公开(公告)号：US10482364B2

公开(公告)日：2019-11-19

申请号：US16412139

申请日：2019-05-14

Applicant: Nthdegree Technologies Worldwide Inc.

Inventor： Steven B. Roach ,  Richard A. Blanchard ,  Eric W. Kahrs ,  Larry Todd Biggs ,  Chye Kiat Ang ,  Mark D. Lowenthal ,  William J. Ray

IPC: G06K19/07 ,  H01L25/075 ,  G06K19/04

Abstract: In one embodiment, an authentication area on a portable object comprises a random arrangement of printed LEDs and a wavelength conversion layer. The object to be authenticated may be a credit card, casino chip, or other object. When the LEDs are energized during authentication of the object, the emitted spectrum and/or persistence of the wavelength conversion layer is detected and encoded in a first code, then compared to valid codes stored in the database. If there is a match, the object is authenticated. The LED power may be remotely inductively coupled and may flash the LEDs, while the wavelength conversion layer emission slowly decays during its optical detection. The flash of blue LED light may be emitted from the edges of the object, which may act as a light guide, for optical feedback to the user that the object is being authenticated.

公开(公告)号：US09236528B2

公开(公告)日：2016-01-12

申请号：US13763642

申请日：2013-02-09

Applicant: NthDegree Technologies Worldwide Inc. ,  The United States of America as represented by the Administrator of the National Aeronautics and Space Administration

Inventor： William Johnstone Ray ,  Mark D. Lowenthal ,  Neil O. Shotton ,  Richard A. Blanchard ,  Mark Allan Lewandowski ,  Kirk A. Fuller ,  Donald Odell Frazier

IPC: H01L29/205 ,  H01L33/00 ,  H01L29/06 ,  H01L31/00 ,  H01L27/15 ,  H01L29/26 ,  H01L31/12 ,  H01L33/20 ,  B82Y20/00 ,  B82Y30/00 ,  H01L27/32 ,  H01L51/00 ,  H01L51/44 ,  H01L51/52 ,  H01L51/56 ,  H01L31/0232 ,  H01L33/08 ,  H01L31/0352 ,  H01L31/05 ,  H01L31/054 ,  H01L31/068 ,  H01L31/0475

CPC classification number: H01L33/00 ,  B82Y20/00 ,  B82Y30/00 ,  H01L21/30 ,  H01L27/142 ,  H01L27/156 ,  H01L27/32 ,  H01L27/3281 ,  H01L31/0232 ,  H01L31/028 ,  H01L31/0304 ,  H01L31/03044 ,  H01L31/0328 ,  H01L31/0352 ,  H01L31/035281 ,  H01L31/0475 ,  H01L31/05 ,  H01L31/0504 ,  H01L31/0508 ,  H01L31/0512 ,  H01L31/0543 ,  H01L31/0547 ,  H01L31/068 ,  H01L33/08 ,  H01L33/20 ,  H01L33/30 ,  H01L33/32 ,  H01L33/34 ,  H01L33/58 ,  H01L33/60 ,  H01L33/62 ,  H01L51/0096 ,  H01L51/447 ,  H01L51/52 ,  H01L51/5203 ,  H01L51/5265 ,  H01L51/5271 ,  H01L51/5275 ,  H01L51/56 ,  H01L2251/5369 ,  H01L2924/0002 ,  Y02E10/52 ,  Y02E10/547 ,  Y02E10/549 ,  Y02P70/521 ,  H01L2924/00

Abstract: The present invention provides an electronic apparatus, such as a lighting device comprised of light emitting diodes (LEDs) or a power generating apparatus comprising photovoltaic diodes, which may be created through a printing process, using a semiconductor or other substrate particle ink or suspension and using a lens particle ink or suspension. An exemplary apparatus comprises a base; at least one first conductor; a plurality of substantially spherical or optically resonant diodes coupled to the at least one first conductor; at least one second conductor coupled to the plurality of diodes; and a plurality of substantially spherical lenses suspended in a polymer attached or deposited over the diodes. The lenses and the suspending polymer have different indices of refraction. In some embodiments, the lenses and diodes have a ratio of mean diameters or lengths between about 10:1 and 2:1. The diodes may be LEDs or photovoltaic diodes, and in some embodiments, have a junction formed at least partially as a hemispherical shell or cap.

公开(公告)号：US20140138846A1

公开(公告)日：2014-05-22

申请号：US14075089

申请日：2013-11-08

Applicant: Nthdegree Technologies Worldwide Inc.

Inventor： Richard A. Blanchard ,  William J. Ray ,  Mark D. Lowenthal ,  Xiaorong Cai

IPC: H01L21/768 ,  H01L23/48 ,  H01L21/288

CPC classification number: H01L23/481 ,  H01L21/288 ,  H01L21/486 ,  H01L21/76879 ,  H01L21/76882 ,  H01L21/76898 ,  H01L23/49827 ,  H01L23/5226 ,  H01L23/5328 ,  H01L24/05 ,  H01L24/06 ,  H01L24/08 ,  H01L24/19 ,  H01L24/80 ,  H01L24/94 ,  H01L25/0657 ,  H01L25/50 ,  H01L2224/03002 ,  H01L2224/0332 ,  H01L2224/05568 ,  H01L2224/0557 ,  H01L2224/06181 ,  H01L2224/08146 ,  H01L2224/08165 ,  H01L2224/73265 ,  H01L2224/76155 ,  H01L2224/83191 ,  H01L2224/94 ,  H01L2225/06513 ,  H01L2225/06517 ,  H01L2225/06572 ,  H01L2924/12042 ,  H01L2224/03 ,  H01L2224/80 ,  H01L2924/00

Abstract: Vias (holes) are formed in a wafer or a dielectric layer. A low viscosity conductive ink, containing microscopic metal particles, is deposited over the top surface of the wafer to cover the vias. An external force is applied to urge the ink into the vias, including an electrical force, a magnetic force, a centrifugal force, a vacuum, or a suction force for outgassing the air in the vias. Any remaining ink on the surface is removed by a squeegee, spinning, an air knife, or removal of an underlying photoresist layer. The ink in the vias is heated to evaporate the liquid and sinter the remaining metal particles to form a conductive path in the vias. The resulting wafer may be bonded to one or more other wafers and singulated to form a 3-D module.

Abstract translation: 通孔（孔）形成在晶片或电介质层中。 包含微观金属颗粒的低粘度导电油墨沉积在晶片的顶表面上以覆盖通孔。 施加外力以将油墨推入通孔中，包括用于使过孔中的空气排气的电力，磁力，离心力，真空或吸力。 表面上的任何剩余的油墨都被刮刀，纺丝，气刀或下面的光致抗蚀剂层除去。 将通孔中的油墨加热以蒸发液体并烧结剩余的金属颗粒，以在通孔中形成导电路径。 所得到的晶片可以结合到一个或多个其它晶片并且被单个化以形成3-D模块。

公开(公告)号：US20140023907A1

公开(公告)日：2014-01-23

申请号：US13944211

申请日：2013-07-17

Applicant: NthDegree Technologies Worldwide Inc.

Inventor： Vera N. Lockett ,  John G. Gustafson ,  Mark D. Lowenthal ,  William J. Ray

IPC: H01G11/52 ,  H01M2/16

CPC classification number: C01B33/18 ,  B01D21/262 ,  B04B7/12 ,  H01G11/24 ,  H01G11/26 ,  H01G11/36 ,  H01G11/38 ,  H01G11/46 ,  H01G11/52 ,  H01M2/1646 ,  H01M4/62 ,  Y02E60/13

Abstract: A printed energy storage device includes a first electrode, a second electrode, and a separator between the first and the second electrode. At least one of the first electrode, the second electrode, and the separator includes frustules, for example of diatoms. The frustules may have a uniform or substantially uniform property or attribute such as shape, dimension, and/or porosity. A property or attribute of the frustules can also be modified by applying or forming a surface modifying structure and/or material to a surface of the frustules. A membrane for an energy storage device includes frustules. An ink for a printed film includes frustules.

Abstract translation: 印刷储能装置包括第一电极，第二电极和第一和第二电极之间的隔板。 第一电极，第二电极和分离器中的至少一个包括例如硅藻的截头圆锥体。 截头锥体可以具有均匀或基本均匀的性质或属性，例如形状，尺寸和/或孔隙率。 还可以通过将表面改性结构和/或材料施加或形成到截头体的表面来改变截头体的属性或属性。 用于能量存储装置的膜包括截头圆锥体。 用于印刷膜的油墨包括截头圆锥体。

公开(公告)号：US20130146905A1

公开(公告)日：2013-06-13

申请号：US13763642

申请日：2013-02-09

Applicant: NthDegree Technologies Worldwide Inc. ,  U.S. Government as represented by the Administrator of the National Aeronautics and Space Administration

Inventor： William Johnstone Ray ,  Mark D. Lowenthal ,  Neil O. Shotton ,  Richard A. Blanchard ,  Mark Allan Lewandowski ,  Kirk A. Fuller ,  Donald Odell Frazier

IPC: H01L33/20 ,  H01L31/0352

CPC classification number: H01L33/00 ,  B82Y20/00 ,  B82Y30/00 ,  H01L21/30 ,  H01L27/142 ,  H01L27/156 ,  H01L27/32 ,  H01L27/3281 ,  H01L31/0232 ,  H01L31/028 ,  H01L31/0304 ,  H01L31/03044 ,  H01L31/0328 ,  H01L31/0352 ,  H01L31/035281 ,  H01L31/0475 ,  H01L31/05 ,  H01L31/0504 ,  H01L31/0508 ,  H01L31/0512 ,  H01L31/0543 ,  H01L31/0547 ,  H01L31/068 ,  H01L33/08 ,  H01L33/20 ,  H01L33/30 ,  H01L33/32 ,  H01L33/34 ,  H01L33/58 ,  H01L33/60 ,  H01L33/62 ,  H01L51/0096 ,  H01L51/447 ,  H01L51/52 ,  H01L51/5203 ,  H01L51/5265 ,  H01L51/5271 ,  H01L51/5275 ,  H01L51/56 ,  H01L2251/5369 ,  H01L2924/0002 ,  Y02E10/52 ,  Y02E10/547 ,  Y02E10/549 ,  Y02P70/521 ,  H01L2924/00

Abstract: The present invention provides an electronic apparatus, such as a lighting device comprised of light emitting diodes (LEDs) or a power generating apparatus comprising photovoltaic diodes, which may be created through a printing process, using a semiconductor or other substrate particle ink or suspension and using a lens particle ink or suspension. An exemplary apparatus comprises a base; at least one first conductor; a plurality of substantially spherical or optically resonant diodes coupled to the at least one first conductor; at least one second conductor coupled to the plurality of diodes; and a plurality of substantially spherical lenses suspended in a polymer attached or deposited over the diodes. The lenses and the suspending polymer have different indices of refraction. In some embodiments, the lenses and diodes have a ratio of mean diameters or lengths between about 10:1 and 2:1. The diodes may be LEDs or photovoltaic diodes, and in some embodiments, have a junction formed at least partially as a hemispherical shell or cap.

Abstract translation: 本发明提供了一种电子设备，例如包括发光二极管（LED）的发光装置或包括可通过印刷工艺产生的光伏二极管的发电装置，其使用半导体或其它基板颗粒墨水或悬浮液， 使用透镜颗粒墨水或悬浮液。 示例性装置包括基座; 至少一个第一导体; 耦合到所述至少一个第一导体的多个基本球形或光学谐振二极管; 耦合到所述多个二极管的至少一个第二导体; 以及悬挂在连接或沉积在二极管上的聚合物中的多个基本上球形的透镜。 透镜和悬浮聚合物具有不同的折射率。 在一些实施例中，透镜和二极管具有在大约10:1和2:1之间的平均直径或长度的比率。 二极管可以是LED或光伏二极管，并且在一些实施例中，具有至少部分地形成为半球形壳或盖的结。

公开(公告)号：US10402610B2

公开(公告)日：2019-09-03

申请号：US16007189

申请日：2018-06-13

Applicant: Nthdegree Technologies Worldwide Inc.

Inventor： Steven B. Roach ,  Richard A. Blanchard ,  Eric Kahrs ,  Larry Todd Biggs ,  Chye Kiat Ang ,  Mark D. Lowenthal ,  William J. Ray

IPC: G06K7/10 ,  H01L25/075 ,  H01L33/50 ,  G06K19/04 ,  G06K19/07 ,  H01L33/54 ,  H01L33/38 ,  H01L33/62 ,  H02J50/10 ,  H02J5/00 ,  H04B5/00

Abstract: In one embodiment, a printed LED area comprises a random arrangement of printed LEDs and a wavelength conversion layer. The LED area is embedded in an object to be authenticated, such as a credit card or a casino chip. The object may include a light guide for enabling the generated light to be emitted from any portion of the object. In one embodiment, when the LEDs are energized during authentication of the object, the existence of light emitted by the object is sufficient authentication and/or provides feedback to the user that the object is being detected. For added security, the emitted spectrum vs. intensity and persistence of the wavelength conversion layer is detected and encoded in a first code, then compared to valid codes stored in the database. If there is a match, the object is authenticated.

公开(公告)号：US09865767B2

公开(公告)日：2018-01-09

申请号：US14991926

申请日：2016-01-09

Applicant: NthDegree Technologies Worldwide Inc.

Inventor： William Johnstone Ray ,  Mark D. Lowenthal ,  Neil O. Shotton ,  Richard A. Blanchard ,  Mark Allan Lewandowski ,  Kirk A. Fuller ,  Donald Odell Frazier

IPC: H01L33/00 ,  H01L21/30 ,  B82Y20/00 ,  B82Y30/00 ,  H01L27/32 ,  H01L51/00 ,  H01L51/44 ,  H01L51/52 ,  H01L51/56 ,  H01L31/0232 ,  H01L33/08 ,  H01L31/0352 ,  H01L33/20 ,  H01L31/05 ,  H01L31/054 ,  H01L31/068 ,  H01L31/0475 ,  H01L27/142 ,  H01L27/15 ,  H01L31/028 ,  H01L31/0304 ,  H01L31/0328 ,  H01L33/30 ,  H01L33/32 ,  H01L33/34 ,  H01L33/58 ,  H01L33/60 ,  H01L33/62

CPC classification number: H01L33/00 ,  B82Y20/00 ,  B82Y30/00 ,  H01L21/30 ,  H01L27/142 ,  H01L27/156 ,  H01L27/32 ,  H01L27/3281 ,  H01L31/0232 ,  H01L31/028 ,  H01L31/0304 ,  H01L31/03044 ,  H01L31/0328 ,  H01L31/0352 ,  H01L31/035281 ,  H01L31/0475 ,  H01L31/05 ,  H01L31/0504 ,  H01L31/0508 ,  H01L31/0512 ,  H01L31/0543 ,  H01L31/0547 ,  H01L31/068 ,  H01L33/08 ,  H01L33/20 ,  H01L33/30 ,  H01L33/32 ,  H01L33/34 ,  H01L33/58 ,  H01L33/60 ,  H01L33/62 ,  H01L51/0096 ,  H01L51/447 ,  H01L51/52 ,  H01L51/5203 ,  H01L51/5265 ,  H01L51/5271 ,  H01L51/5275 ,  H01L51/56 ,  H01L2251/5369 ,  H01L2924/0002 ,  Y02E10/52 ,  Y02E10/547 ,  Y02E10/549 ,  Y02P70/521 ,  H01L2924/00

Abstract: The present invention provides an electronic apparatus, such as a lighting device comprised of light emitting diodes (LEDs) or a power generating apparatus comprising photovoltaic diodes, which may be created through a printing process, using a semiconductor or other substrate particle ink or suspension and using a lens particle ink or suspension. An exemplary apparatus comprises a base; at least one first conductor; a plurality of diodes coupled to the at least one first conductor; at least one second conductor coupled to the plurality of diodes; and a plurality of lenses suspended in a polymer deposited or attached over the diodes. The lenses and the suspending polymer have different indices of refraction. In some embodiments, the lenses and diodes are substantially spherical, and have a ratio of mean diameters or lengths between about 10:1 and 2:1. The diodes may be LEDs or photovoltaic diodes, and in some embodiments, have a junction formed at least partially as a hemispherical shell or cap.

公开(公告)号：US20170066941A1

公开(公告)日：2017-03-09

申请号：US15237393

申请日：2016-08-15

Applicant: NthDegree Technologies Worldwide Inc.

Inventor： Vera N. Lockett ,  Alexandra E. Hartman ,  John G. Gustafson ,  Mark D. Lowenthal ,  William J. Ray ,  Leila Daneshi

IPC: C09D11/52 ,  C09D11/30 ,  C09D11/03 ,  C09D11/037 ,  C09D11/104

CPC classification number: C09D11/52 ,  C08K3/04 ,  C08K3/041 ,  C08K3/042 ,  C08K3/046 ,  C08K3/08 ,  C08K5/053 ,  C08K5/092 ,  C08K2003/0862 ,  C09D11/03 ,  C09D11/037 ,  C09D11/104 ,  C09D11/30

Abstract: A conductive ink may include a nickel component, a polycarboxylic acid component, and a polyol component, the polycarboxylic acid component and the polyol component being reactable to form a polyester component. The polyester component may be formed in situ in the conductive ink from a polyol component and a polycarboxylic acid component. The conductive ink may include a carbon component. The conductive ink may include an additive component. The conductive ink may include nickel flakes, graphene flakes, glutaric acid, and ethylene glycol. The conductive ink may be printed (e.g., screen printed) on a substrate and cured to form a conductive film. A conductive film may include a nickel component and a polyester component.

Abstract translation: 导电油墨可以包括镍组分，多元羧酸组分和多元醇组分，多元羧酸组分和多元醇组分可反应形成聚酯组分。 聚酯组分可以在多元醇组分和多元羧酸组分的导电油墨中原位形成。 导电油墨可以包括碳成分。 导电油墨可以包括添加剂组分。 导电油墨可以包括镍薄片，石墨烯薄片，戊二酸和乙二醇。 导电油墨可以印刷（例如丝网印刷）在基材上并固化以形成导电膜。 导电膜可以包括镍组分和聚酯组分。

公开(公告)号：US09520598B2

公开(公告)日：2016-12-13

申请号：US14050145

申请日：2013-10-09

Applicant: NthDegree Technologies Worldwide, Inc.

Inventor： Vera N. Lockett ,  John G. Gustafson ,  Alexandra E. Hartman ,  Mark D. Lowenthal ,  William J. Ray

IPC: H01M6/40 ,  C07D233/58 ,  H01M4/06 ,  H01M4/62 ,  H01M2/14 ,  H01M2/16 ,  H01M6/16 ,  H01G11/30 ,  H01G11/36

CPC classification number: H01M6/40 ,  C07D233/58 ,  H01G11/30 ,  H01G11/36 ,  H01M2/145 ,  H01M2/1653 ,  H01M2/166 ,  H01M4/06 ,  H01M4/38 ,  H01M4/502 ,  H01M4/622 ,  H01M4/625 ,  H01M6/164 ,  H01M6/166 ,  H01M2220/30 ,  H01M2300/0045 ,  H01M2300/0085

Abstract: A printed energy storage device includes a first electrode including zinc, a second electrode including manganese dioxide, and a separator between the first electrode and the second electrode, the first electrode, second, electrode, and separator printed onto a substrate. The device may include a first current collector and/or a second current collector printed onto the substrate. The energy storage device may include a printed intermediate layer between the separator and the first electrode. The first electrode, and the second electrode may include 1-ethyl-3-methylimidazolium tetrafluoroborate (C2mimBF4). The first electrode and the second electrode may include an electrolyte having zinc tetrafluoroborate (ZnBF4) and 1-ethyl-3-methylimidazolium tetrafluoroborate (C2mimBF4). The first electrode, the second electrode, the first current collector, and/or the second current collector can include carbon nanotubes. The separator may include solid microspheres.

Abstract translation: 印刷储能装置包括：第一电极，包括锌，第二电极，包括二氧化锰;第一电极和第二电极之间的隔膜;第一电极，第二电极和隔膜;印刷在基板上。 该器件可以包括印刷到衬底上的第一集电器和/或第二集电器。 能量存储装置可以包括在分离器和第一电极之间的印刷中间层。 第一电极和第二电极可以包括1-乙基-3-甲基咪唑鎓四氟硼酸盐（C2mimBF4）。 第一电极和第二电极可以包括具有四氟硼酸锌（ZnBF 4）和1-乙基-3-甲基咪唑鎓四氟硼酸盐（C2mimBF4）的电解质。 第一电极，第二电极，第一集电体和/或第二集电体可以包括碳纳米管。 分离器可以包括固体微球。

公开(公告)号：US09236527B2

公开(公告)日：2016-01-12

申请号：US13746191

申请日：2013-01-21

Applicant: NthDegree Technologies Worldwide Inc. ,  The United States of America as represented by the Administrator of the National Aeronautics and Space Administration

Inventor： William Johnstone Ray ,  Mark D. Lowenthal ,  Neil O. Shotton ,  Richard A. Blanchard ,  Mark Allan Lewandowski ,  Kirk A. Fuller ,  Donald Odell Frazier

IPC: H01L33/08 ,  H01L33/20 ,  B82Y20/00 ,  B82Y30/00 ,  H01L27/32 ,  H01L51/00 ,  H01L51/44 ,  H01L51/52 ,  H01L51/56 ,  H01L31/0232 ,  H01L31/0352 ,  H01L31/05 ,  H01L31/054 ,  H01L31/068 ,  H01L31/0475

CPC classification number: H01L33/00 ,  B82Y20/00 ,  B82Y30/00 ,  H01L21/30 ,  H01L27/142 ,  H01L27/156 ,  H01L27/32 ,  H01L27/3281 ,  H01L31/0232 ,  H01L31/028 ,  H01L31/0304 ,  H01L31/03044 ,  H01L31/0328 ,  H01L31/0352 ,  H01L31/035281 ,  H01L31/0475 ,  H01L31/05 ,  H01L31/0504 ,  H01L31/0508 ,  H01L31/0512 ,  H01L31/0543 ,  H01L31/0547 ,  H01L31/068 ,  H01L33/08 ,  H01L33/20 ,  H01L33/30 ,  H01L33/32 ,  H01L33/34 ,  H01L33/58 ,  H01L33/60 ,  H01L33/62 ,  H01L51/0096 ,  H01L51/447 ,  H01L51/52 ,  H01L51/5203 ,  H01L51/5265 ,  H01L51/5271 ,  H01L51/5275 ,  H01L51/56 ,  H01L2251/5369 ,  H01L2924/0002 ,  Y02E10/52 ,  Y02E10/547 ,  Y02E10/549 ,  Y02P70/521 ,  H01L2924/00

Abstract: The present invention provides an electronic apparatus, such as a lighting device comprised of light emitting diodes (LEDs) or a power generating apparatus comprising photovoltaic diodes, which may be created through a printing process, using a semiconductor or other substrate particle ink or suspension and using a lens particle ink or suspension. An exemplary apparatus comprises a base; at least one first conductor; a plurality of diodes coupled to the at least one first conductor; at least one second conductor coupled to the plurality of diodes; and a plurality of lenses suspended in a polymer deposited or attached over the diodes. The lenses and the suspending polymer have different indices of refraction. In some embodiments, the lenses and diodes are substantially spherical, and have a ratio of mean diameters or lengths between about 10:1 and 2:1. The diodes may be LEDs or photovoltaic diodes, and in some embodiments, have a junction formed at least partially as a hemispherical shell or cap.