摘要:
A method of manufacturing a perovskite catalyst composed of perovskite oxide includes mixing step, firing step and acid-treating step. In the mixing step, an A-site material and a B-site material are mixed at a stoichiometric ratio such that the A-site is increased, compared to that of a theoretical composition ABO3 of perovskite oxide in which a ratio of A-site and B-site is 1:1. In the firing step, the obtained mixed powder is fired. In the acid-treating step, the obtained fired powder is acid-treated with acid of pH 2 or more and less than pH 7.
摘要:
A method of producing porous complex oxides includes the steps of providing a mixture of a) precursor elements suitable to produce the complex oxide; or b) one or more precursor elements suitable to produce particles of the complex oxide and one or more metal oxide particles; and c) a particulate carbon-containing pore-forming material selected to provide pore sizes in the range of approximately 7 nm to 250 nm, and treating the mixture to (i) form the porous complex oxide in which two or more of the precursor elements from (a) above or one or more of the precursor elements and one or more of the metals in the metal oxide particles from (b) above are incorporated into a phase of the complex metal oxide and the complex metal oxide has grain sizes in the range of about 1 nm to 150 nm; and (ii) remove the pore-forming material under conditions such that the porous structure and composition of the complex oxide is substantially preserved. The method may be used to produce non-refractory metal oxides as well.
摘要:
The present invention is generally directed to a novel, economic synthesis of oxide ceramic composites. Methods of the present invention, referred to as carbon combustion synthesis of oxides (CCSO), are a modification of self-propagating high-temperature synthesis (SHS) methods in which the heat needed for the synthesis is generated by combustion of carbon in oxygen rather than that of a pure metal. This enables a more economic production of the ceramic material and minimizes the presence of intermediate metal oxides in the product. The reactant mixture generally comprises at least one oxide precursor (e.g., a metal or non metal oxide, or super oxide, or nitride, or carbonate, or chloride, or oxalate, or halides) as a reactant, but no pure metal. Pure carbon in the form of graphite or soot is added to the reactant mixture to generate the desired heat (upon ignition). The mixture is placed in a reactor and exposed to gaseous oxygen. The high-temperature exothermic reaction between the carbon and oxygen generates a self-sustaining reaction in the form of a propagating temperature wave that causes a reaction among the reactants. The reaction proceeds rapidly following ignition, and the final product comprises simple and/or complex oxides of elements present in the oxide precursor(s). CCSO also enables synthesis of oxides that cannot be produced by conventional SHS, such as when the pure metal is pyrophoric (such as Li or La) or such as when it melts at room temperature (e.g., Ga) or such as the combustion heat of the metal is relatively low.
摘要:
Nanocrystalline forms of metal oxides, including binary metal oxide, perovskite type metal oxides, and complex metal oxides, including doped metal oxides, are provided. Methods of preparation of the nanocrystals are also provided. The nanocrystals, including uncapped and uncoated metal oxide nanocrystals, can be dispersed in a liquid to provide dispersions that are stable and do not precipitate over a period of time ranging from hours to months. Methods of preparation of the dispersions, and methods of use of the dispersions in forming films, are likewise provided. The films can include an organic, inorganic, or mixed organic/inorganic matrix. The films can be substantially free of all organic materials. The films can be used as coatings, or can be used as dielectric layers in a variety of electronics applications, for example as a dielectric material for an ultracapacitor, which can include a mesoporous material. Or the films can be used as a high-K dielectric in organic field-effect transistors. In various embodiments, a layered gate dielectric can include spin-cast (e.g., 8 nm-diameter) high-K BaTiO3 nanocrystals and parylene-C for pentacene OFETs.
摘要:
The invention relates to an oxide material of general formula (I) A2-x-yA′XA″yM1-z M′Z04+7, wherein A and A′ are independently a metal cation of a group formed by lanthanides and/or alkalis and/or alkaline earths, A″ is a cationic gap, i.e. a cation vacancy A and/or A′, M and M′ are independently a metal of a group formed by transition metals such as 0
摘要:
Solid membranes comprising an intimate, gas-impervious, multi-phase mixture of an electronically-conductive material and an oxygen ion-conductive material and/or a mixed metal oxide of a perovskite structure are described. Electrochemical reactor components, such as reactor cells, and electrochemical reactors are also described for transporting oxygen from any oxygen-containing gas to any gas or mixture of gases that consume oxygen. The reactor cells generally comprise first and second zones separated by an element having a first surface capable of reducing oxygen to oxygen ions, a second surface capable of reacting oxygen ions with an oxygen-consuming gas, an electron-conductive path between the first and second surfaces and an oxygen ion-conductive path between the first and second surfaces. The element may further comprise (1) a porous substrate, (2) an electron-conductive metal, metal oxide or mixture thereof and/or (3) a catalyst. The reactor cell may further comprise a catalyst in the zone which comprises a passageway from an entrance end to an exit end of the element. Processes described which may be conducted with the disclosed reactor cells and reactors include, for example, the partial oxidation of methane to produce unsaturated compounds or synthesis gas, the partial oxidation of ethanes substitution of aromatic compounds, extraction of oxygen from oxygen-containing gases, including oxidized gases, ammoxidation of methane, etc. The extraction of oxygen from oxidized gases may be used for flue or exhaust gas cleanup.
摘要:
A ferrite magnet powder and a ferrite magnet exhibiting improved magnetic properties are provided at a reduced manufacturing cost. An application product and manufacturing methods thereof are also provided. An oxide magnetic material includes, as a main phase, a ferrite having a hexagonal M-type magnetoplumbite structure. The material includes: A, which is at least one element selected from the group consisting of Sr, Ba, Pb and Ca; R, which is at least one element selected from the group consisting of Y (yttrium), the rare earth elements and Bi; Fe; and B (boron). The constituents A, R, Fe and B of the material satisfy the inequalities of 7.04 at %≦A≦8.68 at %, 0.07 at %≦R≦0.44 at %, 90.4 at %≦Fe≦92.5 at % and 0.015 at %≦B≦0.87 at % to the sum of the elements A, R, Fe and B.
摘要翻译:以降低的制造成本提供铁氧体磁体粉末和呈现磁性能改善的铁氧体磁体。 还提供了一种应用产品及其制造方法。 氧化物磁性材料包括具有六方M型磁铅矿结构的铁素体作为主相。 该材料包括:A,其为选自Sr,Ba,Pb和Ca中的至少一种元素; R是选自Y(钇),稀土元素和Bi的至少一种元素; 铁 和B(硼)。 材料的成分A,R,Fe和B满足不平等值7.04 at%<= A <= 8.68 at%,0.07 at%<= R <= 0.44 at%,90.4 at%<= Fe <= 92.5 at %和0.015at%<= B <= 0.87 at%的元素A,R,Fe和B之和。
摘要:
A process for the preparation of nanostructured materials in high phase purities using cavitation is disclosed. The method comprises mixing a metal containing solution with a precipitating agent and passing the mixture into a cavitation chamber. The chamber consists of a first element to produce cavitation bubbles, and a second element that creates a pressure zone sufficient to collapse the bubbles. The process is useful for the preparation of mixed metal oxide catalysts and materials for piezoelectrics and superconductors.
摘要:
Solid membranes comprising an intimate, gas-impervious, multi-phase mixture of an electronically-conductive material and an oxygen ion-conductive material and/or a mixed metal oxide of a perovskite structure are described. Electrochemical reactor components, such as reactor cells, and electrochemical reactors are also described. The reactor cells generally comprise first and second zones separated by an element having a first surface capable of reducing oxygen to oxygen ions, a second surface capable of reacting oxygen ions with an oxygen-consuming gas, an electron-conductive path between the first and second surfaces and an oxygen ion-conductive path between the first and second surfaces.
摘要:
A ferrite powder for bonded magnets having a substantially magnetoplumbite-type crystal structure and an average diameter of 0.9-2 &mgr;m, the ferrite powder having a basic composition represented by the following general formula: (A1-xRxO.n[Fe1-yMy)2O3] by atomic ratio, wherein A is Sr and/or Ba; R is at least one of rare earth elements including Y, La being indispensable; M is at least one element selected from the group consisting of Co, Mn, Ni and Zn; and x, y and n are numbers meeting the conditions of 0.01≦x≦0.4, [x/(2.6n)]≦y≦[x/(1.6n)], and 5≦n≦6, (Si+Ca) being 0.2 weight % or less, and (Al+Cr) being 0.13 weight % or less, can be produced by mixing iron oxide containing 0.06 weight % or less of (Si+Ca) and 0.1 weight % or less of (Al+Cr) with compounds of A, R and M elements, calcining the resultant mixture for ferritization, pulverizing the resultant magnetically isotropic ferrite and then heat-treating the pulverized ferrite at 750-950° C. for 0.5-3 hours in the air.