公开(公告)号：US20130102819A1

公开(公告)日：2013-04-25

申请号：US13276403

申请日：2011-10-19

申请人： Normen Szesni ,  Alfred Hagemeyer ,  Frank Grossmann ,  Richard Fischer ,  Michael Urbancic ,  Claus Lugmair ,  Mingyong Sun ,  Hongyi C. Hou ,  David Michael Lowe

发明人： Normen Szesni ,  Alfred Hagemeyer ,  Frank Grossmann ,  Richard Fischer ,  Michael Urbancic ,  Claus Lugmair ,  Mingyong Sun ,  Hongyi C. Hou ,  David Michael Lowe

IPC分类号： C07C5/09 ,  B01J23/50 ,  B01J23/52 ,  B01J31/02 ,  B01J23/62 ,  B01J23/89 ,  B01J23/644 ,  B01J23/58 ,  B01J23/44 ,  B01J23/60

CPC分类号： B01J23/44 ,  B01J21/04 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/60 ,  B01J23/62 ,  B01J23/626 ,  B01J23/628 ,  B01J23/6447 ,  B01J23/8926 ,  B01J31/0277 ,  B01J31/0279 ,  B01J31/0284 ,  B01J35/008 ,  B01J35/1009 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/024 ,  B01J37/16 ,  B01J2231/645 ,  B01J2531/824 ,  C07C7/167 ,  C10G45/40 ,  C10G2400/20 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06

摘要： This invention relates to heterogeneous catalysts useful for selective hydrogenation of unsaturated hydrocarbons, comprising palladium and optionally a promoter, supported on a substrate, having an uncoated BET surface area of ≦9 m2/g, the surface being coated with an ionic liquid. Also described are methods of making the catalysts and methods of selective hydrogenation of acetylene and/or dienes in front-end mixed olefin feed streams.

摘要翻译： 本发明涉及可用于不饱和烃的选择性氢化的非均相催化剂，其包含负载在基材上的钯和任选的助催化剂，其具有未涂覆的BET表面积为9m 2 / g，该表面用离子液体涂覆。 还描述了制备催化剂的方法和在前端混合烯烃进料流中乙炔和/或二烯烃的选择性氢化的方法。

公开(公告)号：US20100261603A1

公开(公告)日：2010-10-14

申请号：US12601900

申请日：2008-05-30

申请人： Alfred Hagemeyer ,  Gerhard Mestl ,  Peter Scheck

发明人： Alfred Hagemeyer ,  Gerhard Mestl ,  Peter Scheck

IPC分类号： B01J23/44 ,  B01J23/52

CPC分类号： B01J37/031 ,  B01J23/44 ,  B01J23/52 ,  B01J23/66 ,  B01J35/008 ,  B01J35/026 ,  B01J37/0221 ,  B01J37/024

摘要： The present invention relates to a process for the production of a shell catalyst which comprises a catalyst support shaped body with an outer shell in which metallic Pd and/or Au is contained. In order to provide a process by means of which shell catalysts can be obtained, in the outer shell of which relatively high metallic Pd and/or Au contents are contained, a process is proposed comprising the steps of a) providing a porous catalyst support shaped body; b) providing a first solution in which a Pd and/or an Au precursor compound is contained; c) providing a second solution in which a Pd and/or a Au precursor compound is contained, wherein the first solution brings about a precipitation of the noble-metal component(s) of the second solution and the second solution a precipitation of the noble-metal component(s) of the first solution; d) loading the catalyst support shaped body with the first and with the second solution; e) converting the noble-metal component(s) precipitated on the catalyst support body into the metal form.

摘要翻译： 本发明涉及一种壳催化剂的制备方法，其包括具有外壳的催化剂载体成形体，其中包含金属Pd和/或Au。 为了提供可以获得壳催化剂的方法，在其包含相对高的金属Pd和/或Au含量的外壳中，提出了一种方法，包括以下步骤：a）提供多孔催化剂载体，其形状 身体; b）提供其中包含Pd和/或Au前体化合物的第一溶液; c）提供其中包含Pd和/或Au前体化合物的第二溶液，其中第一溶液导致第二溶液的贵金属组分的沉淀和第二溶液沉淀贵金属 - 第一溶液的金属组分; d）用第一和第二溶液装载催化剂载体成形体; e）将催化剂载体上沉淀的贵金属组分转化为金属形式。

公开(公告)号：US20100190638A1

公开(公告)日：2010-07-29

申请号：US12602026

申请日：2008-05-30

申请人： Alfred Hagemeyer ,  Gerhard Mestl ,  Peter Scheck ,  Silvia Neumann

发明人： Alfred Hagemeyer ,  Gerhard Mestl ,  Peter Scheck ,  Silvia Neumann

IPC分类号： B01J23/66 ,  B01J23/00 ,  B01J21/08 ,  B01J21/04 ,  B01J21/06 ,  B01J23/20 ,  B01J23/40 ,  B01J23/48 ,  B01J23/44 ,  B01J23/50 ,  B01J23/755 ,  B01J23/72 ,  B01J31/20 ,  B01J23/30 ,  B01J23/58 ,  B01J23/745 ,  B01J8/08

CPC分类号： B01J35/008 ,  B01J23/42 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/08 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0221 ,  B01J37/16

摘要： A method for producing a shell catalyst comprising a porous catalyst support shaped body with an outer shell containing at least one transition metal in metal form. To provide a shell catalyst with a relatively small shell thickness, a device is set up to circulate the catalyst support shaped bodies by means of process gases with a reductive effect. The device is charged with catalyst support shaped bodies that are circulated by means of a process gas with a reductive effect, an outer shell of the catalyst support shaped bodies is impregnated with a transition-metal precursor compound by spraying the circulating catalyst support shaped bodies with a solution containing the transition-metal precursor compound, the metal component of the transition-metal precursor compound is converted into the metal form by reduction by means of the process gas, and the catalyst support shaped bodies sprayed with the solution are dried.

摘要翻译： 一种壳催化剂的制备方法，其包括多孔催化剂载体成型体，其外壳含有至少一种金属形式的过渡金属。 为了提供具有相对小的壳厚度的壳催化剂，设置了一种通过具有还原效应的工艺气体循环催化剂载体成形体的装置。 该装置装有催化剂载体成型体，其通过具有还原作用的工艺气体循环，催化剂载体成形体的外壳用过渡金属前体化合物浸渍，通过将循环催化剂载体成形体喷涂 将过渡金属前体化合物的溶液，过渡金属前体化合物的金属成分通过用工艺气体还原而转变为金属形式，并且将溶液喷射的催化剂载体成形体干燥。

公开(公告)号：US07682598B2

公开(公告)日：2010-03-23

申请号：US10739834

申请日：2003-12-18

申请人： Alfred Hagemeyer ,  Raymond E. Carhart ,  Karin Yaccato ,  Andreas Lesik ,  Christopher James Brooks

发明人： Alfred Hagemeyer ,  Raymond E. Carhart ,  Karin Yaccato ,  Andreas Lesik ,  Christopher James Brooks

IPC分类号： C01B3/16

CPC分类号： C01B3/16 ,  B01J23/58 ,  B01J23/6567 ,  B01J37/0205 ,  B01J2219/00364 ,  B01J2219/00527 ,  B01J2219/00691 ,  B01J2219/00745 ,  B01J2219/00747 ,  C01B2203/0283 ,  C01B2203/1041 ,  C01B2203/1064 ,  C01B2203/107 ,  C40B30/08 ,  C40B40/18 ,  C40B60/14 ,  Y02P20/142 ,  Y02P20/52

摘要： The invention is directed toward methods of using alkali-containing catalysts for generation of hydrogen-rich gas at temperatures of less than about 260° C. A WGS catalyst of the invention may have the following composition: a) at least one of Pt, Ru, their oxides and mixtures thereof; b) Na, its oxides or mixtures thereof; and optionally, c) Li, its oxides and mixtures thereof. The catalysts may be supported on a variety of catalyst support materials. The invention is also directed toward catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation.

摘要翻译： 本发明涉及在小于约260℃的温度下使用含碱催化剂产生富氢气体的方法。本发明的WGS催化剂可以具有以下组成：a）Pt，Ru中的至少一种 ，它们的氧化物及其混合物; b）Na，其氧化物或其混合物; 和任选地，c）Li，其氧化物及其混合物。 催化剂可以负载在各种催化剂载体材料上。 本发明还涉及对氢气产生和一氧化碳氧化具有高活性和选择性的催化剂。

公开(公告)号：US20100022386A1

公开(公告)日：2010-01-28

申请号：US12458652

申请日：2009-07-20

申请人： Alfred Hagemeyer ,  Christopher James Brooks ,  Raymond E. Carhart ,  Karin Yaccato ,  Cory Bernard Phillips ,  Peter Strasser ,  Robert K. Grasselli

发明人： Alfred Hagemeyer ,  Christopher James Brooks ,  Raymond E. Carhart ,  Karin Yaccato ,  Cory Bernard Phillips ,  Peter Strasser ,  Robert K. Grasselli

IPC分类号： B01J23/63 ,  B01J23/10 ,  B01J23/652 ,  B01J23/42 ,  B01J23/64 ,  B01J23/745 ,  B01J23/58

CPC分类号： B01J23/622 ,  B01J23/464 ,  B01J23/56 ,  B01J23/624 ,  B01J23/63 ,  B01J23/6445 ,  B01J23/6525 ,  B01J23/8906 ,  B01J23/8933 ,  B01J23/894 ,  B01J23/8966 ,  B01J23/8973 ,  C01B3/16 ,  C01B2203/00 ,  C01B2203/0283 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1088 ,  C01B2203/1094 ,  C01B2203/1614 ,  Y02P20/52

摘要： A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from:a) Pt, its oxides or mixtures thereof,b) at least one of Fe and Rh, their oxides and mixtures thereof, andc) at least one member selected from the group consisting of Sc, Y, Ti, Zr, V, Nb, Ta, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.

公开(公告)号：US07111802B2

公开(公告)日：2006-09-26

申请号：US10880412

申请日：2004-06-28

申请人： Claus G. Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

发明人： Claus G. Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

IPC分类号： B02C19/12

CPC分类号： B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

摘要： Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

摘要翻译： 公开了用于组合（即，高通量）材料研究的方法和装置，例如催化研究，涉及用于同时进行诸如研磨，混合，压制，粉碎，筛分和/或分级的机械处理的并行装置。 。 所述方法和装置可用于机械处理催化材料和其它固体材料，包括但不限于电子材料如磷光体，着色剂如颜料，以及药物如结晶药物或药物候选物。 同时协议和并行设备在制备材料阵列（例如催化材料）方面提供总体通量的显着改进。

公开(公告)号：US06849243B1

公开(公告)日：2005-02-01

申请号：US09937524

申请日：2000-03-21

申请人： Alfred Hagemeyer ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Günter Dambeck ,  Gerhardt Geiss ,  Andrea Rutsch ,  Stephan Weidlich

发明人： Alfred Hagemeyer ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Günter Dambeck ,  Gerhardt Geiss ,  Andrea Rutsch ,  Stephan Weidlich

IPC分类号： B01J23/52 ,  B01J23/58 ,  B01J23/66 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C67/05 ,  C07C67/055 ,  C07C69/15 ,  C01B21/068 ,  C01B33/06

CPC分类号： B01J23/66 ,  B01J23/52 ,  B01J23/58 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： The invention relates to a supported catalyst and the production and use thereof in the synthesis of vinyl acetate in the gaseous phase from ethylene, acetic acid and oxygen, or from gases containing oxygen, whereby the activity and selectivity are simultaneously improved. The catalyst contains palladium, at least one alkali metal compound and optionally one or more catalyst accelerators, in particular, gold, barium and/or cadmium on a porous support. Said support contains at least one reducible metal oxide, in particular oxides of the elements of groups IIIb, IVb, Vb, VIb from the periodic table of elements. Once the support has been loaded with at least one palladium compound, a reduction is carried out at a temperature of >200° C.

摘要翻译： 本发明涉及负载催化剂及其在乙烯，乙酸和氧气或含氧气体合成乙酸乙烯酯的生产和应用，从而同时改善活性和选择性。 催化剂包含钯，至少一种碱金属化合物和任选的一种或多种催化剂促进剂，特别是多孔载体上的金，钡和/或镉。 所述载体包含至少一种可还原金属氧化物，特别是元素周期表中IIIb，IVb，Vb，VIb族元素的氧化物。 一旦载体上载有至少一种钯化合物，在> 200℃的温度下进行还原

公开(公告)号：US06755364B2

公开(公告)日：2004-06-29

申请号：US09902552

申请日：2001-07-09

申请人： Claus Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

发明人： Claus Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

IPC分类号： B02C1912

CPC分类号： B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

摘要： Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

摘要翻译： 公开了用于组合（即，高通量）材料研究的方法和装置，例如催化研究，涉及用于同时进行诸如研磨，混合，压制，粉碎，筛分和/或分级的机械处理的并行装置。 。 所述方法和装置可用于机械处理催化材料和其它固体材料，包括但不限于电子材料如磷光体，着色剂如颜料，以及药物如结晶药物或药物候选物。 同时协议和并行设备在制备材料阵列（例如催化材料）方面提供总体通量的显着改进。

公开(公告)号：US06191312B1

公开(公告)日：2001-02-20

申请号：US09368081

申请日：1999-08-03

申请人： Alfred Hagemeyer ,  Rolf Peter Schulz ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Heinz Alexander

发明人： Alfred Hagemeyer ,  Rolf Peter Schulz ,  Harald Werner ,  Uwe Dingerdissen ,  Klaus Kühlein ,  Heinz Alexander

IPC分类号： C07C49105

CPC分类号： C07C49/443 ,  B01J29/70 ,  B01J2229/16 ,  C07C45/39

摘要： A process for preparing a bicyclooctanone, in particular 1,5-dialkylbicyclo[3.2.1]octan-8-one, by reacting a bicyclooctanol, in particular dialkylbicyclo[3.2.1]octan-8-ol, with a. a catalyst applied to an active-carbon support and comprising heteropolyoxometallate anions of vanadium, molybdenum and phosphorus, and also a corresponding alkali-metal, alkaline-earth-metal and/or ammonium counter ion, and b. a gaseous, oxygen-containing oxidizing agent.

摘要翻译： 一种通过使双环辛醇，特别是二烷基双环[3.2.1]辛烷-8-醇与二环辛烷酮，特别是1,1-二烷基双环[3.2.1]辛-8-酮的制备方法。 用于活性碳载体并包含钒，钼和磷的杂多金属氧酸盐阴离子的催化剂，以及相应的碱金属，碱土金属和/或铵的离子，和b。 一种气态的含氧氧化剂。

公开(公告)号：US6060035A

公开(公告)日：2000-05-09

申请号：US92058

申请日：1998-06-05

申请人： Joaquim Henrique Teles ,  Norbert Rieber ,  Klaus Breuer ,  Dirk Demuth ,  Hartmut Hibst ,  Alfred Hagemeyer

发明人： Joaquim Henrique Teles ,  Norbert Rieber ,  Klaus Breuer ,  Dirk Demuth ,  Hartmut Hibst ,  Alfred Hagemeyer

IPC分类号： B01J23/08 ,  B01J21/16 ,  B01J23/06 ,  B01J37/03 ,  C01B33/20 ,  C07B41/00 ,  C07B61/00 ,  C07C41/06 ,  C07C41/08 ,  C07C41/54 ,  C07C43/15 ,  C07C43/303 ,  C01B15/14

CPC分类号： B01J21/16 ,  B01J23/06 ,  B01J37/03 ,  C01B33/20 ,  C07B41/00 ,  C07C41/06 ,  C07C41/08 ,  C07C41/54

摘要： Compounds of the formulae I and II ##STR1## are prepared by an addition reaction of a compound of the formula IIIR.sup.1 OH IIIwith an acetylene or allene of the formula IV or V ##STR2## where R.sup.1 and R are as defined, in the gas phase at elevated temperatures in the presence of a heterogeneous, silicate-containing catalyst, by a process in which the catalyst used is one which contains or consists of, as the active component, a zinc silicate obtained by precipitation in aqueous solution from a soluble silicon compound and zinc compound, zinc silicate beinga) an essentially X-ray amorphous zinc silicate of the formula VIZn.sub.a Si.sub.c O.sub.a+2c-0.5e (OH).sub.e.fH.sub.2 O VI, where e is from 0 to 2a+4c and the ratio a:c is from 1 to 3.5, and the ratio f:a is from 0 to 200, and/orb) a crystalline zinc silicate having the structure of hemimorphite of the formula Zn.sub.4 Si.sub.2 O.sub.7 (OH).sub.2.H.sub.2 O.

摘要翻译： 式I和II的化合物通过在存在下在升高的温度下在气相中通过式III R1OHIII的化合物与式IV或V的炔或其中R1和R如所定义的二烯的加成反应来制备， 的不均一硅酸盐催化剂，其中使用的催化剂是含有或由作为活性组分的组成的方法，所述方法是通过在可溶性硅化合物和锌化合物的水溶液中沉淀而获得的硅酸锌，硅酸锌 a）基本上是式VI ZnaSicOa + 2c-0.5e（OH）e.fH2OVI的X射线无定形硅酸锌，其中e为0至2a + 4c，a:c为1至3.5，以及 比例f：a为0至200，和/或b）具有式Zn 4 Si 2 O 7（OH）2·H 2 O的半偏氟结构的结晶硅酸锌。