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    PROCESS FOR MODIFYING TS-1 BASED ON MIXED SOLUTION OF QUATERNARY AMMONIUM SALT AND INORGANIC BASE
    74.
    发明申请
    PROCESS FOR MODIFYING TS-1 BASED ON MIXED SOLUTION OF QUATERNARY AMMONIUM SALT AND INORGANIC BASE 有权
    基于季铵盐和无机碱的混合溶液修饰TS-1的方法

    公开(公告)号：US20140301942A1

    公开(公告)日：2014-10-09

    申请号：US14355157

    申请日：2012-03-18

    申请人： Dalian University of Technology

    发明人： Hongchen Guo ,  Ji Su ,  Guanghong Liu

    IPC分类号： B01J29/04

    CPC分类号： B01J29/041 ,  B01J29/035 ,  B01J29/89 ,  B01J2229/183 ,  B01J2229/34 ,  B01J2229/38 ,  C01B37/005 ,  C01B39/085 ,  C07D301/03 ,  C07D303/04

    摘要： This invention belongs to the technical field of inorganic chemical synthesis, relating to a modification method for titanium-silicalite zeolite (TS-1). The feature of the invention is pretreating the TS-1, after that the TS-1 is modified by the mixture of quaternary ammonium salts and inorganic base. The quaternary ammonium salts mentioned above include tetrapropylammonium fluoride, tetrapropylammonium chloride, tetrapropylammonium iodide and their mixture. The inorganic base include that LiOH, NaOH and KOH and their mixture. TS-1 after the modification is aftertreated at last. The benefit of the invention is universal capable to modify the TS-1 synthesized by any method, specially the TS-1 with low cost method, the modification can enhance the catalytic performance on both gas and liquid phase epoxidation of propylene.

    摘要翻译： 本发明属于无机化学合成技术领域，涉及钛硅沸石（TS-1）的改性方法。 本发明的特征是预处理TS-1，之后TS-1被季铵盐和无机碱的混合物改性。 上述季铵盐包括四丙基氟化铵，四丙基氯化铵，四丙基碘化铵及其混合物。 无机碱包括LiOH，NaOH和KOH及其混合物。 修改后的TS-1最终被后处理。 本发明的优点是能够通过任何方法，特别是TS-1以低成本的方法改性TS-1，这种改性可以提高丙烯气相和环氧化的催化性能。

    FUEL CONDITIONING MODULES AND METHODS
    75.
    发明申请
    FUEL CONDITIONING MODULES AND METHODS 有权
    燃料调节模块和方法

    公开(公告)号：US20140216379A1

    公开(公告)日：2014-08-07

    申请号：US14124905

    申请日：2012-05-09

    申请人： Joel S. Ratner

    发明人： Joel S. Ratner

    IPC分类号： B01J8/02 ,  F02B43/00

    CPC分类号： B01J8/02 ,  B01J21/04 ,  B01J21/063 ,  B01J23/02 ,  B01J23/10 ,  B01J23/26 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/72 ,  B01J23/745 ,  B01J23/755 ,  B01J23/80 ,  B01J29/035 ,  B01J29/70 ,  B01J29/7015 ,  B01J37/0246 ,  B01J37/04 ,  B01J2208/00884 ,  B01J2208/025 ,  B01J2229/42 ,  C10G29/04 ,  C10G2300/201 ,  C10L3/10 ,  F02B43/00 ,  F02M27/02 ,  Y02T10/32

    摘要： Fuel conditioning modules that condition a combustible fuel prior to combustion are provided so that fuel to be conditioned is brought into contact with a fuel conditioning insert which includes a zeolite catalyst material comprised of a mixture of zeolite particulates and rare earth metal or metal oxide particulates in a solid resin binder disposed in a housing flow through passageway such that the fuel flowing in the passageway between inlet and outlet ends of the housing contacts the fuel conditioning insert assembly. The catalytic metal is most preferably at least one selected from the group consisting of copper, aluminum, stainless steel, titanium, magnesium, chromium, barium, calcium, platinum, palladium, nickel, bronze and iron. The zeolite catalyst material may be dispersed in the form of solid chips throughout a mass of metallic elements form of a catalytic metal.

    摘要翻译： 提供在燃烧之前调节可燃燃料的燃料调节模块，使待调节的燃料与燃料调节插入物接触，该燃料调节插入物包括由沸石颗粒和稀土金属或金属氧化物颗粒的混合物组成的沸石催化剂材料 固体树脂粘合剂，其设置在壳体中流过通道，使得在壳体的入口端和出口端之间的通道中流动的燃料接触燃料调节插入件组件。 催化金属最优选选自铜，铝，不锈钢，钛，镁，铬，钡，钙，铂，钯，镍，青铜和铁中的至少一种。 沸石催化剂材料可以以整个金属元素形式的催化金属以固体碎屑的形式分散。

    Production of olefins
    76.
    发明授权
    Production of olefins 失效
    生产烯烃

    公开(公告)号：US08536396B2

    公开(公告)日：2013-09-17

    申请号：US10524640

    申请日：2003-08-13

    申请人： Jean-Pierre Dath ,  Walter Vermeiren

    发明人： Jean-Pierre Dath ,  Walter Vermeiren

    IPC分类号： C07C1/20

    CPC分类号： C07C1/22 ,  B01J29/035 ,  B01J29/40 ,  B01J37/0009 ,  B01J2229/16 ,  B01J2229/36 ,  B01J2229/38 ,  B01J2229/42 ,  C07C1/20 ,  C10G3/49 ,  C10G2300/1037 ,  C10G2300/4018 ,  C10G2300/807 ,  C10G2400/20 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/06

    摘要： A process for converting a hydrocarbon feedstock to provide an effluent containing light olefins, the process comprising passing a hydrocarbon feedstock, the feedstock containing at least one C1 to C6 aliphatic hetero compound selected from alcohols, ethers, carbonyl compounds and mixtures thereof and steam in an amount whereby the feedstock contains up to 80 weight % steam, through a reactor containing a crystalline silicate catalyst to produce an effluent including propylene, the crystalline silicate having been subjected to de-alumination by a steaming step and being selected from at least one of an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of from 250 to 500 and an MEL-type crystalline silicate having a silicon/aluminium atomic ratio or from 150 to 800.

    摘要翻译： 一种用于转化烃原料以提供含有轻质烯烃的流出物的方法，所述方法包括使烃原料通过，所述原料含有至少一种选自醇，醚，羰基化合物及其混合物的C1-C6脂族杂化合物和其蒸汽， 其中原料含有高达80重量％的蒸汽，通过含有结晶硅酸盐催化剂的反应器以产生包含丙烯的流出物，所述结晶硅酸盐已经通过蒸汽步骤进行脱铝，并且选自以下的至少一种： 硅/铝原子比为250〜500的MFI型结晶硅酸盐和硅/铝原子比为150〜800的MEL型结晶硅酸盐。

    Process for oxidizing alkylaromatic compounds
    79.
    发明授权
    Process for oxidizing alkylaromatic compounds 失效
    氧化烷基芳族化合物的方法

    公开(公告)号：US07985883B2

    公开(公告)日：2011-07-26

    申请号：US12601578

    申请日：2008-07-08

    申请人： James C. Vartuli ,  Jihad M. Dakka ,  Robert C. Lemon

    发明人： James C. Vartuli ,  Jihad M. Dakka ,  Robert C. Lemon

    IPC分类号： C07C45/53 ,  C07C37/08 ,  C07C407/00

    CPC分类号： C07C409/08 ,  B01J23/34 ,  B01J29/035 ,  B01J35/1057 ,  C07C37/07 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C409/10 ,  C07C409/14 ,  C07C2601/14 ,  Y02P20/52 ,  C07C49/403 ,  C07C39/04

    摘要： In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, with oxygen in the presence of a catalyst comprising a manganese oxide molecular sieve to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I). The hydroperoxide of formula (II) may then be converted to a phenol and an aldehyde or a ketone of the general formula R1COCH2R2 (III), in which R1 and R2 have the same meaning as in formula (I). In the case where the ketone is cyclohexanone, this may then be dehydrogenated to produce further phenol.

    摘要翻译： 在制备氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示具有1至4个碳原子的烷基，条件是R 1和R 2可以连接形成具有 所述环状基团任选被取代，并且R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基与氧在含氧化锰分子筛 以产生通式（II）的氢过氧化物：其中R 1，R 2和R 3具有与式（I）中相同的含义。 然后将式（II）的氢过氧化物转化为通式为R 1 COCH 2 R 2（III）的酚和醛或酮，其中R 1和R 2具有与式（I）中相同的含义。 在酮是环己酮的情况下，然后可以将其脱氢以产生另外的苯酚。