Surfactants based on monounsaturated fatty alcohol derivatives

    公开(公告)号:US09695385B2

    公开(公告)日:2017-07-04

    申请号:US14770912

    申请日:2014-03-05

    Applicant: Stepan Company

    CPC classification number: C11D1/146 A01N25/00 A01N25/30 C07C305/10

    Abstract: Surfactant compositions comprising an alkoxylate, a sulfate, or ether sulfate of a C10-C12 monounsaturated alcohol are disclosed. The alkoxylate, sulfate, or ether sulfate may derive from undecylenic acid or undecylenic alcohol. Compared with their saturated analogs, the monounsaturated alkoxylates, sulfates, and ether sulfates are less irritating, making them valuable for personal care, laundry, cleaners, and other household applications. Microscopy studies show that the alkoxylates, sulfates, and ether sulfates have favorable phase behavior over a wide range of actives levels, expanding opportunities for products with greater compaction. When combined with cationic surfactants, the alkoxylates, sulfates, and ether sulfates exhibit synergy, and they have improved solubility compared with their saturated analogs. The surfactants find value for the personal care, laundry and cleaning, emulsion polymerization, agricultural products, oilfield applications, and specialty foams industries.

    Rumenic Acid Rich Conjugated Linoleic Acid
    164.
    发明申请

    公开(公告)号:US20170152534A1

    公开(公告)日:2017-06-01

    申请号:US15428339

    申请日:2017-02-09

    Applicant: Stepan Company

    Abstract: A process for preparing a conjugated linoleic acid (CLA) material that is enriched in the cis 9, trans 11 (rumenic acid) CLA isomer. The process involves subjecting a material containing at least 75 weight % CLA moieties to an enzymatic conversion, wherein the enzyme has the ability to discriminate between the cis 9, trans 11 and trans 10, cis 12 isomers. The enzyme is advantageously a lipase derived from Candida rugosa. The resulting CLA product stream is distilled to separate the free fatty acid fraction from the glyceride fraction. The recovered free fatty acid fraction contains about 55 weight % to about 70 weight % of the cis 9, trans 11 isomer (rumenic acid), and has a weight ratio of cis 9, trans 11 isomer to trans 10, cis 12 isomer of at least 3.5:1. The material enriched in rumenic acid may be used in foods, particularly infant formulas, or in food supplements or in pharmaceutical compositions.

    Aromatic polyester polyols and aromatic polyester polyol blends containing biorenewable components and methods of making
    167.
    发明授权
    Aromatic polyester polyols and aromatic polyester polyol blends containing biorenewable components and methods of making 有权
    芳族聚酯多元醇和芳族聚酯多元醇混合物,其中含有生物可再生组分和制备方法

    公开(公告)号:US09309345B2

    公开(公告)日:2016-04-12

    申请号:US13692507

    申请日:2012-12-03

    Applicant: Stepan Company

    Abstract: There are provided aromatic polyester polyol compositions comprising: (i) at least one aromatic acid component; (ii) at least one hydroxylated component; (iii) at least one functionalized natural oil component; and (iv) optionally at least one catalyst component for use in preparing foams. The aromatic polyester polyol compositions can be formed by esterification and/or transesterification. The present technology also provides a polyol blend for use in preparing foams wherein the polyol blend comprises (a) an aromatic polyester polyol formed by an interesterification reaction between (i) a phthalic acid based material; (ii) a hydroxylated material; and (iii) a hydrophobic material, wherein the hydrophobic material is present in an amount of from about 1% to about 50% by weight of the aromatic polyester polyol; and (b) a natural oil based polyol, wherein the hydrophobic material in the aromatic polyester polyol compatibilizes the natural oil based polyol to form a phase stable polyol blend.

    Abstract translation: 提供了芳族聚酯多元醇组合物,其包含:(i)至少一种芳族酸组分; (ii)至少一种羟基化成分; (iii)至少一种官能化天然油组分; 和(iv)任选的至少一种用于制备泡沫的催化剂组分。 芳族聚酯多元醇组合物可以通过酯化和/或酯交换形成。 本技术还提供用于制备泡沫的多元醇共混物,其中多元醇共混物包含(a)通过(i)邻苯二甲酸基材料之间的酯交换反应形成的芳族聚酯多元醇; (ii)羟基化材料; 和(iii)疏水性材料,其中所述疏水性材料以所述芳族聚酯多元醇的约1%至约50%重​​量的量存在; 和(b)天然油基多元醇,其中芳族聚酯多元醇中的疏水性材料与天然油基多元醇相容,形成相稳定的多元醇共混物。

    SURFACTANTS BASED ON MONOUNSATURATED FATTY ALCOHOL DERIVATIVES
    169.
    发明申请
    SURFACTANTS BASED ON MONOUNSATURATED FATTY ALCOHOL DERIVATIVES 审中-公开
    基于MONTHNSATURATED脂肪醇衍生物的表面活性剂

    公开(公告)号:US20160002571A1

    公开(公告)日:2016-01-07

    申请号:US14770912

    申请日:2014-03-05

    Applicant: STEPAN COMPANY

    CPC classification number: C11D1/146 A01N25/00 A01N25/30 C07C305/10

    Abstract: Surfactant compositions comprising an alkoxylate, a sulfate, or ether sulfate of a C10-C12 monounsaturated alcohol are disclosed. The alkoxylate, sulfate, or ether sulfate may derive from undecylenic acid or undecylenic alcohol. Compared with their saturated analogs, the monounsaturated alkoxylates, sulfates, and ether sulfates are less irritating, making them valuable for personal care, laundry, cleaners, and other household applications. Microscopy studies show that the alkoxylates, sulfates, and ether sulfates have favorable phase behavior over a wide range of actives levels, expanding opportunities for products with greater compaction. When combined with cationic surfactants, the alkoxylates, sulfates, and ether sulfates exhibit synergy, and they have improved solubility compared with their saturated analogs. The surfactants find value for the personal care, laundry and cleaning, emulsion polymerization, agricultural products, oilfield applications, and specialty foams industries.

    Abstract translation: 公开了包含C10-C12单不饱和醇的烷氧基化物,硫酸盐或醚硫酸盐的表面活性剂组合物。 烷氧基化物,硫酸盐或醚硫酸盐可衍生自十一碳烯酸或十一碳烯醇。 与其饱和类似物相比,单不饱和烷氧基化物,硫酸盐和醚硫酸盐刺激性较小,使其对个人护理,洗衣,清洁剂和其他家用应用是有价值的。 显微镜研究表明,烷氧基化物,硫酸盐和醚硫酸盐在广泛的活性水平上具有良好的相位行为,扩大了具有更大压实度的产品的机会。 当与阳离子表面活性剂组合时,烷氧基化物,硫酸盐和醚硫酸盐表现出协同作用,并且与饱和类似物相比具有改善的溶解性。 表面活性剂可用于个人护理,洗衣和清洁,乳液聚合,农产品,油田应用和特种泡沫行业。

Patent Agency Ranking