公开(公告)号：US07029642B2

公开(公告)日：2006-04-18

申请号：US11071582

申请日：2005-03-04

申请人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

发明人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

IPC分类号： C01B33/38

CPC分类号： C01B39/48 ,  B01J29/04 ,  B01J29/70 ,  B01J29/74 ,  B01J29/89 ,  C01B37/005 ,  C01B37/02 ,  C01B39/08 ,  C01B39/085 ,  C10G49/08

摘要： The invention concerns a novel crystalline solid UVL-1 which has an X ray diffraction diagram containing at least the following characteristic peaks: dhkl (A)2theta (°)I/I0 11.697.55mw to vs 7.5011.79vw to w 5.7615.36w to mw 3.7024.00m to s 3.5724.91s 3.3626.49vs 3.1428.48w to mw 2.5035.88vw 2.4137.30vw and with a chemical composition, expressed as the anhydrous compound, in terms of moles of oxide: (XO2):(Y2O3)m:(Z2/nO)p in which: X represents at least one tetravalent element selected from the group formed by Si, Ge; Y represents at least one trivalent element selected from Al, B, Cr, Ga; Z represents at least one cation with valency n; and in which: n is in the range 2 to 4, m is in the range 0 to 0.2, preferably in the range 0 to 0.05, and p is in the range 0 to 0.2, preferably in the range 0 to 0.05. The invention also concerns a hydrocracking/hydroconversion process and a hydrorefining process employing said solid in the catalyst composition.

公开(公告)号：US20050277542A1

公开(公告)日：2005-12-15

申请号：US10867507

申请日：2004-06-14

申请人： Mark Kaminsky ,  Roger Grey

发明人： Mark Kaminsky ,  Roger Grey

IPC分类号： B01J29/40 ,  B01J29/80 ,  B01J29/89 ,  B01J29/90 ,  B01J37/00 ,  B01J38/48 ,  B01J38/50 ,  B01J38/52 ,  B01J38/58 ,  C07D301/06 ,  C07D301/10 ,  B01J20/34

CPC分类号： C07D301/06 ,  B01J29/80 ,  B01J29/89 ,  B01J29/90 ,  B01J37/0045 ,  B01J38/48 ,  B01J38/52 ,  B01J2229/42 ,  C07D301/10 ,  Y02P20/584

摘要： Used noble metal-containing titanium or vanadium zeolite catalysts, that have been employed in the epoxidation of olefins with hydrogen and oxygen, are regenerated by contacting the spent catalyst with water or an alcohol/water mixture at a temperature of 25° C. to 200° C.

摘要翻译： 已经用于烯烃与氢气和氧气环氧化的含贵金属的钛或钒沸石催化剂通过在25℃至200℃的温度下将废催化剂与水或醇/水混合物接触来再生 C。

公开(公告)号：US20050196335A1

公开(公告)日：2005-09-08

申请号：US11071582

申请日：2005-03-04

申请人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

发明人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

IPC分类号： B01J21/16 ,  B01J29/04 ,  B01J29/70 ,  B01J29/74 ,  B01J29/89 ,  C01B33/26 ,  C01B33/38 ,  C01B37/00 ,  C01B37/02 ,  C01B39/08 ,  C01B39/48 ,  C07B61/00 ,  C07C4/06 ,  C10G45/12 ,  C10G45/64 ,  C10G47/20 ,  C10G49/08 ,  H04L12/28 ,  H04L29/06 ,  C01B39/46

CPC分类号： C01B39/48 ,  B01J29/04 ,  B01J29/70 ,  B01J29/74 ,  B01J29/89 ,  C01B37/005 ,  C01B37/02 ,  C01B39/08 ,  C01B39/085 ,  C10G49/08

摘要： The invention concerns a novel crystalline solid UVL-1 which has an X ray diffraction diagram containing at least the following characteristic peaks: dhkl (A)2theta (°)I/I0 11.697.55mw to vs 7.5011.79vw to w 5.7615.36w to mw 3.7024.00m to s 3.5724.91s 3.3626.49vs 3.1428.48w to mw 2.5035.88vw 2.4137.30vw and with a chemical composition, expressed as the anhydrous compound, in terms of moles of oxide:  (XO2):(Y2O3)m:(Z2/nO)p in which: X represents at least one tetravalent element selected from the group formed by Si, Ge; Y represents at least one trivalent element selected from Al, B, Cr, Ga; Z represents at least one cation with valency n; and in which: n is in the range 2 to 4, m is in the range 0 to 0.2, preferably in the range 0 to 0.05, and p is in the range 0 to 0.2, preferably in the range 0 to 0.05. The invention also concerns a hydrocracking/hydroconversion process and a hydrorefining process employing said solid in the catalyst composition.

公开(公告)号：US20050182264A1

公开(公告)日：2005-08-18

申请号：US10506584

申请日：2003-02-28

申请人： Hiroaki Abekawa ,  Masaru Ishino

发明人： Hiroaki Abekawa ,  Masaru Ishino

IPC分类号： B01J29/89 ,  C07D301/12

CPC分类号： C07D301/12 ,  B01J29/89 ,  Y02P20/52

摘要： A method is provided for producing propylene oxide, wherein propylene is reacted with hydrogen peroxide in the presence of an organic solvent and a crystalline titanosilicate catalyst having an MWW structure containing Ti, the Ti having been incorporated during crystallization.

摘要翻译： 提供了一种用于生产环氧丙烷的方法，其中丙烯与有机溶剂和具有包含Ti的MWW结构的结晶钛硅酸盐催化剂的存在下与过氧化氢反应，在结晶过程中引入了Ti。

公开(公告)号：US06930219B2

公开(公告)日：2005-08-16

申请号：US10313720

申请日：2002-12-06

申请人： Zhiping Shan ,  Jacobus Cornelius Jansen ,  Chuen Y. Yeh ,  Philip J. Angevine ,  Thomas Maschmeyer ,  Mohamed S. Hamdy

发明人： Zhiping Shan ,  Jacobus Cornelius Jansen ,  Chuen Y. Yeh ,  Philip J. Angevine ,  Thomas Maschmeyer ,  Mohamed S. Hamdy

IPC分类号： B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/00 ,  B01J29/03 ,  B01J29/04 ,  B01J29/08 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  B01J37/10 ,  C01B13/36 ,  C01B33/12 ,  C01B37/00 ,  C01B37/02 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G2/00 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/20 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C2/12 ,  A61K38/00 ,  C07C5/03 ,  C07C5/10 ,  C07C5/22 ,  C07C5/32 ,  C07C5/333 ,  C07C37/00 ,  C07C249/00 ,  C07D301/00 ,  C10G11/02 ,  C10G25/00 ,  C10G73/02

CPC分类号： C10G2/332 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J29/046 ,  B01J29/084 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C15/073 ,  C07C49/84

摘要： A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of silica containing at least 97% by volume of pores having a pore size ranging from about 15 Å to about 30 Å and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2θ. The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.

摘要翻译： 一种用于处理有机化合物的方法包括提供一种组合物，其包括基本上介孔结构的二氧化硅，其含有至少97体积％的孔径范围为约至约的孔，并且具有至少约0.01的微孔体积 cc / g，其中介孔结构具有至少约0.02重量％的至少一种选自Al，Ti，V，Cr，Zn，Fe，Sn，Mo的催化和/或化学活性的杂原子 ，Ga，Ni，Co，In，Zr，Mn，Cu，Mg，Pd，Pt和W，催化剂在2θ处具有0.3°至约3.5°的一个峰的X射线衍射图。 催化剂在反应条件下与有机原料接触，其中处理过程选自烷基化，酰化，低聚，选择性氧化，加氢处理，异构化，脱金属催化脱蜡，羟基化，氢化，氨肟化，异构化，脱氢，裂化和吸附。

公开(公告)号：US06858129B2

公开(公告)日：2005-02-22

申请号：US10635400

申请日：2003-08-06

申请人： Gary David Mohr ,  Kenneth Ray Clem ,  Wilfried Jozef Mortier ,  Machteld Maria Mertens ,  Xiaobing Feng ,  Marc H. Anthonis ,  Bart Schoofs

发明人： Gary David Mohr ,  Kenneth Ray Clem ,  Wilfried Jozef Mortier ,  Machteld Maria Mertens ,  Xiaobing Feng ,  Marc H. Anthonis ,  Bart Schoofs

IPC分类号： B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  B01J29/87 ,  B01J29/89 ,  B01J37/00 ,  C10G11/05 ,  C10G29/20 ,  C10G45/64 ,  C07C5/22

CPC分类号： B01J29/7042 ,  B01J29/06 ,  B01J29/40 ,  B01J29/80 ,  B01J29/87 ,  B01J29/89 ,  B01J37/0009 ,  B01J2229/42 ,  B01J2229/62 ,  C10G11/05 ,  C10G29/205 ,  C10G45/64

摘要： There is provided a zeolite bound zeolite catalyst which does not contain significant amount of non-zeolitic binder and can be tailored to optimize its performance and a process for converting hydrocarbons utilizing the zeolite bound zeolite catalyst. The zeolite bound zeolite catalyst comprises core crystals containing first crystals of a first zeolite and optionally second crystals of a second zeolite having a composition, structure type, or both that is different from said first zeolite and binder crystals containing third crystals of a third zeolite and optionally fourth crystals of a fourth zeolite having a composition, structure type, or both that is different from said third zeolite. If the core crystals do not contain the second crystals of the second zeolite, then the binder crystals must contain the fourth crystals of the fourth zeolite. The zeolite bound zeolite finds application in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportional of toluene, isomerization, and transalkylation reactions.

摘要翻译： 提供沸石结合的沸石催化剂，其不含有显着量的非沸石粘合剂，并且可以调整其优化其性能，以及使用沸石结合的沸石催化剂转化烃的方法。 沸石结合的沸石催化剂包括含有第一沸石的第一晶体的芯晶体和任选具有与所述第一沸石不同的组成，结构类型或两者的第二沸石的第二晶体，以及包含第三沸石的第三晶体的粘结剂晶体， 任选具有与所述第三沸石不同的组成，结构类型或二者的第四沸石的第四晶体。 如果核心晶体不含第二沸石的第二晶体，则粘合剂晶体必须含有第四沸石的第四晶体。 沸石结合的沸石可用于烃转化过程，例如催化裂化，烷基化，甲苯不成比例，异构化和烷基转移反应。

公开(公告)号：US20050014636A1

公开(公告)日：2005-01-20

申请号：US10618909

申请日：2003-07-14

申请人： Bing Zhou ,  Michael Rueter

发明人： Bing Zhou ,  Michael Rueter

IPC分类号： B01J21/18 ,  B01J23/16 ,  B01J23/38 ,  B01J23/40 ,  B01J23/44 ,  B01J23/70 ,  B01J29/89 ,  B01J35/00 ,  B01J37/02 ,  B01J37/18 ,  C01B3/40 ,  C01B15/029 ,  H01M4/90 ,  C08F20/02 ,  B01J31/00

CPC分类号： H01M4/9075 ,  B01J21/18 ,  B01J23/16 ,  B01J23/38 ,  B01J23/40 ,  B01J23/44 ,  B01J23/70 ,  B01J29/89 ,  B01J35/0013 ,  B01J37/0203 ,  B01J37/18 ,  C01B3/40 ,  C01B15/029 ,  C01B2203/1047 ,  H01M4/90 ,  Y02P20/52

摘要： Intermediate precursor compositions for use in manufacturing supported reactive catalysts having a controlled coordination structure, and methods for manufacturing such precursor compositions are disclosed. The precursor compositions include a catalyst complex formed from catalyst atoms and a control agent that is applied to a substrate. Reduction of the catalyst complex yields supported reactive catalyst in which a preponderance of the top or outer layer of atoms of the catalyst particles exhibit a controlled coordination number of 2. The supported catalysts are useful for a variety of chemical reactions, including the preparation of hydrogen peroxide with high selectivity.

摘要翻译： 公开了用于制备具有受控配位结构的负载型反应性催化剂的中间体前体组合物，以及制备这种前体组合物的方法。 前体组合物包括由催化剂原子形成的催化剂络合物和施加到基材上的控制剂。 催化剂络合物的还原产生支持的反应催化剂，其中催化剂颗粒的顶部或外层原子的优势表现出受控的配位数2.支持的催化剂可用于各种化学反应，包括制备氢 过氧化物具有高选择性。

公开(公告)号：US20050013773A1

公开(公告)日：2005-01-20

申请号：US10875087

申请日：2004-06-24

申请人： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Johannes Koegler ,  Thomas Maschmeyer

发明人： Zhiping Shan ,  Jacobus Jansen ,  Chuen Yeh ,  Johannes Koegler ,  Thomas Maschmeyer

IPC分类号： C01B13/14 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/00 ,  B01J29/03 ,  B01J29/04 ,  B01J29/08 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J32/00 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  B01J37/08 ,  B01J37/10 ,  C01B13/32 ,  C01B13/36 ,  C01B33/113 ,  C01B33/12 ,  C01B33/26 ,  C01B37/00 ,  C01B37/02 ,  C01B39/00 ,  C07B61/00 ,  C07C2/66 ,  C07C15/073 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G2/00 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/20 ,  C10G35/095 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G47/16 ,  C10G47/20 ,  C10G49/08 ,  C10G50/00 ,  C01F7/00

CPC分类号： B82Y30/00 ,  B01J21/06 ,  B01J21/12 ,  B01J23/26 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/04 ,  B01J29/041 ,  B01J29/084 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/80 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/033 ,  B01J37/10 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J2229/62 ,  C01B13/366 ,  C01B33/126 ,  C01B37/005 ,  C01B37/02 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C07C2/66 ,  C07C45/46 ,  C07D301/06 ,  C07D301/10 ,  C10G2/332 ,  C10G11/04 ,  C10G11/05 ,  C10G27/04 ,  C10G29/205 ,  C10G45/00 ,  C10G45/04 ,  C10G45/12 ,  C10G45/60 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G49/08 ,  C10G50/00 ,  C07C15/073 ,  C07C49/84

摘要： A catalytic material includes a microporous zeolite supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite beta, zeolite Y or ZSM-5. The mesoporous inorganic oxide can be, e.g., silica or alumina, and can optionally include other metals. Methods for making and using the catalytic material are described herein.

公开(公告)号：US20040265210A1

公开(公告)日：2004-12-30

申请号：US10496836

申请日：2004-05-27

发明人： Hisanori Shinohara ,  Masahito Yoshikawa ,  Yuji Ozeki ,  Atsushi Okamoto ,  Motohiro Kuroki

IPC分类号： D01F009/12

CPC分类号： B82Y30/00 ,  B01J29/046 ,  B01J29/072 ,  B01J29/146 ,  B01J29/46 ,  B01J29/86 ,  B01J29/88 ,  B01J29/89 ,  B01J35/065 ,  B01J2229/186 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/02 ,  C01B2202/04 ,  C01B2202/06 ,  C01B2202/34 ,  C01B2202/36 ,  D01F9/127

摘要： A method for preparing hollow nanofibers having carbon as a primary component by contacting a carbon-containing compound with a catalyst at 500 to 1200null C., wherein the catalyst is one of a zeolite exhibiting thermal resistance at 900null C. and, supported thereon, a metal; a metallosilicate zeolite containing a heteroatom except aluminum and silicon and a metal; a supporting material and fine cobalt particles exhibiting a binding energy of a cobalt 2P3/2 electron of 779.3 to 781.0 eV; a supporting material and fine cobalt particles exhibiting a cobalt atom ratio in the surface of the supporting material of 0.1 to 1.5%, as measured by the X-ray photoelectron spectroscopy at 10 kV and 18 mA; a supporting material and fine cobalt particles exhibiting a weight ratio of cobalt to a second metal component of 2.5 or more; and a zeolite having a film form and a metal.

摘要翻译： 一种制备具有碳作为主要成分的中空纳米纤维的方法，其通过使含碳化合物与催化剂在500-1200℃下接触，其中催化剂是在900℃下具有耐热性的沸石之一， ，金属 含有铝和硅以外的杂原子的金属硅酸盐沸石和金属; 表现出779.3〜781.0eV的钴2P3 / 2电子的结合能的支撑材料和细钴粒子; 通过在10kV和18mA的X射线光电子能谱测量，在支撑材料的表面上显示钴原子比为0.1〜1.5％的支撑材料和细钴粒子; 表示钴与第二金属成分的重量比为2.5以上的负载材料和细钴粒子; 和具有膜形式和金属的沸石。

公开(公告)号：US20040179983A1

公开(公告)日：2004-09-16

申请号：US10385180

申请日：2003-03-10

发明人： Prakash G. Balan

IPC分类号： B01F007/00 ,  B01F007/16

CPC分类号： B01J23/38 ,  B01D29/018 ,  B01D29/58 ,  B01J8/009 ,  B01J8/0257 ,  B01J29/89 ,  B01J2208/00814 ,  B01J2208/00849 ,  B01J2208/00876 ,  B01J2208/00884 ,  B01J2229/186 ,  B01J2229/42 ,  Y02P20/582

摘要： A unique reactor configuration especially suitable for interphase mass transfer and mixing of multiple phases, i.e. gas(es), liquid(s), and solid(s) where reaction is catalyzed by a solid catalyst comprises a draught tube reactor wherein the solid catalyst particles are maintained in an annular space between the draught tube of the reactor and an annulus-defining wall by means of filter elements positioned downstream and optionally also upstream from the catalyst bed.

摘要翻译： 特别适用于反应由固体催化剂催化的多相（即气体，液体和固体）的相间传质和混合的独特的反应器构型包括引流管反应器，其中固体催化剂颗粒 通过位于下游和任选地也位于催化剂床上游的过滤元件保持在反应器的引流管和环形壁之间的环形空间中。