Structure and method for metal gate stack oxygen concentration control using an oxygen diffusion barrier layer and a sacrificial oxygen gettering layer
    68.
    发明授权
    Structure and method for metal gate stack oxygen concentration control using an oxygen diffusion barrier layer and a sacrificial oxygen gettering layer 有权
    使用氧扩散阻挡层和牺牲吸氧层的金属栅堆叠氧浓度控制的结构和方法

    公开(公告)号:US09087918B2

    公开(公告)日:2015-07-21

    申请号:US14146095

    申请日:2014-01-02

    Abstract: A process is disclosed of forming metal replacement gates for NMOS and PMOS transistors with oxygen in the PMOS metal gates and metal atom enrichment in the NMOS gates such that the PMOS gates have effective work functions above 4.85 eV and the NMOS gates have effective work functions below 4.25 eV. Metal work function layers in both the NMOS and PMOS gates are oxidized to increase their effective work functions to the desired PMOS range. An oxygen diffusion blocking layer is formed over the PMOS gate and an oxygen getter is formed over the NMOS gates. A getter anneal extracts the oxygen from the NMOS work function layers and adds metal atom enrichment to the NMOS work function layers, reducing their effective work functions to the desired NMOS range. Processes and materials for the metal work function layers, the oxidation process and oxygen gettering are disclosed.

    Abstract translation: 公开了一种用于在PMOS金属栅中的氧和NMOS栅极中的金属原子富集的NMOS和PMOS晶体管形成金属替代栅极的工艺,使得PMOS栅极具有高于4.85eV的有效功函数,并且NMOS栅极具有以下有效的功函数 4.25 eV。 NMOS和PMOS栅极中的金属功函数层被氧化,以将它们的有效功函数增加到期望的PMOS范围。 在PMOS栅极上形成氧扩散阻挡层,在NMOS栅极上形成氧吸气剂。 吸气剂退火从NMOS功能层提取氧气,并将金属原子富集添加到NMOS功能层,将其有效功函数降低到所需的NMOS范围。 公开了金属加工功能层的工艺和材料,氧化工艺和吸氧剂。

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