公开(公告)号：US20050177017A1

公开(公告)日：2005-08-11

申请号：US10981740

申请日：2004-11-05

申请人： Patrick Euzen ,  Emmanuelle Guillon

发明人： Patrick Euzen ,  Emmanuelle Guillon

IPC分类号： B01J21/12 ,  B01J23/42 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  C07C2/66 ,  C07C5/00 ,  C07C2/68

CPC分类号： B01J21/12 ,  B01J23/42 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  C07C2/66 ,  C07C15/107

摘要： The invention relates to a process for the production of at least one compound that is selected from among the 2-, 3-, 4-, 5-, and 6-phenylalkanes by alkylation of an aromatic compound by means of at least one olefin that comprises at least 9 carbon atoms per molecule, in the presence of a catalyst that comprises at least one non-zeolitic substrate with a silicated alumina base that contains an amount of more than 6% by weight and less than or equal to 50% by weight of silica (SiO2) and that exhibits particular characteristics, whereby said process is carried out at a temperature of between 30 and 400° C., a pressure of between 0.1 and 10 MPa, an hourly volumetric flow rate of 0.50 to 200 h−1, and an aromatic compound/olefin molar ratio of between 1:1 and 50:1.

摘要翻译： 本发明涉及一种通过至少一种烯烃将芳族化合物烷基化制备至少一种选自2-，3-，4-，5-和6-苯基烷烃的化合物的方法， 在每个分子中包含至少9个碳原子的催化剂存在下，所述催化剂包含至少一种非沸石基质，其中硅烷氧化铝基质含量超过6重量％且小于或等于50重量％ 的二氧化硅（SiO 2），并且其表现出特定的特性，由此所述方法在30至400℃的温度下进行，压力为0.1至10MPa，小时体积流速为0.50至200h -1 ，芳香族化合物/烯烃的摩尔比为1：1〜50：1。

公开(公告)号：US06218334B1

公开(公告)日：2001-04-17

申请号：US08973407

申请日：1997-12-15

申请人： Fabio Alario ,  Jean-Marie Deves ,  Patrick Euzen

发明人： Fabio Alario ,  Jean-Marie Deves ,  Patrick Euzen

IPC分类号： B01J2713

CPC分类号： C10G35/09 ,  B01J23/56 ,  B01J23/58 ,  B01J23/63 ,  B01J23/8933 ,  B01J27/13

摘要： The invention relates to a catalyst comprising: a matrix consisting of 0 and 100% by weight of &lgr; transition alumina, the complement up to 100% by weight of the matrix being in &ggr; transition alumina, and relative to the total weight of the catalyst, from 0.001 to 2% by weight of silicon, from 0.1 to 15% by weight of at least one halogen chosen from the group formed by fluorine, chlorine, bromine and iodine, from 0.01 to 2% by weight of at least one noble metal from the platinum group, from 0.005 to 10% by weight of at least one promoter metal chosen from the group formed by tin, germanium, indium, gallium, thallium, antimony, lead, rhenium, manganese, chromium, molybdenum and tungsten, and if required from 0.001 to 10% by weight of a doping metal.

摘要翻译： 本发明涉及一种催化剂，其包括：由0和100重量％的羔羊酸过渡氧化铝组成的基体，所述基体的重量比率高达100重量％，并且相对于催化剂的总重量， 0.001至2重量％的硅，0.1至15重量％的至少一种选自氟，氯，溴和碘的卤素，0.01至2重量％的至少一种贵金属， 选自0.005至10重量％的至少一种选自由锡，锗，铟，镓，铊，锑，铅，铼，锰，铬，钼和钨形成的助催化剂金属， 0.001〜10重量％的掺杂金属。

公开(公告)号：US6045689A

公开(公告)日：2000-04-04

申请号：US973402

申请日：1997-12-15

申请人： Fabio Alario ,  Jean-Marie Deves ,  Patrick Euzen

发明人： Fabio Alario ,  Jean-Marie Deves ,  Patrick Euzen

IPC分类号： B01J23/56 ,  B01J23/63 ,  B01J23/64 ,  B01J27/13 ,  B01J27/135 ,  C10G35/09 ,  C10G35/06 ,  C10G35/085

CPC分类号： C10G35/09 ,  B01J23/56 ,  B01J23/63 ,  B01J27/13

摘要： A process for converting hydrocarbons into aromatic compounds, which entails contacting a composition containing hydrocarbons with a catalyst under temperature and pressure conditions to produce the aromatic compounds, the catalyst containing a matrix of .eta. transition alumina and/or .gamma. transition alumina. The catalyst contains 0.001 to 2 wt % of silicon, 0.1 to 15 wt % of at least one platinum group metal, and 0.005 to 10 wt % of at least one promoter metal. The promoter metals may be tin, germanium, indium, gallium, thallium, antimony, lead, rhenium, manganese, chromium, molybdenium or tungsten. The catalyst may also contain a doping metal.

摘要翻译： PCT No.PCT / FR96 / 00919 Sec。 371 1997年12月15日第 102（e）日期1997年12月15日PCT Filted 1996年6月14日PCT公布。 出版物WO97 / 00306 日期1997年1月3日一种将烃转化为芳族化合物的方法，其需要在温度和压力条件下使含烃的组合物与催化剂接触以产生芳族化合物，所述催化剂含有等离子体氧化铝和/或γ过渡氧化铝 。 催化剂含有0.001〜2重量％的硅，0.1〜15重量％的至少一种铂族金属和0.005〜10重量％的至少一种助催化剂金属。 助催化剂金属可以是锡，锗，铟，镓，铊，锑，铅，铼，锰，铬，钼或钨。 催化剂也可以含有掺杂金属。

公开(公告)号：US5830822A

公开(公告)日：1998-11-03

申请号：US496957

申请日：1995-06-30

申请人： Patrick Euzen

发明人： Patrick Euzen

IPC分类号： B01J23/00 ,  B01J23/34 ,  B01J23/78 ,  B01J23/80 ,  B01J37/03 ,  B01J21/04 ,  B01J101/32

CPC分类号： B01J37/03 ,  B01J23/002 ,  B01J23/34 ,  B01J23/78 ,  B01J23/80 ,  B01J2523/00

摘要： A non-selective high temperature resistant oxidation catalyst and a process for the preparation of this catalyst is described. The catalyst mainly has the formula A.sub.1-x B.sub.y C.sub.z Al.sub.12-y-z O.sub.19-.delta., where A represents at least one element selected from the group formed by barium, strontium and the rare earths; B represents at least one element with valency Y selected from the group formed by Mn, Co and Fe; C represents at least one element selected from the group formed by Mg and Zn; x has a value of 0 to 0.25, y has a value of 0.5 to 3 and z has a value of 0.01 to 3; the sum y+z has a maximum value of 4 and .delta. has a value which is determined as a function of the respective valencies X and Y of elements A and B and the value of x, y and z and is equal to 1-1/2{(1-x)X+yY-3y-z}. The catalysts of the invention are particularly for use in processes for the catalytic combustion of hydrocarbons, carbon monoxide, hydrogen or mixtures thereof.

摘要翻译： 描述了非选择性耐高温氧化催化剂和制备该催化剂的方法。 催化剂主要具有式A1-xByCzAl12-y-zO19-δ，其中A代表选自钡，锶和稀土形成的组中的至少一种元素; B表示选自由Mn，Co和Fe形成的基团中的至少一种价态Y的元素; C表示选自由Mg和Zn形成的基团中的至少一种元素; x的值为0〜0.25，y为0.5〜3，z为0.01〜3的值。 总和y + z的最大值为4，delta具有被确定为元素A和B的各个价值X和Y的函数的值，并且x，y和z的值等于1- + E，fra 1/2 + EE {（1-x）X + yY-3y-z}。 本发明的催化剂特别用于烃，一氧化碳，氢气或其混合物的催化燃烧方法。

公开(公告)号：US09862653B2

公开(公告)日：2018-01-09

申请号：US14236726

申请日：2012-07-25

申请人： Nikolai Nesterenko ,  Delphine Minoux ,  Cindy Adam ,  Jean-Pierre Dath ,  Joseph Lopez ,  Patrick Euzen

发明人： Nikolai Nesterenko ,  Delphine Minoux ,  Cindy Adam ,  Jean-Pierre Dath ,  Joseph Lopez ,  Patrick Euzen

IPC分类号： C07C1/24 ,  B01J37/10 ,  B01J37/28 ,  B01J29/40 ,  B01J29/85

CPC分类号： C07C1/24 ,  B01J29/40 ,  B01J29/85 ,  B01J37/10 ,  B01J37/28 ,  C07C2527/14 ,  C07C2529/06 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/04

摘要： A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.

公开(公告)号：US07807598B2

公开(公告)日：2010-10-05

申请号：US11889891

申请日：2007-08-17

申请人： Patrick Euzen ,  Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Cedric Boissiere ,  David Grosso

发明人： Patrick Euzen ,  Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Cedric Boissiere ,  David Grosso

IPC分类号： B01J29/06

CPC分类号： C01B39/04 ,  B01J20/08 ,  B01J20/16 ,  B01J20/18 ,  B01J20/28007 ,  B01J20/28083 ,  B01J29/041 ,  B01J29/08 ,  B01J29/40 ,  B01J29/60 ,  B01J29/7007 ,  B01J29/80 ,  B01J2229/62 ,  B82Y30/00 ,  C01B39/48

摘要： A mesostructured material that consists of at least two elementary spherical particles, each of said particles comprising a mesostructured matrix based on aluminum oxide and having a pore size of between 1.5 and 30 nm, an aluminum oxide content that represents more than 46% by weight relative to the mass of said matrix, which has amorphous walls with a thickness of between 1 and 30 nm and whereby said elementary spherical particles have a maximum diameter of 10 μm, is described. Said mesostructured matrix can also contain silicon oxide. Each of the spherical particles of the mesostructured material can also contain zeolitic nanocrystals so as to form a material with a mixed porosity that is both mesostructured and zeolitic in nature. The preparation of said material is also described.

摘要翻译： 由至少两个基本球形颗粒组成的介孔结构材料，每个所述颗粒包含基于氧化铝的孔结构基质，孔径在1.5至30nm之间，氧化铝含量相对于46重量％ 相对于具有1〜30nm厚度的非晶壁的所述基体的质量，并且由此所述基本球形颗粒的最大直径为10μm。 所述介孔结构的基质也可以含有氧化硅。 介孔结构材料的每个球形颗粒也可以含有沸石纳米晶体，以便形成具有混合孔隙率的材料，其本质上是介孔结构和沸石。 还描述了所述材料的制备。

公开(公告)号：US07563743B2

公开(公告)日：2009-07-21

申请号：US11221416

申请日：2005-09-08

申请人： Patrick Euzen ,  Alexandra Chaumonnot ,  Carole Bobin ,  Patrick Bourges ,  Christophe Gueret ,  Hugues Dulot

发明人： Patrick Euzen ,  Alexandra Chaumonnot ,  Carole Bobin ,  Patrick Bourges ,  Christophe Gueret ,  Hugues Dulot

IPC分类号： B01J27/00 ,  B01J21/00 ,  B01J23/00 ,  B01J23/10 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J20/00 ,  C07C4/02 ,  C10G11/00 ,  C10G11/02

CPC分类号： B01J37/28 ,  B01J21/02 ,  B01J21/12 ,  B01J23/74 ,  B01J23/85 ,  B01J23/883 ,  B01J23/8877 ,  B01J23/888 ,  B01J23/8885 ,  B01J23/8993 ,  B01J27/188 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  B01J37/30 ,  C10G49/04 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).

摘要翻译： 本发明涉及具有低含量大孔的铝硅酸盐底物上的掺杂催化剂和使用它们的加氢裂化/加氢转化和加氢处理方法。 催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和选自磷，硼和硅中的受控量的掺杂剂的氢脱氢元素 和具有二氧化硅 - 氧化铝基底的非沸石基材，其含有大于15重量％且小于或等于95重量％的二氧化硅（SiO 2）的量。

公开(公告)号：US20090118556A1

公开(公告)日：2009-05-07

申请号：US11722610

申请日：2005-12-13

申请人： Patrick Euzen ,  Patrick Bourges ,  Christophe Gueret ,  Carole Bobin ,  Alexandra Chaumonnot ,  Hugues Dulot

发明人： Patrick Euzen ,  Patrick Bourges ,  Christophe Gueret ,  Carole Bobin ,  Alexandra Chaumonnot ,  Hugues Dulot

IPC分类号： B01J29/14 ,  B01J29/08 ,  C07C5/10

CPC分类号： B01J37/0009 ,  B01J21/12 ,  B01J29/146 ,  B01J29/166 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/14 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10−10 m to 24.15×10−10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).

摘要翻译： 本发明涉及具有低大孔含量的混合沸石/铝硅酸盐载体上的掺杂催化剂，以及使用它们的加氢裂化/加氢转化和加氢处理方法。 该催化剂包含至少一种选自由元素周期表第ⅥB族和第Ⅷ族元素形成的基团和选自磷，硼和硅的受控量的掺杂元素和基于沸石Y的载体的脱氢元素， 在24.40×10 -10 m至24.15×10 -10 m范围内的晶胞的晶格参数a和含有多于5重量％和95重量％以下的二氧化硅（SiO 2）的二氧化硅 - 氧化铝。

公开(公告)号：US07297828B2

公开(公告)日：2007-11-20

申请号：US11098570

申请日：2005-04-05

申请人： Patrick Euzen ,  Emmanuelle Guillon

发明人： Patrick Euzen ,  Emmanuelle Guillon

IPC分类号： C07C2/68

CPC分类号： B01J37/0009 ,  B01J21/12 ,  B01J29/06 ,  B01J29/084 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/10 ,  B01J2229/16 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2/66 ,  C07C2/68 ,  C07C6/126 ,  C07C15/107 ,  C07C2521/12 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2527/12 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/70 ,  C07C15/113

摘要： An alkylating process for the production of at least one of 2-, 3-, 4-, 5-, and 6-phenylalkanes by alkylation of an aromatic compound with a feedstock containing at least one olefin comprising at least 9 carbon atoms per molecule, in the presence of a catalyst comprising at least one substrate based on at least a zeolite and a non-zeolitic silica-alumina matrix with a low content of macropores, whereby said matrix contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2), whereby said process is carried out at a temperature of between 30 and 400° C., a pressure of between 0.1 and 10 MPa, an hourly volumetric flow rate of 0.50 to 200 h−1, and an aromatic compound/olefin molar ratio of between 1:1 and 50:1.

摘要翻译： 烷基化方法，用于通过芳族化合物与含有至少一种包含每个分子至少9个碳原子的烯烃的原料烷基化来生产2-，3-，4-，5-和6-苯基烷烃中的至少一种， 在包含至少一种基于至少一种沸石的底物和具有低含量大孔的非沸石二氧化硅 - 氧化铝基质的催化剂存在下，其中所述基质含有的重量大于5％ 等于95重量％的二氧化硅（SiO 2/2），由此所述方法在30-400℃的温度，0.1-10MPa的压力，小时体积 流动速率为0.50〜200h -1，芳香族化合物/烯烃的摩尔比为1：1〜50：1。

公开(公告)号：US20060213809A1

公开(公告)日：2006-09-28

申请号：US11370174

申请日：2006-03-08

申请人： Karin Barthelet ,  Patrick Euzen ,  Hugues Dulot ,  Patrick Bourges

发明人： Karin Barthelet ,  Patrick Euzen ,  Hugues Dulot ,  Patrick Bourges

IPC分类号： C10G11/00

CPC分类号： C10G67/06 ,  C10G25/003 ,  C10G2300/201 ,  C10G2300/4081 ,  C10G2300/4093

摘要： The invention concerns an improved hydrocracking process with a recycle having a step for eliminating polyaromatic compounds from at least a portion of the recycled fraction by adsorption on a particular adsorbent based on alumina-silica with a controlled macropore content.

摘要翻译： 本发明涉及一种改进的加氢裂化方法，其中循环具有通过在具有受控大孔含量的基于氧化铝 - 二氧化硅的特定吸附剂上进行吸附而从至少一部分循环级分中消除多芳族化合物的步骤。