摘要:
A method comprises heating an aqueous solution of colloidal silver particles. A soluble noble metal halide salt is added to the aqueous solution which undergoes a redox reaction on a surface of the silver particles to form noble metal/silver halide SPs, noble metal halide/silver halide SPs or noble metal oxide/silver halide SPs on the surface of the silver particles. The heat is maintained for a predetermined time to consume the silver particles and release the noble metal/silver halide SPs, the noble metal halide/silver halide SPs or the noble metal oxide/silver halide SPs into the aqueous solution. The aqueous solution is cooled. The noble metal/silver halide SPs, the noble metal halide/silver halide SPs or noble metal oxide/silver halide SPs are separated from the aqueous solution. The method optionally includes adding a soluble halide salt to the aqueous solution.
摘要:
A process for adsorbing HCl from a regeneration vent gas. The regeneration vent gas from a regeneration zone is cooled, and the cooled regeneration vent gas is passed to an adsorption zone that is spaced apart from the regeneration zone. A spent catalyst is passed from a reaction zone to the adsorption zone. HCl from the regeneration vent gas is adsorbed onto the spent catalyst in the adsorption zone to enrich the spent catalyst with HCl to provide HCl-rich spent catalyst and deplete HCl from the regeneration vent gas to provide HCl-lean regeneration vent gas. The HCl-lean regeneration vent gas is purged to atmosphere, and the HCl-rich spent catalyst is passed to a regeneration zone disengaging hopper.
摘要:
Apparatuses and methods are provided for regenerating catalyst particles. In one embodiment, a method for regenerating catalyst particles includes passing the catalyst particles through a halogenation zone and a drying zone. The method feeds drying gas to the drying zone and passes a first portion of the drying gas from the drying zone to the halogenation zone. The method includes removing a second portion of the drying gas from the drying zone and injecting a halogen gas into the second portion of the drying gas. Further, the method includes delivering the halogen gas and the second portion of the drying gas to the halogenation zone. In the method, substantially all of the drying gas fed to the drying zone enters the halogenation zone.
摘要:
One exemplary embodiment can be a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, at least two alkali metals or at least two alkaline earth metals, or mixtures of alkali metals and alkaline earth metals and a support.
摘要:
The present disclosure relates to a dehydrogenation catalyst composite comprising at least one alumina support impregnated with at least one layer of at least one alkaline earth metal element and at least one layer comprising at least one catalytic metal element, at least one group VIA element and optionally, at least one halogen element. The present disclosure also relates to a process for preparation of the dehydrogenation catalyst composite.
摘要:
A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising (a) ruthenium metal or a ruthenium oxide, (b) manganese oxide and (c) alkaline metal component or alkaline earth metal component.
摘要:
The present invention relates to catalysts, to processes for making catalysts with halide containing precursors and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid to ethanol. The catalyst comprises a precious metal and one or more active metals on a support, optionally a modified support.
摘要:
A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising a copper oxide and a tellurium oxide.
摘要:
One exemplary embodiment can be a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, a lanthanide-series metal including one or more elements of atomic numbers 57-71 of the periodic table, and a support. Generally, an average bulk density of the catalyst is about 0.300-about 0.620 gram per cubic centimeter, and an atomic ratio of the lanthanide-series metal:noble metal is less than about 1.3:1. Moreover, the lanthanide-series metal can be distributed at a concentration of the lanthanide-series metal in a 100 micron surface layer of the catalyst less than about two times a concentration of the lanthanide-series metal at a central core of the catalyst.