公开(公告)号：US20050154243A1

公开(公告)日：2005-07-14

申请号：US11000859

申请日：2004-12-01

申请人： Chuen Yeh ,  Jinsuo Xu ,  Philip Angevine

发明人： Chuen Yeh ,  Jinsuo Xu ,  Philip Angevine

IPC分类号： B01J29/06 ,  B01J29/70 ,  B01J35/00 ,  B01J37/00 ,  B01J37/08 ,  C01B37/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/48 ,  C07C2/58 ,  C07C2/66 ,  C10G29/20 ,  C10G45/64 ,  C10G47/16 ,  C07C2/68 ,  C07C5/22

CPC分类号： C07C2/66 ,  B01J29/06 ,  B01J29/7007 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/08 ,  B01J2229/40 ,  B01J2229/64 ,  C01B37/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/48 ,  C07C2/58 ,  C07C6/126 ,  C07C2529/40 ,  C10G29/205 ,  C10G45/64 ,  C10G47/16 ,  Y02P20/52 ,  C07C15/073 ,  C07C9/21

摘要： An aromatic alkylation process includes contacting an aromatic compound with an alkylating agent in the presence of a zeolite beta in a reaction zone under alkylation reaction conditions, wherein said zeolite beta is a high performance zeolite beta possessing a ratio of strong acid sites/weak acid sites greater than 1. The high performance zeolite beta is superior to conventional zeolite beta in the aromatics alkylation reaction, such as benzene alkylation with ethylene for ethylbenzene production, and benzene alkylation with propylene for cumene production.

摘要翻译： 芳族烷基化方法包括在烷基化反应条件下在反应区中在β沸石存在下使芳族化合物与烷基化剂接触，其中所述沸石β是具有强酸性位点/弱酸性位点的比例的高性能沸石β 大于1.在芳族烷基化反应中，高性能沸石β优于常规沸石β，例如用乙烯生产乙烯的苯烷基化和用丙烯生产异丙苯的苯烷基化。

公开(公告)号：US20050234283A1

公开(公告)日：2005-10-20

申请号：US10824390

申请日：2004-04-14

申请人： Jinsuo Xu ,  Chuen Yeh ,  Philip Angevine

发明人： Jinsuo Xu ,  Chuen Yeh ,  Philip Angevine

IPC分类号： B01J21/06 ,  B01J23/24 ,  B01J23/30 ,  B01J23/652 ,  B01J27/053 ,  B01J27/057 ,  B01J37/00 ,  B01J37/08 ,  C07C5/27 ,  C10G45/60 ,  C10G45/62 ,  C10G47/02 ,  C10G49/04 ,  C07C5/22 ,  B01J21/16 ,  C10G11/02

CPC分类号： B01J23/6527 ,  B01J21/063 ,  B01J21/066 ,  B01J23/24 ,  B01J23/30 ,  B01J23/652 ,  B01J27/053 ,  B01J27/057 ,  B01J37/0009 ,  B01J37/08 ,  C07C5/2772 ,  C07C2523/652 ,  C10G45/60 ,  C10G45/62 ,  C10G47/02 ,  C10G49/04 ,  C10G2300/1081 ,  C10G2300/4018 ,  C07C9/00

摘要： A catalyst composition includes an oxygen compound of an element selected from Group IVB or Group IVA of the Periodic Table of the Elements; an oxygen compound of an element selected from Group VIB or Group VIA of the Periodic Table of the Elements; and at least about 1% by weight based upon total catalyst weight of fumed silica particles. The catalyst composition is advantageously employed in hydrocarbon conversion processes such as isomerization.

摘要翻译： 催化剂组合物包括选自元素周期表的IVB族或IVA族元素的元素的氧化合物; 选自元素周期表的VIB族或VIA族的元素的氧化合物; 和基于热解二氧化硅颗粒的总催化剂重量的至少约1重量％。 催化剂组合物有利地用于烃转化过程如异构化。

公开(公告)号：US20060052234A1

公开(公告)日：2006-03-09

申请号：US11198564

申请日：2005-08-05

申请人： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

发明人： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

IPC分类号： C10G47/02 ,  C10G45/04 ,  C10G11/02 ,  B01J29/06

CPC分类号： B01J29/046 ,  B01J21/12 ,  B01J23/44 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/084 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/32 ,  B01J2229/42 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C10G2/332 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G50/00 ,  C07C15/073

摘要： A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of refractory oxide containing at least 97% by volume of pores having a pore size ranging from about 15 Å to about 30 Å and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2 theta (θ). The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.

摘要翻译： 一种用于处理有机化合物的方法包括提供一种组合物，其包括耐火氧化物的基本介孔结构，其含有至少97体积％的孔径为约至约的孔，并且具有至少约 0.01cc / g，其中介孔结构与其中至少约0.02重量％的至少一种催化和/或化学活性的选自Al，Ti，V，Cr，Zn，Fe，Sn， Mo，Ga，Ni，Co，In，Zr，Mn，Cu，Mg，Pd，Pt和W，并且催化剂具有在2θ（θ）处在0.3°至约3.5°具有一个峰的X射线衍射图， 。 催化剂在反应条件下与有机原料接触，其中处理过程选自烷基化，酰化，低聚，选择性氧化，加氢处理，异构化，脱金属催化脱蜡，羟基化，氢化，氨肟化，异构化，脱氢，裂化和吸附。

公开(公告)号：US20050201920A1

公开(公告)日：2005-09-15

申请号：US11101858

申请日：2005-04-08

申请人： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

发明人： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer ,  Mohamed Hamdy

IPC分类号： B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/00 ,  B01J29/03 ,  B01J29/04 ,  B01J29/08 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  B01J37/10 ,  C01B13/36 ,  C01B33/12 ,  C01B37/00 ,  C01B37/02 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G2/00 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/20 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C27/00 ,  C07C27/06 ,  C10G11/02 ,  C10G15/00

CPC分类号： C10G2/332 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J29/046 ,  B01J29/084 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C15/073 ,  C07C49/84

摘要： A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of silica containing at least 97% by volume of pores having a pore size ranging from about 15 Å to about 30 Å and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2θ. The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.

公开(公告)号：US20070170096A1

公开(公告)日：2007-07-26

申请号：US11726294

申请日：2007-03-21

申请人： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer

发明人： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Philip Angevine ,  Thomas Maschmeyer

IPC分类号： C01F7/02 ,  C10G35/06 ,  C10G47/12 ,  C10G45/00 ,  C07C1/00

CPC分类号： C01B37/00 ,  B01J21/04 ,  B01J35/10 ,  B01J35/1061 ,  B01J37/0018 ,  C01F7/36 ,  C01F7/448 ,  C01P2002/01 ,  C01P2002/72 ,  C01P2002/86 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17

摘要： Mesoporous aluminum oxides with high surface areas have been synthesized using inexpensive, small organic templating agents instead of surfactants. Option-ally, some of the aluminum can be framework-substituted by one or more other elements. The material has high thermal stability and possesses a three-dimensionally randomly connected mesopore network with continuously tunable pore sizes. This material can be used as catalysts for dehydration, hydrotreating, hydrogenation, catalytic reforming, steam reforming, amination, Fischer-Tropsch synthesis and Diels-Alder synthesis, etc.

摘要翻译： 使用廉价的小型有机模板剂代替表面活性剂，已经合成了具有高表面积的介孔氧化铝。 可选的是，一些铝可以由一个或多个其他元素框架代替。 该材料具有高热稳定性，并具有连续可调孔径的三维随机连接的中孔网络。 该材料可用作脱水，加氢处理，氢化，催化重整，蒸汽重整，胺化，费 - 托合成和狄尔斯 - 阿尔德合成等催化剂。

公开(公告)号：US20060128555A1

公开(公告)日：2006-06-15

申请号：US11350156

申请日：2006-02-08

申请人： Zhiping Shan ,  Peter Wilhelm ,  Bowden Maingay ,  Philip Angevine ,  Jacobus Jansen ,  Chuen Yeh ,  Thomas Maschmeyer ,  Frits Dautzenberg ,  Leonardo Marchese ,  Heloise Oliveira Pastore

发明人： Zhiping Shan ,  Peter Wilhelm ,  Bowden Maingay ,  Philip Angevine ,  Jacobus Jansen ,  Chuen Yeh ,  Thomas Maschmeyer ,  Frits Dautzenberg ,  Leonardo Marchese ,  Heloise Oliveira Pastore

IPC分类号： B01J29/06

CPC分类号： C10G11/04 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/084 ,  B01J29/166 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/85 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D215/227 ,  C07D301/06 ,  C07D301/10 ,  C10G2/332 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G45/68 ,  C10G47/00 ,  C10G47/14 ,  C10G47/16 ,  C10G49/02 ,  C10G49/08 ,  C10G50/00 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/10 ,  C10G2400/30 ,  C07C15/073 ,  C07C49/84

摘要： A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.

摘要翻译： 催化材料包括负载在介孔无机氧化物载体上的微孔沸石。 微孔沸石可以包括沸石β，沸石Y（包括“超稳定Y”-USY），丝光沸石，沸石L，ZSM-5，ZSM-11，ZSM-12，ZSM-20，Theta-1，ZSM-23， ZSM-34，ZSM-35，ZSM-48，SSZ-32，PSH-3，MCM-22，MCM-49，MCM-56，ITQ-1，ITQ-2，ITQ-4，ITQ-21，SAPO- 5，SAPO-11，SAPO-37，Breck-6，ALPO 4 -5等。介孔无机氧化物可以是例如二氧化硅或硅酸盐。 催化材料可以通过引入一些金属进一步改性，例如 铝，钛，钼，镍，钴，铁，钨，钯和铂。 可用作酰化，烷基化，二聚，低聚，聚合，氢化，脱氢，芳构化，异构化，加氢处理，催化裂化和加氢裂化反应的催化剂。

公开(公告)号：US20050164870A1

公开(公告)日：2005-07-28

申请号：US10764797

申请日：2004-01-26

申请人： Zhiping Shan ,  Xintao Gao ,  Chuen Yeh ,  Philip Angevine ,  Martin Kraus

发明人： Zhiping Shan ,  Xintao Gao ,  Chuen Yeh ,  Philip Angevine ,  Martin Kraus

IPC分类号： B01J21/04 ,  B01J21/08 ,  B01J21/10 ,  B01J29/03 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  C01B33/12 ,  C01B37/00 ,  C01B37/02 ,  C01G1/02 ,  B01J29/06

CPC分类号： B01J35/10 ,  B01J21/08 ,  B01J21/10 ,  B01J29/0308 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/036 ,  C01B37/00 ,  C01B37/02 ,  C01G1/02

摘要： A method for making a mesoporous or combined mesoporous/microporous inorganic oxide includes reacting a source of inorganic oxide with a complexing agent at a complexation temperature to provide a complex; decomposing the complex to provide a porous material precursor having an inorganic oxide framework containing at least some organic pore-forming agent; and removing the organic pore forming agent from the inorganic oxide framework by solvent extraction and/or calcination.

摘要翻译： 制备介孔或组合介孔/微孔无机氧化物的方法包括在络合温度下使无机氧化物源与络合剂反应以提供络合物; 分解复合物以提供具有含有至少一些有机成孔剂的无机氧化物骨架的多孔材料前体; 并通过溶剂萃取和/或煅烧从无机氧化物骨架中除去有机成孔剂。

公开(公告)号：US20060264318A1

公开(公告)日：2006-11-23

申请号：US11446320

申请日：2006-06-02

申请人： Zhiping Shan ,  Peter Waller ,  Bowden Maingay ,  Philip Angevine ,  Jacobus Jansen ,  Chuen Yeh ,  Thomas Maschmeyer ,  Frits Dautzenberg ,  Leonardo Marchese ,  Heloise Pastore

发明人： Zhiping Shan ,  Peter Waller ,  Bowden Maingay ,  Philip Angevine ,  Jacobus Jansen ,  Chuen Yeh ,  Thomas Maschmeyer ,  Frits Dautzenberg ,  Leonardo Marchese ,  Heloise Pastore

IPC分类号： B01J29/04

CPC分类号： C10G11/04 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/084 ,  B01J29/166 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/85 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D215/227 ,  C07D301/06 ,  C07D301/10 ,  C10G2/332 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G45/68 ,  C10G47/00 ,  C10G47/14 ,  C10G47/16 ,  C10G49/02 ,  C10G49/08 ,  C10G50/00 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/10 ,  C10G2400/30 ,  C07C15/073 ,  C07C49/84

摘要： A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.

公开(公告)号：US20050197499A1

公开(公告)日：2005-09-08

申请号：US10795726

申请日：2004-03-08

申请人： Zhiping Shan ,  Chuen Yeh ,  Philip Angevine ,  Frits Dautzenberg ,  Jacobus Jansen

发明人： Zhiping Shan ,  Chuen Yeh ,  Philip Angevine ,  Frits Dautzenberg ,  Jacobus Jansen

IPC分类号： C07D301/12 ,  C07D201/04

CPC分类号： C07D301/19 ,  Y02P20/125

摘要： An integrated process combines olefin epoxidation with production of cyclohexanone and cyclohexanol for nylon. Cyclohexanone and cyclohexanol normally produced by the oxidation of cyclohexane, in which cyclohexyl hydroperoxide is generated and is removed or decomposed down stream. However, this invention utilizes the intermediate of cyclohexyl hydroperoxide as an oxidant for the olefin epoxidation and meanwhile generates a valuable product.

摘要翻译： 一体化方法将烯烃环氧化与生产环己酮和环己醇用于尼龙。 通常通过环己烷氧化生成环己酮和环己醇，其中产生环己基氢过氧化物并在流下被除去或分解。 然而，本发明利用环己基氢过氧化物的中间体作为烯烃环氧化的氧化剂，同时产生有价值的产物。

公开(公告)号：US20050194289A1

公开(公告)日：2005-09-08

申请号：US11023724

申请日：2004-12-28

申请人： Rudolf Overbeek ,  Nelleke Puil ,  Chuen Yeh ,  Lawrence Murrell ,  Yun-Feng Chang ,  Philip Angevine ,  Johannes Koegler

发明人： Rudolf Overbeek ,  Nelleke Puil ,  Chuen Yeh ,  Lawrence Murrell ,  Yun-Feng Chang ,  Philip Angevine ,  Johannes Koegler

IPC分类号： B01D53/02 ,  B01J6/00 ,  B01J8/18 ,  B01J20/18 ,  B01J29/06 ,  B01J29/70 ,  B01J35/00 ,  B01J37/00 ,  B01J37/08 ,  B01J37/14 ,  C01B37/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/48 ,  C07C2/58 ,  C07C2/66 ,  C10G29/20 ,  C10G45/64 ,  C10G47/16 ,  C10G11/00 ,  C01B39/26 ,  C01B39/42 ,  C10G11/04

CPC分类号： C10G47/16 ,  B01D53/02 ,  B01J6/001 ,  B01J8/18 ,  B01J20/183 ,  B01J29/18 ,  B01J29/7007 ,  B01J29/7034 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/08 ,  B01J37/14 ,  B01J2219/0254 ,  B01J2229/40 ,  B01J2229/64 ,  C01B39/04 ,  C01B39/265 ,  C01B39/42 ,  C01B39/48 ,  C07C2/66 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/70 ,  C10G11/05 ,  C10G29/205 ,  C10G45/64 ,  C07C15/073

摘要： A method for making a zeolite includes providing a reaction mixture containing mixed inorganic oxides and an organic templating agent, heating the reaction mixture, removing the templating agent at a temperature of no greater than 550° C. and under conditions such that the resulting zeolite is has an AAI of at least 1.2. The zeolite is preferably zeolite beta, TEA-mordenite or TEA-ZSM-12.

摘要翻译： 制备沸石的方法包括提供含有混合无机氧化物和有机模板剂的反应混合物，加热反应混合物，在不高于550℃的温度下除去模板剂，并在使得所得沸石为 具有至少1.2的AAI。 沸石优选为沸石β，TEA-丝光沸石或TEA-ZSM-12。