CATALYTIC PYROLYSIS OF OLIVE MILL WASTE
    43.
    发明申请
    CATALYTIC PYROLYSIS OF OLIVE MILL WASTE 审中-公开
    橄榄油废料的催化热解

    公开(公告)号:US20150065762A1

    公开(公告)日:2015-03-05

    申请号:US14477720

    申请日:2014-09-04

    摘要: Methods and apparatus for producing bio-oil that include providing a catalyst that includes red mud in a catalyst bed in a fluid state, the catalyst being maintained at a temperature suitable for pyrolysis; providing a flow of a non-reactive fluid into the catalyst bed; entraining a biomass that includes olive mill waste in the flow of non-reactive fluid, so that the biomass is delivered to the catalyst bed; pyrolyzing the biomass; collecting gases and vapors that result from pyrolysis; and condensing the gases and vapors into bio-oil.

    摘要翻译: 用于生产生物油的方法和设备包括提供在流体状态下在催化剂床中包括红泥的催化剂,所述催化剂保持在适于热解的温度; 提供非反应性流体流入催化剂床; 在非反应性流体的流动中夹带包括橄榄磨废物的生物质,使得生物质被输送到催化剂床; 热解生物量; 收集由热解产生的气体和蒸气; 并将气体和蒸气冷凝成生物油。

    Catalyst for converting acid-containing inferior crude oil and process for making and using the same
    49.
    发明授权
    Catalyst for converting acid-containing inferior crude oil and process for making and using the same 有权
    用于转化含酸劣质原油的催化剂及其制备和使用方法

    公开(公告)号:US08809216B2

    公开(公告)日:2014-08-19

    申请号:US12812148

    申请日:2009-01-09

    IPC分类号: B01J29/06 C10G11/05

    摘要: The present invention relates to a catalyst for converting inferior acid-containing crude oil. Based on the total amount of the catalyst, said catalyst comprises from 1 to 50 wt % of a mesopore material, from 1 to 60 wt % of molecular sieves and from 5 to 98 wt % of thermotolerant inorganic oxides and from 0 to 70 wt % of clays. Said mesopore material is an amorphous material containing alkaline earth oxide, silica and alumina, and has an anhydrous chemical formula of (0-0.3)Na2O.(1-50)MO.(6-58)Al2O3.(40-92)SiO2, based on the weight percent of the oxides, wherein M is one or more selected from Mg, Ca and Ba. Said mesopore material has a specific surface area of 200-400 m2/g, a pore volume of 0.5-2.0 ml/g, an average pore diameter of 8-20 nm, and a most probable pore size of 5-15 nm. The catalyst provided in the present invention is suitable for the catalytic conversion of crude oil having a total acid number of greater than 0.5 mgKOH/g and for the removal of organic acids, carbon residues and metals in crude oil, and thus has very good economic benefits.

    摘要翻译: 本发明涉及用于转化劣质含酸原油的催化剂。 基于催化剂的总量,所述催化剂包含1至50重量%的中孔材料,1至60重量%的分子筛和5至98重量%的耐热无机氧化物和0至70重量% 的粘土。 所述中孔材料是含有碱土金属氧化物,二氧化硅和氧化铝的无定形材料,具有无水化学式(0-0.3)Na2O(1-50)MO。(6-58)Al2O3。(40-92)SiO2 ,基于氧化物的重量百分数,其中M是选自Mg,Ca和Ba中的一种或多种。 所述中孔材料的比表面积为200-400m2 / g,孔体积为0.5-2.0ml / g,平均孔径为8-20nm,最可能的孔径为5-15nm。 本发明提供的催化剂适用于总酸值大于0.5mgKOH / g的原油的催化转化和用于去除原油中的有机酸,碳残余物和金属,因此具有非常好的经济性 好处