Microwave annealing of flowable oxides with trap layers

    公开(公告)号:US10211045B1

    公开(公告)日:2019-02-19

    申请号:US15878502

    申请日:2018-01-24

    Abstract: An insulator is formed by flowable chemical vapor deposition (FCVD) process. The insulator is cured by exposing the insulator to ultraviolet light while flowing ozone over the insulator to produce a cured insulator. The curing process forms nitrogen, hydrogen, nitrogen monohydride, or hydroxyl-rich atomic clusters in the insulator. Following the curing process, these methods select wavelengths of microwave radiation (that will be subsequently used during annealing) so that such wavelengths excite the nitrogen, hydrogen, nitrogen monohydride, or hydroxyl-rich atomic clusters. Then, these methods anneal the cured insulator by exposing the cured insulator to microwave radiation in an inert (e.g., non-oxidizing) ambient atmosphere, at a temperature below 500° C., so as to increase the density of the cured insulator.

    Concurrently forming nFET and pFET gate dielectric layers
    7.
    发明授权
    Concurrently forming nFET and pFET gate dielectric layers 有权
    同时形成nFET和pFET栅极电介质层

    公开(公告)号:US09059315B2

    公开(公告)日:2015-06-16

    申请号:US13732455

    申请日:2013-01-02

    CPC classification number: H01L21/823857

    Abstract: Embodiments include methods of forming an nFET-tuned gate dielectric and a pFET-tuned gate dielectric. Methods may include forming a high-k layer above a substrate having a pFET region and an nFET region, forming a first sacrificial layer, a pFET work-function metal layer, and a second sacrificial layer above the first high-k layer in the pFET region, and an nFET work-function metal layer above the first high-k layer in the nFET region and above the second sacrificial layer in the pFET region. The first high-k layer then may be annealed to form an nFET gate dielectric layer in the nFET region and a pFET gate dielectric layer in the pFET region. The first high-k layer may be annealed in the presence of a nitrogen source to cause atoms from the nitrogen source to diffuse into the first high-k layer in the nFET region.

    Abstract translation: 实施例包括形成nFET调谐的栅极电介质和pFET调谐的栅极电介质的方法。 方法可以包括在pFET区域和nFET区域之上形成高k层,形成第一牺牲层,pFET功函数金属层和在pFET中的第一高k层上方的第二牺牲层 区域,以及在nFET区域中的第一高k层上方的nFET功函数金属层,并且在pFET区域中的第二牺牲层上方。 第一高k层然后可以退火以在nFET区域中形成nFET栅极介电层,并在pFET区域中形成pFET栅极电介质层。 第一高k层可以在存在氮源的情况下进行退火,以使来自氮源的原子扩散到nFET区域中的第一高k层。

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