDA ,  Masahide MIURA ,  Hiromasa SUZUKI ,  Isao CHINZEI ,  Akiya CHIBA ,  Kosuke IIZUKA

IPC: B01J23/10 ,  B01J37/16 ,  B01J37/12 ,  B01J37/00

CPC classification number: B01J23/10 ,  B01J37/0009 ,  B01J37/12 ,  B01J37/16 ,  C01G25/00 ,  C01P2002/50 ,  C01P2002/74 ,  C01P2004/61 ,  C01P2006/12 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/3706 ,  B01J2523/36 ,  B01J2523/3718

Abstract: A ceria-zirconia-based composite oxide including a composite oxide containing ceria and zirconia, wherein the ceria-zirconia-based composite oxide contains at least one member selected from the group consisting of praseodymium, lanthanum, and yttrium in an amount of 0.5 to 5.0 mol % relative to a total amount of the cations contained in the ceria-zirconia-based composite oxide, where the ratio of the content of both cerium and the at least one member selected from the group consisting of praseodymium, lanthanum, and yttrium in the ceria-zirconia-based composite oxide to the content of zirconium therein ([cerium and the at least one member selected from the group consisting of praseodymium, lanthanum, and yttrium]:[zirconium]) is in the range of 43:57 to 48:52 by mole ratio.

Abstract translation: 一种二氧化铈 - 氧化锆系复合氧化物，其包含含有二氧化铈和氧化锆的复合氧化物，其中所述二氧化铈 - 氧化锆系复合氧化物含有选自镨，镧和钇中的至少一种，其含量为0.5〜5.0 相对于二氧化铈 - 氧化锆类复合氧化物中所含的阳离子的总量的摩尔％，其中铈和选自镨，镧和钇中的至少一种的含量在 二氧化铈 - 氧化锆基复合氧化物与其中锆的含量（[铈和选自镨，镧和钇中的至少一种]：[锆]）在43:57至48的范围内 ：52摩尔比。

公开(公告)号：US09328036B2

公开(公告)日：2016-05-03

申请号：US14270057

申请日：2014-05-05

Applicant: UOP LLC

Inventor： Susie C. Martins ,  Erin M. Broderick ,  Douglas A. Nafis ,  Kaitlin M. DeSalvo ,  Stuart Smith ,  Alakananda Bhattacharyya

IPC: C07C2/60 ,  C07C2/62 ,  C07C2/68 ,  C07C2/70

CPC classification number: C07C2/62 ,  B01J27/053 ,  B01J27/08 ,  B01J27/16 ,  B01J27/28 ,  B01J27/285 ,  B01J27/30 ,  B01J27/32 ,  B01J31/0284 ,  B01J31/0288 ,  B01J35/12 ,  B01J37/16 ,  B01J38/56 ,  B01J38/60 ,  C07C2/60 ,  C07C2527/125 ,  C07C2531/02 ,  C07C2531/22 ,  C10G50/00 ,  C10G2300/1092 ,  C10G2400/02 ,  Y02P20/584 ,  C07C9/21

Abstract: A hydrocarbon conversion process is described. The process includes contacting a hydrocarbon feed with an acidic catalyst under hydrocarbon conversion conditions in a hydrocarbon conversion zone. The hydrocarbon feed reacts to form a mixture comprising reaction products, the acidic catalyst, and deactivated acidic catalyst containing conjunct polymer. The mixture is separated into at least two streams, a first stream comprising the reaction products and a second stream comprising the deactivated acidic catalyst. The reaction products are recovered. The deactivated acidic catalyst is contacted with at least one silane or borane compound in a regeneration zone under regeneration conditions, the conjunct polymer reacting with the at least one silane or borane compound resulting in a catalyst phase and an organic phase containing the conjunct polymer and at least one silyl or boryl compound.

Abstract translation: 描述烃转化方法。 该方法包括在烃转化区的烃转化条件下使烃进料与酸性催化剂接触。 烃进料反应形成包含反应产物，酸性催化剂和含有结合聚合物的失活酸性催化剂的混合物。 将混合物分离成至少两股物流，包含反应产物的第一物流和包含失活的酸性催化剂的第二料流。 回收反应产物。 失活的酸性催化剂在再生条件下在再生区中与至少一种硅烷或硼烷化合物接触，该结合聚合物与至少一种硅烷或甲硼烷化合物反应，产生催化剂相和含有结合聚合物的有机相， 至少一种甲硅烷基或硼基化合物。

公开(公告)号：US09266094B2

公开(公告)日：2016-02-23

申请号：US14240056

申请日：2012-08-29

Applicant: Michael Merkel ,  Karl-Heinz Wilke ,  Peter Lehner

Inventor： Michael Merkel ,  Karl-Heinz Wilke ,  Peter Lehner

IPC: B01J23/648 ,  C07C209/36 ,  B01J37/02 ,  B01J23/62 ,  B01J23/64 ,  B01J35/00 ,  B01J35/10 ,  B01J27/055 ,  B01J27/10 ,  B01J37/16 ,  B01J37/18

CPC classification number: B01J23/6482 ,  B01J23/62 ,  B01J23/64 ,  B01J27/055 ,  B01J27/10 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/16 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/36 ,  Y02P20/52 ,  B01J2523/13 ,  B01J2523/44 ,  B01J2523/55 ,  B01J2523/824 ,  C07C211/46

Abstract: The present invention relates to a catalyst comprising a ceramic support with a BET surface area of less than 40 m2/g and (a) 1.0 to 100 g of at least one metal of groups 8 to 12 of the periodic table of the elements, (b) 1.0 g to 100 g of at least one metal of groups 4 to 6 and 12 of the periodic table of the elements and (c) 1.0 g to 100 g of at least one metal of groups 14 and 15 of the periodic table of the elements per liter of bulk volume of the ceramic support, wherein the catalyst is additionally doped with (d) potassium in a content of from 0.0050% by weight to 0.20% by weight, based on the total weight of the catalyst. The present invention also provides the use of such a catalyst in the catalytic gas phase hydrogenation of nitroaromatics.

Abstract translation: 本发明涉及一种催化剂，其包含BET表面积小于40m 2 / g的陶瓷载体和（a）元素周期表中至少一种第8至12族金属的至少一种金属的至少一种金属（ b）将1.0g至100g元素周期表第4至6和12族的至少一种金属和（c）1.0g至100g元素周期表第14和15族的至少一种金属 每升体积的陶瓷载体的元素，其中催化剂另外掺有（d）含量为0.0050重​​量％至0.20重量％的钾，基于催化剂的总重量。 本发明还提供了这种催化剂在硝基芳族化合物的催化气相氢化中的用途。

公开(公告)号：US09259715B2

公开(公告)日：2016-02-16

申请号：US14436372

申请日：2013-10-16

Applicant: ARCHER DANIELS MIDLAND COMPANY

Inventor： Kevin Martin ,  Josh Terrian ,  Leandra Vircks

IPC: B01J23/889 ,  B01J35/00 ,  C07C29/60 ,  B01J21/18 ,  B01J37/16

CPC classification number: B01J23/8896 ,  B01J21/18 ,  B01J35/0006 ,  B01J37/16 ,  C07C29/60 ,  C07C31/205

Abstract: A hydrogenation catalyst comprising nickel, rhenium, and cadmium is disclosed. Process of using hydrogenation catalyst for producing propylene glycol from polyol feedstock are also disclosed. The present invention relates generally to catalysts and more particularly, to catalysts having an enhanced ability to produce propylene glycol from sugar alcohols while reducing the production of by-products.

Abstract translation: 公开了一种包含镍，铼和镉的氢化催化剂。 还公开了使用氢化催化剂从多元醇原料生产丙二醇的方法。 本发明一般涉及催化剂，更具体地说，涉及具有增强从糖醇生产丙二醇的能力同时减少副产物生产的催化剂。

公开(公告)号：US20160008790A1

公开(公告)日：2016-01-14

申请号：US14772880

申请日：2013-05-28

Applicant: OSAKA GAS CO., LTD.

Inventor： Susumu Takami ,  Hirofumi Ohtsuka ,  Takenori Hirano

IPC: B01J23/46 ,  C01B3/40 ,  B01J37/02 ,  B01J35/00 ,  B01J23/63 ,  B01J37/08

CPC classification number: B01J23/468 ,  B01J23/46 ,  B01J23/63 ,  B01J35/0006 ,  B01J37/0201 ,  B01J37/035 ,  B01J37/08 ,  B01J37/16 ,  B01J2523/00 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/142 ,  Y02P20/52 ,  B01J2523/31 ,  B01J2523/3725 ,  B01J2523/827 ,  B01J2523/828

Abstract: For implementing a reforming reaction such as steam reforming or autothermal reforming, to obtain hydrogen, carbon monoxide, carbon dioxide, methane, etc. by bringing hydrocarbons and steam into contact with a reforming catalyst, an arrangement is provided to enable reforming of the hydrocarbon to proceed under a stable condition for an extended period thanks to high sulfur resistance thereof. The arrangement employs a reforming catalyst supporting both platinum and iridium on an inorganic oxide support for the reforming of the hydrocarbon.

Abstract translation: 为了实现诸如蒸汽重整或自热重整的重整反应，通过使烃和蒸汽与重整催化剂接触来获得氢气，一氧化碳，二氧化碳，甲烷等，提供了使烃重整为 由于其高耐硫性，在稳定的条件下进行延长的时间。 该装置采用在无机氧化物载体上负载铂和铱的重整催化剂用于烃的重整。

公开(公告)号：US09233356B2

公开(公告)日：2016-01-12

申请号：US14626374

申请日：2015-02-19

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Satoshi Nagao ,  Naotaka Sawada ,  Yusaku Inatomi

IPC: B01J23/40 ,  B01J23/42 ,  B01J23/56 ,  B01J23/46 ,  B01J35/00 ,  B01J23/10 ,  B01J37/08 ,  B01J37/16

CPC classification number: B01J23/468 ,  B01D53/9422 ,  B01D2255/1025 ,  B01D2255/1028 ,  B01D2255/2063 ,  B01D2255/2068 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/908 ,  B01J23/10 ,  B01J23/464 ,  B01J23/63 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0211 ,  B01J37/08 ,  B01J37/16 ,  B01J2523/00 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/48 ,  B01J2523/822 ,  B01J2523/827

Abstract: An exhaust gas purification catalyst including a catalyst support and bimetallic particles supported thereon, wherein said bimetallic particles include an at least partial solid solution of rhodium and iridium and have a diffraction peak at 40.66°

Abstract translation: 一种包含催化剂载体和负载在其上的双金属颗粒的废气净化催化剂，其中所述双金属颗粒包括铑和铱的至少部分固溶体，并且在40.66°<2θ时具有衍射峰;在X射线衍射中具有衍射峰， 一个CuKα射线。 一种排气净化催化剂的制造方法，包括在足以还原铑和铱的温度下加热含有铑盐，铱盐和还原剂的混合溶液，由此制造双金属粒子，其包含铑的至少部分固溶体 和铱 并将生产的双金属颗粒支撑在催化剂载体上。

公开(公告)号：US20150372313A1

公开(公告)日：2015-12-24

申请号：US14649145

申请日：2012-12-03

Applicant: Minhua SHAO ,  Brandon Howard SMITH ,  UNITED TECHNOLOGIES CORPORATION

Inventor： Minhua SHAO ,  Brandon Howard SMITH

IPC: H01M4/92 ,  H01M4/90

CPC classification number: H01M4/92 ,  B01J21/18 ,  B01J23/44 ,  B01J23/892 ,  B01J35/008 ,  B01J35/1014 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/009 ,  B01J37/0201 ,  B01J37/06 ,  B01J37/086 ,  B01J37/088 ,  B01J37/16 ,  H01M4/9041

Abstract: A core-shell catalyst includes a porous, palladium-based core particle and a catalytic layer on the particle. The particle can be made by providing a precursor particle that has palladium interspersed with a sacrificial material. At least a portion of the sacrificial material is then removed such that the remaining precursor particle is porous.

Abstract translation: 核 - 壳催化剂包括多孔的钯基核颗粒和颗粒上的催化层。 可以通过提供具有散布有牺牲材料的钯的前体颗粒来制备颗粒。 然后去除牺牲材料的至少一部分，使得剩余的前体颗粒是多孔的。

公开(公告)号：US20150360207A1

公开(公告)日：2015-12-17

申请号：US14803431

申请日：2015-07-20

Applicant: Johnson Matthey PLC

Inventor： Duncan Roy COUPLAND

IPC: B01J21/12 ,  B01J35/04 ,  B01D53/94 ,  B01J37/08 ,  B01D53/86 ,  B01J21/04 ,  B01J37/34

CPC classification number: B01J37/0009 ,  B01D15/08 ,  B01D53/0407 ,  B01D53/8634 ,  B01D53/9436 ,  B01D2255/2092 ,  B01D2255/30 ,  B01D2255/92 ,  B01D2257/60 ,  B01D2257/602 ,  B01J21/04 ,  B01J21/12 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/16 ,  B01J23/40 ,  B01J23/70 ,  B01J35/026 ,  B01J35/04 ,  B01J37/0018 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/08 ,  B01J37/14 ,  B01J37/16 ,  B01J37/18 ,  B01J37/341 ,  B01J37/349 ,  B22F3/1055 ,  B33Y10/00 ,  B33Y70/00 ,  B33Y80/00 ,  C01B21/48 ,  C10G2/00 ,  C10G25/003 ,  C10G45/04 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/705 ,  C21B13/00 ,  C22B9/023 ,  C22B43/00 ,  C22B61/00 ,  Y02P10/295 ,  Y10T428/2982 ,  Y10T428/2991

Abstract: A method for producing a catalyst using an additive layer method includes: (i) forming a layer of a powdered catalyst or catalyst support material, (ii) binding or fusing the powder in said layer according to a predetermined pattern, (iii) repeating (i) and (ii) layer upon layer to form a shaped unit, and (iv) optionally applying a catalytic material to said shaped unit.

Abstract translation: 使用添加层法制造催化剂的方法包括：（i）形成粉末状催化剂或催化剂载体材料层，（ii）根据预定图案将粉末粘合或熔合在所述层中，（iii）重复（ i）和（ii）层上形成成形单元，和（iv）任选地将催化材料施加到所述成形单元。