公开(公告)号：US20180016479A1

公开(公告)日：2018-01-18

申请号：US15545929

申请日：2016-01-12

申请人： NAMICS Corporation

发明人： Satomi KAWAMOTO ,  Yoshihide FUKUHARA ,  Hiromi SONE ,  Atsushi SAITO ,  Toyokazu HOTCHI

IPC分类号： C09J163/04 ,  C09J11/06 ,  C08K3/36 ,  C08K5/3445 ,  C08K5/3437 ,  C09J11/04 ,  C09J7/00

CPC分类号： C09J163/04 ,  C08K3/36 ,  C08K5/3437 ,  C08K5/3445 ,  C08L63/00 ,  C09J7/00 ,  C09J7/10 ,  C09J11/04 ,  C09J11/06 ,  C09J109/02 ,  C09J161/04 ,  C09J163/00 ,  C09J171/10 ,  C09J2203/326 ,  C09J2205/102 ,  C09J2205/114 ,  C09J2423/00 ,  C09J2433/00 ,  C09J2461/00 ,  C09J2463/00 ,  H01L2224/83101

摘要： Provided is a film adhesive which is preferably used as a NCF, void-free, has excellent electrical connectivity and its high reliability, does not develop cracks easily, and has high surface flatness. Also provided is a semiconductor device in which the film adhesive according to the present invention is used as an NCF during the manufacture of the semiconductor device. The film adhesive according to the present invention contains (A) an epoxy resin; (B) a bisphenol F type phenoxy resin; (C) a phenol resin-based curing agent; (D) a modified imidazole compound; (E) a silica filler; (F) oxyquinoline; and (G) a butadiene-acrylonitrile-methacrylic acid copolymer. The content of component (A) is 19.3 to 33.8 parts by mass. The content of component (B) is 7.5 to 9.1 parts by mass. The content of component (D) is 1.915 to 5 parts by mass. The content of component (E) is 30 to 60 parts by mass. The content of component (F) is 2.5 to 10 parts by mass. The liquid epoxy resin of component (A) contains a phenol novolac type epoxy resin and a liquid epoxy resin. The ratio of phenol novolac type epoxy resin to the epoxy resin of component (A) is not less than 46%. The equivalent ratio of component (C) relative to component (A) is 0.25 to 0.75.

公开(公告)号：US09574120B2

公开(公告)日：2017-02-21

申请号：US14357527

申请日：2012-11-09

申请人： Zhengzhou Zhongyuan Applied Technology Research and Development Co., Ltd.

发明人： Deheng Zhang ,  Junshi Kong ,  Wenli Li ,  Huan Wu ,  Yajuan Yang

IPC分类号： C09J147/00 ,  C09J109/02 ,  C09J163/00 ,  C08L9/02 ,  B29C47/00

CPC分类号： C09J147/00 ,  B29C47/0066 ,  C08K3/013 ,  C08L9/02 ,  C08L23/20 ,  C08L63/00 ,  C08L81/04 ,  C09J109/02 ,  C09J163/00 ,  C08K3/0033

摘要： The present invention provides a structural adhesive sheet specifically for use in a mirror base of an automobile interior rear-view mirror and a method for producing the same, said structural adhesive sheet comprises in parts by weight of 20-100 parts of a nitrile-butadiene rubber, 10-70 parts of a partially cured polysulfide adhesive, 5-40 parts of a bisphenol A type epoxy resin, 0.1-2.5 parts of a crosslinking agent, 0.2-2.5 parts of a softening agent, 3-20 parts of a curing agent, 1-10 parts of an accelerator, 20-100 parts of an inorganic filler, and 0.1-3.0 parts of a silane coupling agent. The structural adhesive sheet of the present invention is obtained by subjecting the above-mentioned components to a compounding process and an extrusion film forming process. The advantages of said structural adhesive sheet include good film-forming property, and simple curing process, while having high structural strength, good toughness, and excellent heat-resistance and cold-resistance after cured.

摘要翻译： 本发明提供一种专门用于汽车内部后视镜的镜底的结构粘合片及其制造方法，所述结构粘合片包含20-100份的腈 - 丁二烯的重量份 橡胶，10-70份部分固化的聚硫化物粘合剂，5-40份双酚A型环氧树脂，0.1-2.5份交联剂，0.2-2.5份软化剂，3-20份固化剂 助剂，1-10份促进剂，20-100份无机填料和0.1-3.0份硅烷偶联剂。 本发明的结构粘合片是通过对上述组分进行配混和挤出成膜过程而获得的。 所述结构粘合片的优点包括良好的成膜性和简单的固化过程，同时结构强度高，韧性好，固化后耐热性和耐寒性优异。

公开(公告)号：US08323448B2

公开(公告)日：2012-12-04

申请号：US12679058

申请日：2008-09-05

申请人： Yuki Hisha ,  Kimihiko Yoda

发明人： Yuki Hisha ,  Kimihiko Yoda

IPC分类号： C04B37/00 ,  C09J4/00 ,  C09J101/00 ,  C09J201/00 ,  C08J3/28 ,  B32B7/12 ,  C08K5/16

CPC分类号： C09J109/02 ,  C08K5/098 ,  C08K5/14 ,  C08K5/17 ,  C08K5/29 ,  C08L9/02 ,  C08L33/20 ,  C08L2666/04 ,  C09J4/06

摘要： A two-part type adhesive composition which comprises a first composition comprising (A) a nitrile butadiene rubber having an acrylonitrile content of from 10 to 30%, (B) a polymerizable (meth)acrylic liquid composition, (C) an organic peroxide and (D) a basic compound having an amine structure, and a second composition comprising (E) a reaction condensate of an amine and an aldehyde and (F) a reducing agent containing copper, is provided. In a preferred embodiment, the first composition also contains a photopolymerization initiator. A bonding method using the adhesive composition provides high adhesion and quick curing properties on the second time scale, and a high retention in durability on a high temperature and high humidity test.

摘要翻译： 一种双组分型粘合剂组合物，其包含第一组合物，其包含（A）丙烯腈含量为10至30％的丁腈橡胶，（B）可聚合（甲基）丙烯酸液体组合物，（C）有机过氧化物和 （D）具有胺结构的碱性化合物，和第二组合物，其包含（E）胺和醛的反应缩合物和（F）含铜还原剂的第二组合物。 在优选的实施方案中，第一组合物还含有光聚合引发剂。 使用粘合剂组合物的粘合方法在第二时间尺度上提供高粘合性和快速固化性，并且在高温高湿试验中具有高耐久性保持性。

公开(公告)号：US20100147462A1

公开(公告)日：2010-06-17

申请号：US12706197

申请日：2010-02-16

申请人： Christian Ring ,  Thorsten Krawinkel

发明人： Christian Ring ,  Thorsten Krawinkel

IPC分类号： C09J133/20

CPC分类号： C09J109/02 ,  C08C19/02 ,  C08K3/08 ,  C08L63/00 ,  C08L2666/08 ,  C08L2666/14 ,  C09J7/10 ,  C09J7/35 ,  C09J163/00 ,  C09J2409/00 ,  C09J2463/00 ,  H05K1/0393 ,  H05K3/386 ,  H05K2201/0133 ,  H05K2203/0191 ,  Y10T428/2804 ,  Y10T428/2826

摘要： Heat-activable adhesive tape for producing and further processing flexible conductor tracks, with an adhesive composed at least of a. an acid- or acid anhydride-modified acrylonitrile-butadiene copolymer, and b. an epoxy resin, the weight ratio of the two components a/b being greater than 1.5 and no additional nonpolymer hardener being used.

摘要翻译： 用于制造和进一步处理柔性导体轨道的热激活胶带，其中至少由一种粘合剂组成。 酸或酸酐改性的丙烯腈 - 丁二烯共聚物，和b。 环氧树脂，两种组分a / b的重量比大于1.5，不使用另外的非聚合物硬化剂。

公开(公告)号：US20050215712A1

公开(公告)日：2005-09-29

申请号：US10506490

申请日：2003-08-27

申请人： Kiyofumi Fukasawa ,  Tomohiro Kaise

发明人： Kiyofumi Fukasawa ,  Tomohiro Kaise

IPC分类号： B32B15/06 ,  C08L9/02 ,  C08L23/28 ,  C08L27/04 ,  C08L61/06 ,  C08L65/04 ,  C09J109/02 ,  C09J123/28 ,  C09J161/06 ,  C09J165/00 ,  C09J165/04 ,  C08L71/10

CPC分类号： C09J109/02 ,  B32B15/06 ,  C08L9/02 ,  C08L23/286 ,  C08L27/04 ,  C08L61/06 ,  C08L65/04 ,  C08L2666/02 ,  C08L2666/06 ,  C08L2666/12 ,  C08L2666/16 ,  C08L2666/22 ,  C09J123/286 ,  C09J161/06 ,  C09J165/04 ,  Y10T428/31688 ,  Y10T428/31696

摘要： A vulcanizable adhesive composition, which comprises 100 parts by weight of phenolxylylene resin or phenolbiphenyl resin, 10 to 1,000 parts by weight of resol-type phenol resin, 0 to 1,000 parts by weight of novolak-type phenol resin, 10 to 1,000 parts by weight of unvulcanized nitrile rubber and 10 to 500 parts by weight of chlorinated polyethylene, is effectively applied to (hydrogenated) nitrile rubber with a nitrile content of 18 to 48%, and has a suppression effect on a decrease in the adhesiveness even if exposed to dip in various cryogenic liquids such as flon gas, polyalkylene glycol, water, etc. for a long time.

摘要翻译： 一种可硫化粘合剂组合物，其包含100重量份的苯二酚树脂或苯酚联苯树脂，10至1,000重量份的甲阶酚醛树脂型酚醛树脂，0至1,000重量份的酚醛清漆型酚醛树脂，10至1,000重量份 的未硫化丁腈橡胶和10〜500重量份氯化聚乙烯，有效地应用于腈含量为18〜48％的（氢化）丁腈橡胶，并且即使暴露于浸渍时也具有抑制粘合性降低的作用 在各种低温液体如氟利昂气体，聚亚烷基二醇，水等中长时间使用。

公开(公告)号：US5891566A

公开(公告)日：1999-04-06

申请号：US806448

申请日：1997-02-26

申请人： Yukinori Sakumoto ,  Shigeyuki Yokoyama ,  Akihiro Shibuya ,  Atsushi Koshimura

发明人： Yukinori Sakumoto ,  Shigeyuki Yokoyama ,  Akihiro Shibuya ,  Atsushi Koshimura

IPC分类号： C08L9/02 ,  C08L79/08 ,  C09J7/02 ,  C09J7/04 ,  C09J109/02 ,  C09J121/02 ,  C09J161/06 ,  H01L23/495 ,  B32B7/12

CPC分类号： H01L23/49558 ,  C09J109/02 ,  C09J121/02 ,  C09J161/06 ,  C09J7/0246 ,  C09J7/0282 ,  C09J7/045 ,  C08L79/08 ,  C08L9/02 ,  C09J2201/122 ,  C09J2479/086 ,  H01L2924/0002 ,  Y10T156/1093 ,  Y10T29/49208 ,  Y10T428/28 ,  Y10T428/2852 ,  Y10T428/2887 ,  Y10T428/2891 ,  Y10T428/31721

摘要： An adhesive tape for electronic parts, comprising(a) a heat resistant base film, and(b) an adhesive layer laminated on at least one surface of said base film, said adhesive layer comprising(i) a resol type phenol resin, and(ii) an acrylonitrile/butadiene copolymer,in a proportion of from 100 to 500 parts by weight of said resol type phenol resin per 100 parts by weight of said acrylonitrile/butadiene copolymer,said resol type phenol resin being selected from the group consisting of bisphenol A type resins, alkylphenol type resins, phenol type resins and their co-condensed type phenol resins which contain as the phenol component at least one member selected from the group consisting of bisphenol A, alkylphenols and phenol.

摘要翻译： 一种用于电子部件的胶带，包括（a）耐热基膜和（b）层压在所述基膜的至少一个表面上的粘合剂层，所述粘合剂层包括（i）甲阶型酚醛树脂和（ ii）丙烯腈/丁二烯共聚物，相对于每100重量份所述丙烯腈/丁二烯共聚物，所述甲阶酚醛树脂型酚醛树脂为100-500重量份，所述甲阶酚醛树脂型酚醛树脂选自双酚 作为苯酚成分含有选自双酚A，烷基酚，苯酚中的至少1种的树脂，烷基酚型树脂，苯酚型树脂及其共缩合型酚醛树脂。

公开(公告)号：US5863988A

公开(公告)日：1999-01-26

申请号：US768392

申请日：1996-12-18

申请人： Takeshi Hashimoto ,  Katuji Nakaba ,  Jun Tochihira

发明人： Takeshi Hashimoto ,  Katuji Nakaba ,  Jun Tochihira

IPC分类号： C08F8/30 ,  C08F8/42 ,  C09J109/02 ,  C08F8/00

CPC分类号： C08F8/42 ,  C08F8/30 ,  C09J109/02 ,  C08K5/17 ,  C08K5/18 ,  C08K5/544 ,  C08L61/04 ,  H01L2224/32245 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/4826 ,  H01L2224/4911 ,  H01L2224/73215 ,  H01L2224/73265 ,  H01L24/45 ,  H01L24/73 ,  H01L2924/01012 ,  H01L2924/01019 ,  H01L2924/0102 ,  H01L2924/01078 ,  H01L2924/01079 ,  Y10T428/31663

摘要： An adhesive for electronic parts, which can be used for bonding and cured at a relatively low temperature and has sufficient heat resistance and reliability, and an adhesive tape for electronic parts, for which the above adhesive is adapted, the adhesive being a liquid adhesive obtained by dissolving an acrylonitrile-butadiene copolymer as Component (a), a phenolic resin as Component (b), a compound having at least 2 maleimide groups as Component (c) and a diamine compound of the general formula (1) specified in claim 1, and/or a polysiloxane compound terminating with an amino group at each terminal, having a weight average molecular weight of 200 to 7,000 and having the general formula specified in claim 1, as Component (d) in an organic solvent, and in which the total amount of Components (b), (c) and (d) per 100 parts by weight of Component (a) is 10 to 900 parts by weight, the amount of Component (b) based on the total amount of Components (b), (c) and (d) is 10 to 90% by weight, and the amount of amino groups of Component (d) per mole equivalent of the maleimide groups of Component (c) is 0.01 to 2.0 mole equivalents.

摘要翻译： 用于电子部件的粘合剂，其可用于在较低温度下粘合和固化并具有足够的耐热性和可靠性，以及适用上述粘合剂的电子部件用胶带，所述粘合剂是获得的液体粘合剂 通过将作为组分（a）的丙烯腈 - 丁二烯共聚物，作为组分（b）的酚醛树脂，作为组分（c）具有至少2个马来酰亚胺基团的化合物和权利要求1中规定的通式（1）的二胺化合物 ，和/或在每个末端具有氨基的聚硅氧烷化合物，其重均分子量为200-7000，具有权利要求1中规定的通式为有机溶剂中的组分（d），其中 组分（a）每100重量份中组分（b），（c）和（d）的总量为10至900重量份，基于组分（b）总量的组分（b） ，（c）和（d）为10〜90重量％ nd组分（d）每摩尔当量组分（c）的马来酰亚胺基团的氨基的量为0.01-2.0摩尔当量。

公开(公告)号：US5134182A

公开(公告)日：1992-07-28

申请号：US561356

申请日：1990-08-01

申请人： Kwang-Ho Chu

发明人： Kwang-Ho Chu

IPC分类号： C08L9/02 ,  C09J109/02 ,  C09J133/06

CPC分类号： C09J109/02 ,  C09J133/06 ,  C08L9/02

摘要： A composition based upon a blend of lower alkyl or lower alkoxyalkyl polyacrylate ester elastomers with one or more materials selected from liquid butadiene acrylonitrile copolymers and halogenated fire-retardant plasticizers. Blends with the liquid butadiene acrylonitrile copolymers include from about 5 to about 50% by weight of the copolymer and from about 50 to about 95% by weight of the polyacrylate ester elastomer. Blends with the halogenated fire-retardant plasticizer include from about 5 to about 100 parts by weight of the halogenated fire-retardant plasticizer per 100 parts of the polyacrylate ester elastomer. Hydrocarbon-resistant sealant compositions further contain effective amounts of one or more plasticizers in amounts effective to plasticize the blend together with one or more reinforcing materials. Flame-resistant sealant compositions utilize phosphate ester plasticizers and further contain one or more flame-retardant materials including alumina trihydrate, magnesium carbonate and magnesium hydroxide hydrate.

摘要翻译： 一种基于低级烷基或低级烷氧基烷基聚丙烯酸酯弹性体与一种或多种选自液体丁二烯丙烯腈共聚物和卤化阻燃增塑剂的材料的混合物的组合物。 与液体丁二烯丙烯腈共聚物的共混物包括约5至约50重量％的共聚物和约50至约95重量％的聚丙烯酸酯弹性体。 与卤化阻燃增塑剂的混合物包括每100份聚丙烯酸酯弹性体约5至约100重量份的卤化阻燃增塑剂。 耐烃密封剂组合物还含有效量的一种或多种增塑剂，其量有效地使共混物与一种或多种增强材料一起增塑。 耐火密封剂组合物使用磷酸酯增塑剂并且还含有一种或多种阻燃材料，包括三水合氧化铝，碳酸镁和氢氧化镁水合物。

公开(公告)号：US4920176A

公开(公告)日：1990-04-24

申请号：US279680

申请日：1988-12-05

申请人： August H. Jorgensen, Jr.

发明人： August H. Jorgensen, Jr.

IPC分类号： C08K9/04 ,  C08C1/15 ,  C08K9/00 ,  C08L9/04 ,  C08L21/02 ,  C09D7/12 ,  C09D109/04 ,  C09J109/02 ,  C09J109/04 ,  C09J121/00 ,  H01B3/28

CPC分类号： C08C1/15 ,  C09J109/02

摘要： Nitrile rubber emulsion latexes containing anionic emulsifying aids such as surfactants are treated with large amounts of cationic polymeric coagulants to form innocuous water insoluble residues. The polymeric coagulants chemically react with the anionic emulsifying aids by forming polymer adducts whereby the adducts are physically maintained in the nitrile rubber. The need for complete or thorough washing steps, which is generally tedious, expensive, and commercially impractical, is thus reduced or eliminated. Moreover, the dried latex particles have been found to have improved properties such as water resistance, adhesion, and the like.

公开(公告)号：US4160757A

公开(公告)日：1979-07-10

申请号：US772882

申请日：1977-02-28

申请人： Toshio Honda ,  Yukio Fukuura ,  Shoji Tanaka ,  Itsuo Tanuma ,  Yoshikatsu Suzuki ,  Hikaru Ishikawa

发明人： Toshio Honda ,  Yukio Fukuura ,  Shoji Tanaka ,  Itsuo Tanuma ,  Yoshikatsu Suzuki ,  Hikaru Ishikawa

IPC分类号： C08L7/00 ,  C08G18/00 ,  C08G18/64 ,  C08L9/02 ,  C08L21/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L75/00 ,  C08L81/00 ,  C08L81/04 ,  C09J109/02 ,  C09J121/00 ,  C09J133/20 ,  C09J175/04 ,  C09J181/04 ,  C08K5/09 ,  C08L9/00 ,  C08L27/00 ,  C08L63/00

CPC分类号： C08G18/6453 ,  C08L81/04 ,  C08L9/02 ,  C09J109/02 ,  C09J133/20 ,  C09J175/04 ,  C09J181/04

摘要： An adhesive composition which shows improved stickiness and adhesive property at room temperature and exhibits an excellent adhering ability in a short time is prepared by compounding(a) an acrylonitrile-containing copolymer having carbon-to-carbon double bond(b) a phenol-polysulfide resin(c) a metal oxide, and(d) a polyfunctional electrophilic reactive compound containing at least two electrophilic reactive groups.

摘要翻译： 通过配合（A）具有碳 - 碳双重键（B）酚醛聚合物的含丙烯腈共聚物（A）的丙烯腈共聚物，制备在室温下显示改善的粘性和粘合性并在短时间内显示出优异的粘着性的粘合剂组合物 树脂（C）金属氧化物，和（D）包含至少两个电子反应组的多功能电解反应化合物。