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公开(公告)号：US5440805A
公开(公告)日：1995-08-15
申请号：US127975
申请日：1993-09-27
IPC分类号： H01L21/48 , H01L23/498 , H01L23/538 , H05K1/00 , H05K1/02 , H05K3/20 , H05K3/24 , H05K3/28 , H05K3/32 , H05K3/42 , H05K3/46 , H05K3/36
CPC分类号： H05K3/4632 , H01L21/4857 , H01L23/49894 , H01L23/5383 , H05K3/205 , H05K3/4617 , H05K3/4647 , H05K3/4682 , H01L2221/68345 , H01L2924/0002 , H05K1/0206 , H05K1/0289 , H05K2201/0129 , H05K2201/015 , H05K2201/09563 , H05K2203/0726 , H05K2203/0733 , H05K2203/1189 , H05K3/20 , H05K3/243 , H05K3/28 , H05K3/328 , H05K3/423 , H05K3/4652 , H05K3/4658 , Y10T29/49126 , Y10T29/49155 , Y10T29/49165
摘要： In accordance with the present invention, a circuit assembly is manufactured in an additive process using at least one layer of a fluoropolymer composite material and a conductive material. The conductive layers are plated, and the fluoropolymer composite layers are laminated. The use of the filled fluoropolymeric composite eliminates the need for a barrier metal layer between the insulation and the conductors. A plurality of these circuit assemblies are stacked, one on top of the other. At least, selected exposed locations of the conductive material comprise a diffusible conductive material (e.g., gold). Once stacked the circuit assemblies are subjected to lamination under heat and pressure to simultaneously fuse adjacent fluoropolymer composite material and diffuse adjacent diffusible conductive material together to form an integral multilayer circuit having solid conductive interconnects.
摘要翻译： 根据本发明，使用至少一层含氟聚合物复合材料和导电材料的添加工艺制造电路组件。 对导电层进行电镀，层压含氟聚合物复合层。 使用填充的氟聚合物复合材料消除了在绝缘体和导体之间的阻挡金属层的需要。 多个这些电路组件一个在另一个之上堆叠。 至少，导电材料的选定的暴露位置包括可扩散的导电材料（例如金）。 一旦堆叠，电路组件在热和压力下进行层压以同时熔化相邻的含氟聚合物复合材料并将相邻的可扩散导电材料扩散在一起以形成具有固体导电互连的整体多层电路。
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公开(公告)号：US5024871A
公开(公告)日：1991-06-18
申请号：US483501
申请日：1990-02-21
申请人： David J. Arthur , Gwo S. Swei
发明人： David J. Arthur , Gwo S. Swei
IPC分类号： C08K3/00 , C04B26/08 , C04B35/14 , C04B41/45 , C08K9/00 , C08K9/04 , C08L27/12 , H01B1/22 , H01L23/14 , H05K1/03 , H05K3/38 , H05K3/46
CPC分类号： C04B41/009 , C04B26/08 , C04B35/14 , C04B41/4584 , C08K9/04 , H01L23/145 , H05K1/0373 , C04B2111/00844 , H01L2924/0002 , H05K1/034 , H05K1/0366 , H05K2201/015 , H05K2201/0195 , H05K2201/0209 , H05K2201/0239 , H05K3/4626 , Y10S428/901 , Y10T428/24917 , Y10T428/25 , Y10T428/259 , Y10T428/29 , Y10T428/3154
摘要： A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a zirconate coupling agent and/or a titanate coupling agent.
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公开(公告)号：US5384181A
公开(公告)日：1995-01-24
申请号：US131870
申请日：1993-10-05
CPC分类号： H05K1/0373 , C08K9/06 , H01B3/445 , H01L23/145 , H01L2924/0002 , H05K1/034 , H05K1/0366 , H05K1/056 , H05K2201/015 , H05K2201/0195 , H05K2201/0209 , H05K2201/0239 , H05K2201/0251 , H05K2201/068 , H05K3/389 , H05K3/4626 , Y10S428/901 , Y10T428/24802 , Y10T428/252 , Y10T428/259 , Y10T428/2995 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663 , Y10T428/31692
摘要： A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a silane and the ceramic has a volume % fraction of between about 26-45. The composite of this invention exhibits excellent chemical resistance, particularly to alkaline environments. Preferably, the silane comprises a blend of at least one phenyl silane and at least one fluorosilane. The silane is preferably coated to a level of 10% of the total weight of ceramic filler.
摘要翻译： 提出了一种复合材料，其由陶瓷填充的含氟聚合物组成，其中陶瓷涂覆有硅烷，陶瓷的体积％分数介于约26-45之间。 本发明的复合材料表现出优异的耐化学性，特别是对碱性环境。 优选地，硅烷包含至少一种苯基硅烷和至少一种氟硅烷的共混物。 优选将硅烷涂覆至陶瓷填料总重量的10％的水平。
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公开(公告)号：US5374453A
公开(公告)日：1994-12-20
申请号：US90488
申请日：1993-07-13
申请人： Gwo S. Swei , David J. Arthur
发明人： Gwo S. Swei , David J. Arthur
IPC分类号： B29C41/28 , B29D7/01 , C08J3/00 , C08J3/215 , C08J9/26 , H05K1/03 , H05K1/05 , H05K3/38 , B05D3/02
CPC分类号： C08J9/26 , B29C41/28 , B29D7/01 , C08J3/005 , C08J3/215 , H05K1/034 , H05K1/0373 , B29K2027/18 , B29K2105/04 , B29K2105/16 , C08J2327/12 , H05K1/056 , H05K2201/015 , H05K2201/0209 , H05K2201/0212 , H05K2201/0215 , H05K2201/0239 , H05K3/386 , Y02P20/582
摘要： A method for making a particulate filled polymeric matrix composite film includes mixing a polymeric matrix material with a dispersion of particulate filler in a carrier liquid to form a casting composition and adjusting the viscosity of the casting composition to retard separation of the particulate filler from the composition. A layer of the viscosity-adjusted casting composition is cast on a substrate and the layer is consolidated to form the particulate filled polymer matrix composite film. Films made by the method include very thin, e.g less than 1.0 mil, fluoropolymeric matrix films highly filled with very small diameter, preferably spherical, particles for use as, e.g. dielectric substrate materials in laminar electrical circuits.
摘要翻译： 制备颗粒填充的聚合物基质复合膜的方法包括将聚合物基体材料与颗粒填料的分散体混合在载体液体中以形成流延组合物并调节流延组合物的粘度以阻止颗粒填料与组合物的分离 。 将粘度调节的浇铸组合物的一层浇铸在基材上，并将该层固结以形成填充颗粒的聚合物基质复合膜。 通过该方法制备的膜包括非常薄的，例如小于1.0密耳的高度填充有非常小直径，优选球形的颗粒的含氟聚合物基质膜，用于例如， 层状电路中的电介质基片材料。
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公开(公告)号：US5281466A
公开(公告)日：1994-01-25
申请号：US703633
申请日：1991-05-22
IPC分类号： C04B26/08 , C04B35/14 , C04B41/45 , C08K9/02 , C08K9/04 , C08K9/06 , H01B3/44 , H01L23/14 , H05K1/03 , H05K1/05 , H05K3/38 , H05K3/46 , B32B3/00
CPC分类号： H05K3/4626 , C04B26/08 , C04B35/14 , C04B41/4584 , C08K9/02 , C08K9/04 , C08K9/06 , H01B3/445 , H01L23/145 , H05K1/0373 , H01L2924/0002 , H05K1/034 , H05K1/0366 , H05K1/05 , H05K1/056 , H05K2201/015 , H05K2201/0195 , H05K2201/0209 , H05K2201/0239 , H05K2201/0251 , H05K2201/068 , H05K3/389 , H05K3/4611 , Y10S428/901 , Y10T428/24802 , Y10T428/252 , Y10T428/259 , Y10T428/2995 , Y10T428/3154 , Y10T428/31544 , Y10T428/31692
摘要： A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a zirconate coupling agent and/or a titanate coupling agent and the ceramic has a volume % fraction of between about 26-45.
摘要翻译： 提出了一种复合材料，其由陶瓷填充的含氟聚合物组成，其中陶瓷涂覆有锆酸酯偶联剂和/或钛酸酯偶联剂，陶瓷的体积％分数为约26-45。
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公开(公告)号：US5354611A
公开(公告)日：1994-10-11
申请号：US71345
申请日：1993-05-28
申请人： David J. Arthur , Gwo S. Swei , Phong X. Nguyen
发明人： David J. Arthur , Gwo S. Swei , Phong X. Nguyen
CPC分类号： H05K1/0373 , C08K7/28 , C08K9/04 , H05K1/034 , H05K2201/0116 , H05K2201/015 , H05K2201/0209 , H05K2201/0239 , H05K2201/0254 , Y10T428/252 , Y10T428/259 , Y10T428/2982 , Y10T428/2995 , Y10T428/2996 , Y10T428/3154 , Y10T428/31544
摘要： A composite material is disclosed. The material comprises a polymeric matrix and from about 20 volume percent to about 70 volume percent inorganic particles distributed throughout the matrix. Suitable inorganic particles include hollow inorganic microspheres and porous inorganic particles. The inorganic particles are coated with a surface coating. The composite material of the present invention exhibits a dielectric constant of less than about 2.5 and a thermal coefficient of expansion of less than about 70 ppm/.degree.C.
摘要翻译： 公开了一种复合材料。 该材料包括聚合物基质和分布在整个基质中的约20体积％至约70体积％的无机颗粒。 合适的无机颗粒包括中空无机微球和多孔无机颗粒。 无机颗粒用表面涂层涂覆。 本发明的复合材料的介电常数小于约2.5，热膨胀系数小于约70ppm /℃。
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公开(公告)号：US5312576A
公开(公告)日：1994-05-17
申请号：US704983
申请日：1991-05-24
申请人： Gwo S. Swei , David J. Arthur
发明人： Gwo S. Swei , David J. Arthur
IPC分类号： B29C41/28 , B29D7/01 , C08J3/00 , C08J3/215 , C08J9/26 , H05K1/03 , H05K1/05 , H05K3/38 , B29C39/00 , B32B27/00
CPC分类号： C08J9/26 , B29C41/28 , B29D7/01 , C08J3/005 , C08J3/215 , H05K1/034 , H05K1/0373 , B29K2027/18 , B29K2105/04 , B29K2105/16 , B29K2995/0006 , C08J2327/12 , H05K1/056 , H05K2201/015 , H05K2201/0209 , H05K2201/0212 , H05K2201/0215 , H05K2201/0239 , H05K3/386 , Y02P20/582
摘要： A method for making a particulate filled polymeric matrix composite film includes mixing a polymeric matrix material with a dispersion of particulate filler in a carrier liquid to form a casting composition and adjusting the viscosity of the casting composition to retard separation of the particulate filler from the composition. A layer of the viscosity-adjusted casting composition is cast on a substrate and the layer is consolidated to form the particulate filled polymer matrix composite film. Films made by the method include very thin, e.g. less than 1.0 mil, fluoropolymeric matrix films highly filled with very small diameter, preferably spherical, particles for use as, e.g. dielectric substrate materials in laminar electrical circuits.
摘要翻译： 制备颗粒填充的聚合物基质复合膜的方法包括将聚合物基体材料与颗粒填料的分散体混合在载体液体中以形成流延组合物并调节流延组合物的粘度以阻止颗粒填料与组合物的分离 。 将粘度调节的浇铸组合物的一层浇铸在基材上，并将该层固结以形成填充颗粒的聚合物基质复合膜。 通过该方法制成的膜包括非常薄的，例如 小于1.0密耳，高度填充有非常小直径的氟聚合物基质膜，优选为球形颗粒，用作例如。 层状电路中的电介质基片材料。
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公开(公告)号：US06172139B2
公开(公告)日：2001-01-09
申请号：US08146981
申请日：1993-11-02
申请人： Gwo S. Swei , David J. Arthur
发明人： Gwo S. Swei , David J. Arthur
IPC分类号： C08J305
CPC分类号： C08J9/26 , B29C41/28 , B29D7/01 , B29K2027/18 , B29K2105/04 , B29K2105/16 , B29K2995/0006 , C08J3/005 , C08J3/215 , C08J2327/12 , H05K1/034 , H05K1/0373 , H05K1/056 , H05K3/386 , H05K2201/015 , H05K2201/0209 , H05K2201/0212 , H05K2201/0215 , H05K2201/0239 , Y02P20/582
摘要： A method for making a particulate filled polymeric matrix composite film includes mixing a polymeric matrix material with a dispersion of particulate filler in a carrier liquid to form a casting composition and adjusting the viscosity of the casting composition to retard separation of the particulate filler from the composition. A layer of the viscosity-adjusted casting composition is cast on a substrate and the layer is consolidated to form the particulate filled polymer matrix composite film. Films made by the method include very thin, e.g less than 1.0 mil, fluoropolymeric matrix films highly filled with very small diameter, preferably spherical, particles for use as, e.g. dielectric substrate materials in laminar electrical circuits.
摘要翻译： 制备颗粒填充的聚合物基质复合膜的方法包括将聚合物基体材料与颗粒填料的分散体混合在载体液体中以形成流延组合物并调节流延组合物的粘度以阻止颗粒填料与组合物的分离 。 将粘度调节的浇铸组合物的一层浇铸在基材上，并将该层固结以形成填充颗粒的聚合物基质复合膜。 通过该方法制备的膜包括非常薄的，例如小于1.0密耳的高度填充有非常小直径，优选球形的颗粒的含氟聚合物基质膜，用于例如， 层状电路中的电介质基片材料。
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公开(公告)号：US5198295A
公开(公告)日：1993-03-30
申请号：US704303
申请日：1991-05-22
申请人： David J. Arthur , Gwo S. Swei , Allen F. Horn, III
发明人： David J. Arthur , Gwo S. Swei , Allen F. Horn, III
IPC分类号： C04B26/08 , C04B35/14 , C04B41/45 , C08K9/02 , C08K9/04 , C08K9/06 , H01B3/44 , H01L23/14 , H05K1/03 , H05K1/05 , H05K3/38 , H05K3/46
CPC分类号： H05K3/4626 , C04B26/08 , C04B35/14 , C04B41/4584 , C08K9/02 , C08K9/04 , C08K9/06 , H01B3/445 , H01L23/145 , H05K1/0373 , H01L2924/0002 , H05K1/034 , H05K1/0366 , H05K1/05 , H05K1/056 , H05K2201/015 , H05K2201/0195 , H05K2201/0209 , H05K2201/0239 , H05K2201/0251 , H05K2201/068 , H05K3/389 , H05K3/4611 , Y10S428/901 , Y10T428/25 , Y10T428/252 , Y10T428/259 , Y10T428/2982 , Y10T428/2991 , Y10T428/2995 , Y10T428/3154 , Y10T428/31544
摘要： A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a titanate and/or zirconate and the ceramic has a volume % fraction of between about 45-50.
摘要翻译： 提出了一种复合材料，其由陶瓷填充的含氟聚合物组成，其中陶瓷涂覆有钛酸盐和/或锆酸盐，陶瓷的体积％分数在约45-50之间。
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公开(公告)号：US5194326A
公开(公告)日：1993-03-16
申请号：US704320
申请日：1991-05-22
申请人： David J. Arthur , Gwo S. Swei , Allen F. Horn, III
发明人： David J. Arthur , Gwo S. Swei , Allen F. Horn, III
IPC分类号： B32B15/08 , C08K9/06 , C09C3/12 , C09D127/12 , H01B3/00 , H01B3/44 , H01L23/14 , H05K1/03 , H05K1/05 , H05K3/38 , H05K3/46
CPC分类号： H05K3/4626 , C08K9/06 , H01B3/445 , H01L23/145 , H05K1/0373 , H01L2924/0002 , H05K1/034 , H05K1/0366 , H05K1/05 , H05K1/056 , H05K2201/015 , H05K2201/0195 , H05K2201/0209 , H05K2201/0239 , H05K2201/0251 , H05K2201/068 , H05K3/389 , H05K3/4611 , Y10T428/24372 , Y10T428/24917 , Y10T428/252 , Y10T428/254 , Y10T428/3154 , Y10T428/31544
摘要： A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a fluorosilane and the ceramic has a volume % fraction of between about 45-50.
摘要翻译： 提出了一种复合材料，其由陶瓷填充的含氟聚合物组成，其中陶瓷涂覆有氟硅烷，陶瓷的体积％分数在约45-50之间。
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