ADHESIVE COMPOSITIONS COMPRISING A SILSESQUIOXANE POLYMER CROSSLINKER, ARTICLES AND METHODS

    公开(公告)号:US20170321088A1

    公开(公告)日:2017-11-09

    申请号:US15306200

    申请日:2015-06-08

    Abstract: Pressure sensitive adhesive compositions are described comprising at least one low Tg ethylenically unsaturated monomer, and at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The low Tg ethylenically unsaturated monomer typically has a Tg no greater than 10° C. In some embodiments, the composition comprises at least 50, 55, 60, 65, or 70 wt-% of low Tg ethylenically unsaturated monomer. The low Tg ethylenically unsaturated monomer is typically an alkyl (meth)acrylate comprising 4 to 20 carbon atoms. In another embodiment, an adhesive composition is described comprising a syrup. The syrup comprising i) a free-radically polymerizable solvent monomer; ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers, and iii) at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The free-radically polymerizable solvent monomer, polymerized units of the solute (meth)acrylic polymer, or a combination thereof comprise a low Tg ethylenically unsaturated monomer. Also described are pressure sensitive adhesive articles and method of preparing adhesive articles.

    PRESSURE-SENSITIVE ADHESIVE
    38.
    发明申请

    公开(公告)号:US20170292040A1

    公开(公告)日:2017-10-12

    申请号:US15480429

    申请日:2017-04-06

    Applicant: tesa SE

    Abstract: A powerful pressure-sensitive adhesive which is notable by way of good wetting and dewetting behaviour on surfaces having different surface energies comprises at least 50 wt %, based on the total weight of the pressure-sensitive adhesive, of at least one polymer A which may be derived from the following monomer composition: a1) 55 to 75 wt % of at least one (meth)acrylic ester having a homopolymer glass transition temperature of not more than −60° C. and an alcohol component based on a branched, primary alcohol, having an iso index of 1; a2) 20 to 40 wt % of at least one (meth)acrylic ester having an alcohol component based on a linear C1-C18 alcohol; a3) 5 to 15 wt % of acrylic acid. The pressure-sensitive adhesive of the invention reveals particularly good properties when combined with a foamed carrier.

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