Method of making a semiconductor with copper passivating film
    21.
    发明授权
    Method of making a semiconductor with copper passivating film 有权
    用铜钝化膜制造半导体的方法

    公开(公告)号:US06287970B1

    公开(公告)日:2001-09-11

    申请号:US09370912

    申请日:1999-08-06

    IPC分类号: H01L2144

    摘要: A method of making a semiconductor device includes the steps of forming an oxide layer adjacent a semiconductor substrate, etching trenches within the oxide layer, depositing a copper layer to at least fill the etched trenches, and forming a copper arsenate layer on the deposited copper layer. The copper arsenate layer is then chemically mechanically polished. The copper layer may be deposited by at least one of electrodeposition, electroplating and chemical vapor deposition. The copper arsenate layer on the surface of the deposited copper layer inhibits oxidation and corrosion and stabilizes the microstructure of the deposited copper layer to thereby eliminate a need to subsequently anneal the deposited copper layer.

    摘要翻译: 制造半导体器件的方法包括以下步骤:在半导体衬底附近形成氧化物层,蚀刻氧化物层内的沟槽,沉积铜层以至少填充蚀刻的沟槽,以及在沉积的铜层上形成砷酸铜层 。 然后将砷酸铜层化学机械抛光。 可以通过电沉积,电镀和化学气相沉积中的至少一种来沉积铜层。 沉积的铜层表面上的砷酸铜层抑制氧化和腐蚀并稳定沉积的铜层的微观结构,从而不需要随后退火沉积的铜层。

    Methods of fabricating an integrated circuit device with composite oxide dielectric
    22.
    发明授权
    Methods of fabricating an integrated circuit device with composite oxide dielectric 有权
    制造具有复合氧化物电介质的集成电路器件的方法

    公开(公告)号:US06235594B1

    公开(公告)日:2001-05-22

    申请号:US09340224

    申请日:1999-06-25

    IPC分类号: H01L21336

    摘要: A method of fabricating an integrated circuit device includes forming a first metal oxide layer adjacent a semiconductor substrate. The first metal oxide layer may be formed of tantalum oxide, for example. A second metal oxide layer, which includes an oxide with a relatively high dielectric constant such as titanium oxide, zirconium oxide, or ruthenium oxide, is formed on the first metal oxide layer opposite the semiconductor substrate, and a metal nitride layer, such as titanium nitride, is formed on the metal oxide layer opposite the first metal oxide layer. The metal nitride layer includes a metal which is capable of reducing the metal oxide of the first metal oxide layer. Thus, the second metal oxide layer substantially blocks reduction of the metal oxide of the first metal oxide layer by the metal of the metal nitride layer.

    摘要翻译: 制造集成电路器件的方法包括:形成与半导体衬底相邻的第一金属氧化物层。 第一金属氧化物层例如可以由氧化钽形成。 在与半导体衬底相对的第一金属氧化物层上形成第二金属氧化物层,其包含氧化钛,氧化锆或氧化钌等介电常数较高的氧化物,金属氮化物层如钛 在与第一金属氧化物层相对的金属氧化物层上形成氮化物。 金属氮化物层包括能够还原第一金属氧化物层的金属氧化物的金属。 因此,第二金属氧化物层通过金属氮化物层的金属基本上阻止第一金属氧化物层的金属氧化物的还原。

    Method of making a capacitor
    23.
    发明授权
    Method of making a capacitor 有权
    制作电容器的方法

    公开(公告)号:US06218255B1

    公开(公告)日:2001-04-17

    申请号:US09277778

    申请日:1999-03-29

    IPC分类号: H01L2120

    摘要: The present invention provides a method for fabricating a capacitor, comprising the steps of forming a trench in a substrate, forming a layer of a first material selected from the group consisting of titanium and titanium nitride in the trench, filling the trench with a conductive material to form a conductive plug, planarizing the substrate, patterning the substrate to partially expose the first material and to create a top portion and a bottom portion to the plug, wherein the bottom portion is in the substrate, and removing the first material from the top portion of the plug.

    摘要翻译: 本发明提供一种制造电容器的方法,包括以下步骤:在衬底中形成沟槽,在沟槽中形成从由钛和氮化钛组成的组中选择的第一材料的层,用导电材料填充沟槽 以形成导电插塞,平坦化基板,图案化基板以部分地暴露第一材料并且产生到插头的顶部部分和底部部分,其中底部部分在基板中,并且从顶部移除第一材料 插头的一部分。

    Method for forming vias in a low dielectric constant material
    24.
    发明授权
    Method for forming vias in a low dielectric constant material 有权
    在低介电常数材料中形成通孔的方法

    公开(公告)号:US06180518B2

    公开(公告)日:2001-01-30

    申请号:US09430226

    申请日:1999-10-29

    IPC分类号: H01L214763

    摘要: A method for making a semiconductor device includes the steps of forming a first conductive layer adjacent a substrate, forming an etch stop layer on the conductive layer, and forming a dielectric layer on the etch stop layer. The dielectric layer includes a material having a low dielectric constant, and a via is formed through the dielectric layer to expose the etch stop layer at the bottom, with porous sidewalls being produced. The exposed etch stop layer is etched using an etchant that cooperates with etched material from the etch stop layer to form a polymeric layer to coat the porous sidewalls of the via. Since the etchant cooperates with the etched material from the etch stop layer to form the polymeric layer coating the porous sidewalls of the via, a separate coating layer deposition step is not required after the via is etched and cleaned. After the porous sidewalls have been coated and polymeric material has been etched from the bottom of the via, a barrier metal layer is formed on the polymeric layer, a seed layer is formed on the barrier metal layer, and a second conductive layer is formed on the seed layer contacting the first conductive layer in the via.

    摘要翻译: 制造半导体器件的方法包括以下步骤:在衬底附近形成第一导电层,在导电层上形成蚀刻停止层,并在蚀刻停止层上形成介电层。 电介质层包括具有低介电常数的材料,并且通过介电层形成通孔以暴露底部的蚀刻停止层,产生多孔侧壁。 使用与蚀刻停止层的蚀刻材料配合的蚀刻剂来蚀刻暴露的蚀刻停止层,以形成聚合物层以涂覆通孔的多孔侧壁。 由于蚀刻剂与来自蚀刻停止层的蚀刻材料配合以形成涂覆通孔的多孔侧壁的聚合物层,在蚀刻和清洁通孔之后不需要单独的涂层沉积步骤。 在已经涂覆多孔侧壁并且已经从通孔的底部蚀刻聚合物材料之后,在聚合物层上形成阻挡金属层,在阻挡金属层上形成种子层,并且在第二导电层上形成第二导电层 种子层与通孔中的第一导电层接触。

    Method for cleaning via openings in integrated circuit manufacturing
    25.
    发明授权
    Method for cleaning via openings in integrated circuit manufacturing 有权
    集成电路制造中通孔的清洗方法

    公开(公告)号:US06169036A

    公开(公告)日:2001-01-02

    申请号:US09276034

    申请日:1999-03-25

    IPC分类号: H01L2100

    摘要: A method is for cleaning via openings during manufacturing of integrated circuits. The method preferably comprises the steps of sputter cleaning the via opening at least once, and exposing the via opening to a reducing atmosphere at least once. The method may include alternatingly repeating the sputter cleaning and exposing steps. The step of sputter cleaning is preferably performed prior to the step of exposing, and a sputter cleaning may be performed after a last step of exposing the via opening to the reducing atmosphere. In one embodiment, the exposed metal portion comprises a metal compound, such as an oxide. Accordingly, the step of sputter cleaning removes at least a portion of the metal oxide, and the step of exposing comprises reducing at least a portion of the metal oxide. The invention is particularly applicable when the metal interconnection layer is a copper, as copper readily oxides at its exposed surface.

    摘要翻译: 一种用于在集成电路制造期间通孔的清洁方法。 该方法优选地包括以下步骤:将通孔开口至少一次溅射清洗,并将通孔开至少一次暴露于还原气氛。 该方法可以包括交替重复溅射清洗和曝光步骤。 溅射清洗的步骤优选在曝光步骤之前进行,并且可以在将通孔打开至还原气氛的最后步骤之后进行溅射清洗。 在一个实施方案中,暴露的金属部分包括金属化合物,例如氧化物。 因此,溅射清洗的步骤除去至少一部分金属氧化物,并且曝光步骤包括还原金属氧化物的至少一部分。 当金属互连层是铜时,本发明特别适用,因为铜在其暴露的表面容易氧化。