公开(公告)号：US20210284616A1

公开(公告)日：2021-09-16

申请号：US17259979

申请日：2019-06-17

申请人： SABIC GLOBAL TECHNOLOGIES B.V.

发明人： Jintang DUAN

IPC分类号： C07D301/08 ,  C07D303/04

摘要： Systems and methods for producing ethylene oxide (EO) are disclosed. Ethylene oxide is produced by direct oxidizing ethylene with oxygen in a reactor. The effluent from the reactor is processed to produce (a) a product stream comprising water and ethylene oxide, (b) a reabsorber overhead stream comprising ethylene, methane, argon, and carbon dioxide, and (c) a carbonate flash gas stream comprising carbon dioxide, ethylene, methane, and water. The reabsorber overhead stream and the carbonate flash gas stream are combined to form a reclaim gas stream. The reclaimed gas stream is separated in a membrane separation unit to remove carbon dioxide and argon, forming a recycle stream comprising primarily ethylene and methane, collectively.

公开(公告)号：US10526549B2

公开(公告)日：2020-01-07

申请号：US15961651

申请日：2018-04-24

申请人： Lyondell Chemical Technology

发明人： Sandor Nagy ,  Dan D. Lindsey ,  Barbara Kimmich ,  Justin E. Turner ,  Nicholas Bruschi ,  Ha H. Nguyen ,  Pranit S. Metkar ,  Anthony S. Dearth

IPC分类号： C07C5/56 ,  C10G45/08 ,  C07C15/46 ,  C07D303/04 ,  B01J27/051 ,  C07D301/08 ,  C07C1/22 ,  C07D301/19

摘要： The present disclosure relates to a method including subjecting an organic stream comprising at least one oxygenate to hydrotreatment, whereby a hydrotreatment product comprising ethylbenzene is produced, wherein the organic stream is a product of a process for the production of propylene oxide; and separating an ethylbenzene product stream from the hydrotreatment product, to yield a residual stream.

公开(公告)号：US20180312764A1

公开(公告)日：2018-11-01

申请号：US15961651

申请日：2018-04-24

申请人： Lyondell Chemical Technology, L.P.

发明人： Sandor Nagy ,  Dan D. Lindsey ,  Barbara Kimmich ,  Justin E. Turner ,  Nicholas Bruschi ,  Ha H. Nguyen ,  Pranit S. Metkar ,  Anthony S. Dearth

IPC分类号： C10G45/08 ,  C07C15/46 ,  C07C5/56 ,  C07D303/04 ,  C07D301/08 ,  B01J27/051

摘要： The present disclosure relates to a method including subjecting an organic stream comprising at least one oxygenate to hydrotreatment, whereby a hydrotreatment product comprising ethylbenzene is produced, wherein the organic stream is a product of a process for the production of propylene oxide; and separating an ethylbenzene product stream from the hydrotreatment product, to yield a residual stream.

公开(公告)号：US20180258012A1

公开(公告)日：2018-09-13

申请号：US15760272

申请日：2016-09-16

申请人： SHELL OIL COMPANY

发明人： Alouisius Nicolaas Renée BOS ,  Georgios MITKIDIS ,  Guus VAN ROSSUM ,  Maria SAN ROMAN MACIA ,  Ronald Jan SCHOONEBEEK ,  Vatsal Mukundlal SHAH ,  Michael Johannes Franciscus Maria VERHAAK

IPC分类号： C07C5/48 ,  C07D301/08 ,  B01J27/057

CPC分类号： C07C5/48 ,  B01J27/0576 ,  C07C2523/20 ,  C07C2523/28 ,  C07C2527/057 ,  C07D301/08 ,  Y02P20/52 ,  C07C11/04

摘要： The invention relates to a process of the oxidative dehydrogenation of a C2-6 alkane, comprising subjecting a stream comprising methane and the C2-6 alkane, in which stream the volume ratio of methane to the C2-6 alkane is of from 0.005:1 to 100:1, to oxydehydrogenation conditions resulting in a stream comprising methane, a C2-6 alkene and optionally a C2-6 carboxylic acid.

公开(公告)号：US09079154B2

公开(公告)日：2015-07-14

申请号：US13872506

申请日：2013-04-29

申请人： BASF SE

发明人： Tobias Rosendahl ,  Torsten Mäurer ,  Dirk Hensel ,  Andreas Lehr

IPC分类号： B01J23/00 ,  C07D301/03 ,  B01J27/02 ,  C07D301/04 ,  C07D301/08 ,  B01J37/08 ,  B01J23/68 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/06

CPC分类号： B01J27/02 ,  B01J23/685 ,  B01J23/686 ,  B01J23/688 ,  B01J35/1066 ,  B01J35/1076 ,  B01J35/109 ,  B01J37/0036 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08 ,  C07D301/04 ,  C07D301/08 ,  Y02P20/52

摘要： The present invention relates to a catalyst for preparing alkylene oxides, which is a supported silver catalyst having a novel promoter combination. The present invention further relates to a process for producing the catalyst and the use of the catalyst for the oxidation of alkylenes to alkylene oxides. In addition, the present invention relates to a process for preparing ethylene oxide from ethylene, which comprises the oxidation of ethylene in the presence of the stated catalyst.

摘要翻译： 本发明涉及一种用于制备环氧烷烃的催化剂，它是具有新型启动子组合的负载型银催化剂。 本发明还涉及一种制备该催化剂的方法和该催化剂用于将亚烷基氧化成环氧烷烃的用途。 此外，本发明涉及一种由乙烯制备环氧乙烷的方法，其包括在所述催化剂存在下氧化乙烯。

公开(公告)号：US08404190B2

公开(公告)日：2013-03-26

申请号：US12678274

申请日：2008-11-07

申请人： Harvey E. Andresen ,  Christopher P. Christenson ,  Charles W. Lipp ,  John R. Mayer ,  Thomas J. Kling ,  Victor R. Fey ,  Laurence G. Britton ,  Michael J. Rangitsch ,  Michael L. Hutchison

发明人： Harvey E. Andresen ,  Christopher P. Christenson ,  Charles W. Lipp ,  John R. Mayer ,  Thomas J. Kling ,  Victor R. Fey ,  Laurence G. Britton ,  Michael J. Rangitsch ,  Michael L. Hutchison

IPC分类号： B01J19/26 ,  C07D301/08

CPC分类号： B01J19/26 ,  B01F3/04049 ,  B01F5/0453 ,  B01F5/0456 ,  B01J4/002 ,  B01J12/00 ,  B01J2219/00263 ,  C07D301/08

摘要： A hydrocarbon-containing gas is mixed with an oxygen-containing gas in a gas mixer in the presence of a water mist. The water mist surrounds and contacts entrained particles in either the oxygen-containing gas stream or the hydrocarbon-containing gas stream. The water acts to suppress and prevent ignition of the hydrocarbon gas in the mixer by serving as a sink for heat created by energetic collisions between such particles and structures within the gas mixer. The water mist also acts to quench ignition caused by such collisions. The water mist can be introduced into the gas mixer in a number of different configurations, including via nozzles injecting a mist into a hydrocarbon gas manifold or an oxygen gas manifold, nozzles placed within the gas mixer adjacent to ends of the oxygen supply pipes, and nozzles placed coaxially within the oxygen supply pipes in the gas mixer.

摘要翻译： 在气雾混合器中，在水雾的存在下，将含烃气体与含氧气体混合。 水雾在含氧气流或含烃气流中包围并接触夹带的颗粒。 水通过作为在气体混合器内的这种颗粒和结构之间的能量碰撞产生的热量来抑制和防止混合器中的烃气的点燃。 水雾还起到由这种碰撞引起的点火的作用。 可以以多种不同的结构将水雾引入到气体混合器中，包括将气雾喷入烃气歧管或氧气歧管中的通孔喷嘴，邻近氧气供应管的气体混合器内的喷嘴，以及 喷嘴同轴放置在气体混合器内的供氧管内。

公开(公告)号：US20100267973A1

公开(公告)日：2010-10-21

申请号：US12754200

申请日：2010-04-05

申请人： Albert C. Liu ,  Liping Zhang

发明人： Albert C. Liu ,  Liping Zhang

IPC分类号： C07D301/08 ,  C07C31/20 ,  C07C213/02 ,  C07C41/02 ,  C07C68/00 ,  B01J27/24 ,  B01J27/045 ,  B01J23/58 ,  B01J23/46 ,  B01J23/656 ,  B01J23/652 ,  B01J23/16

CPC分类号： C07D301/10

摘要： A method for enhancing the efficiency of a rhenium-promoted epoxidation catalyst is provided. Advantageously, the method may be carried out in situ, i.e., within the epoxidation process, and in fact, may be carried out during production of the desired epoxide. As such, a method for the epoxidation of alkylenes incorporating the efficiency-enhancing method is also provided, as is a method for using the alkylene oxides so produced for the production of 1,2-diols, 1,2-carbonates, 1,2-diol ethers, or alkanolamines.

摘要翻译： 提供了提高铼促进的环氧化催化剂的效率的方法。 有利地，该方法可以在原位进行，即在环氧化方法中进行，实际上可以在制备期望的环氧化物期间进行。 因此，还提供了包含效率增强方法的亚烷基环氧化方法，以及如此制备用于生产1,2-二醇，1,2-碳酸酯，1,2- - 二醇醚或链烷醇胺。

公开(公告)号：US07569710B1

公开(公告)日：2009-08-04

申请号：US12070992

申请日：2008-02-23

申请人： Brian Ozero

发明人： Brian Ozero

IPC分类号： C07D301/32 ,  C07D301/08 ,  C07C29/10

CPC分类号： C07C29/106 ,  C07D301/08 ,  C07D301/32 ,  Y02P20/582 ,  C07C31/202

摘要： An improved process for the recovery of a high-purity, ethylene oxide-water stream for use as feed to integrated ethylene glycol or ethylene oxide purification reactors by first contacting the gaseous effluent from ethylene oxide reactors with an aqueous alkaline quench solution water wash, then absorbing ethylene oxide from the washed vapor into process water to produce a dilute EO-water absorbate of which 10-90% is sent directly to the EO reabsorber/residual absorber, thereby bypassing the EO stripper.

摘要翻译： 一种用于回收高纯度环氧乙烷 - 水流的改进方法，用于通过首先使环氧乙烷反应器的气态流出物与碱性骤冷溶液水洗液接触，用于整合的乙二醇或环氧乙烷净化反应器的进料，然后 将环氧乙烷从洗涤的蒸汽中吸收到工艺水中，以产生稀释的EO-水吸收剂，其中10-90％直接发送到EO再吸收器/残余吸收器，从而绕过EO汽提器。

公开(公告)号：US20050187410A1

公开(公告)日：2005-08-25

申请号：US11108452

申请日：2005-04-18

申请人： Zhiping Shan ,  Thomas Maschmeyer ,  Jacobus Jansen

发明人： Zhiping Shan ,  Thomas Maschmeyer ,  Jacobus Jansen

IPC分类号： B01J21/06 ,  B01J21/08 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/00 ,  B01J29/03 ,  B01J29/04 ,  B01J29/08 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  B01J37/10 ,  C01B13/36 ,  C01B33/12 ,  C01B37/00 ,  C01B37/02 ,  C07B61/00 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/08 ,  C07D301/10 ,  C07D303/04 ,  C10G2/00 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/20 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C249/08

CPC分类号： B01J29/89 ,  B01J21/06 ,  B01J21/063 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/0316 ,  B01J29/04 ,  B01J29/042 ,  B01J29/046 ,  B01J29/084 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  B82Y30/00 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/08 ,  C07D301/10 ,  C10G2/332 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C15/073 ,  C07C49/84

摘要： A material especially useful for the selective oxidation of hydrocarbons and other organic compounds includes a non-crystalline, porous inorganic oxide having at least 97 volume percent mesopores based on micropores and mesopores, and at least one catalytically active metal selected from the group consisting of one or more transition metal and one or more noble metal.

公开(公告)号：US20050137271A1

公开(公告)日：2005-06-23

申请号：US11044299

申请日：2005-01-28

申请人： Derek Colman ,  Trevor Hesketh ,  Ian Reid ,  William Woodfin

发明人： Derek Colman ,  Trevor Hesketh ,  Ian Reid ,  William Woodfin

IPC分类号： C07D307/60 ,  B01F3/02 ,  B01F5/00 ,  B01F5/04 ,  B01J8/02 ,  B01J19/00 ,  B01J19/26 ,  C01B3/38 ,  C07B61/00 ,  C07C5/333 ,  C07C5/48 ,  C07C11/04 ,  C07C45/33 ,  C07C51/215 ,  C07C51/265 ,  C07C51/31 ,  C07C67/05 ,  C07C69/15 ,  C07C253/24 ,  C07D301/08 ,  C07D307/89 ,  C07C27/06

CPC分类号： C01B3/386 ,  B01J8/0242 ,  B01J8/0285 ,  B01J19/006 ,  B01J19/26 ,  B01J2208/00 ,  B01J2219/00069 ,  B01J2219/00085 ,  B01J2219/00155 ,  B01J2219/00159 ,  B01J2219/00164 ,  B01J2219/00243 ,  B01J2219/0286 ,  B01J2219/1923 ,  C01B2203/0261 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/107 ,  C01B2203/1247 ,  C01B2203/1288 ,  C07C5/48 ,  C07C45/33 ,  C07C51/215 ,  C07C51/265 ,  C07C51/313 ,  C07C67/05 ,  C07C253/24 ,  C07D301/08 ,  C07C11/02 ,  C07C57/145 ,  C07C63/16 ,  C07C69/01 ,  C07C69/15 ,  C07C255/08

摘要： A process for the oxidation of a hydrocarbon, said process comprising partially oxidising in a reaction zone, a mixture comprising a hydrocarbon and an oxygen-containing gas in the presence of a catalyst which is capable of supporting oxidation of the hydrocarbon, wherein prior to said partial oxidation, said mixture comprising the hydrocarbon and the oxygen-containing gas is passed through a heat exchanger. Preferably the heat exchanger is a compact heat exchanger. Prior to passage through the heat exchanger a mixture of hydrocarbon and oxygen-containing gas may be passed through a baffle zone which comprises a housing containing at least one baffle plate. In a preferred embodiment, the invention relates to a process for the production of an olefin such as ethylene by the catalytic oxidative dehydrogenation of a hydrocarbon or mixture of hydrocarbons.

摘要翻译： 一种用于氧化烃的方法，所述方法包括在反应区中部分氧化，含有烃和含氧气体的混合物，所述混合物在能够支持所述烃的氧化的催化剂的存在下，其中在所述 部分氧化，所述包含烃和含氧气体的混合物通过热交换器。 优选地，热交换器是紧凑的热交换器。 在通过热交换器之前，烃和含氧气体的混合物可以通过挡板区域，该挡板区域包括容纳至少一个挡板的壳体。 在优选的实施方案中，本发明涉及通过烃或烃混合物的催化氧化脱氢来生产烯烃如乙烯的方法。