公开(公告)号：US09556087B2

公开(公告)日：2017-01-31

申请号：US14201173

申请日：2014-03-07

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Jihad M. Dakka ,  Lorenzo C. DeCaul ,  Victor DeFlorio

IPC: C07C69/76 ,  C07C5/367 ,  C07C67/08 ,  C07C2/74 ,  C07C51/265 ,  B01J29/03 ,  B01J29/08 ,  B01J29/12 ,  B01J29/14 ,  B01J29/70 ,  B01J29/74 ,  B01J29/76

CPC classification number: C07C5/367 ,  B01J29/0325 ,  B01J29/085 ,  B01J29/12 ,  B01J29/14 ,  B01J29/7057 ,  B01J29/7084 ,  B01J29/7415 ,  B01J29/7469 ,  B01J29/7615 ,  B01J29/7669 ,  C07C2/74 ,  C07C51/265 ,  C07C67/08 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2601/14 ,  Y02P20/52 ,  C07C13/28 ,  C07C15/14 ,  C07C63/331 ,  C07C69/76

Abstract: In a process for producing methyl-substituted biphenyl compounds, a feed comprising at least one aromatic hydrocarbon selected from the group consisting of toluene, xylene and mixtures thereof is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes and/or (dimethylcyclohexyl)xylenes together with dialkylated C21+ compounds. At least part of the dialkylated C21+ compounds is then removed from the hydroalkylation reaction product to produce a dehydrogenation feed; and at least part of the dehydrogenation feed is dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of methyl-substituted biphenyl compounds.

Abstract translation: 在生产甲基取代的联苯化合物的方法中，在有效产生加氢烷基化反应的条件下，在加氢烷基化催化剂的存在下，将包含至少一种选自甲苯，二甲苯及其混合物的芳族烃的进料与氢气接触 包含（甲基环己基）甲苯和/或（二甲基环己基）二甲苯与二烷基化C21 +化合物的产物。 然后将至少部分二烷基化C21 +化合物从加氢烷基化反应产物中除去以产生脱氢进料; 并且在有效产生包含甲基取代的联苯化合物的混合物的脱氢反应产物的条件下，在脱氢催化剂存在下，将脱氢进料的至少一部分脱氢。

公开(公告)号：US20160031714A1

公开(公告)日：2016-02-04

申请号：US14862893

申请日：2015-09-23

Applicant: BASF SE

Inventor： Ulrich MUELLER ,  Andrei-Nicolae Parvulescu ,  Jeff Yang ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Stefan Dumser

IPC: C01B39/02 ,  B01J29/70 ,  B01J37/06 ,  B01J37/10 ,  B01J37/00 ,  C01B39/48 ,  B01J35/02

CPC classification number: B01J29/04 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/7065 ,  B01J29/7088 ,  B01J29/86 ,  B01J29/89 ,  B01J35/002 ,  B01J35/026 ,  B01J37/0072 ,  B01J37/009 ,  B01J37/06 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/30 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/12 ,  C01B39/48

Abstract: The present invention relates to a process for process for the preparation of a zeolitic material which process comprises (i) providing a boron-containing zeolitic material and (ii) deboronating the boron-containing zeolitic material by treating the boron-containing zeolitic material with a liquid solvent system thereby obtaining a deboronated zeolitic material, which liquid solvent system does not contain an inorganic or organic acid, or a salt thereof.

公开(公告)号：US20150367334A1

公开(公告)日：2015-12-24

申请号：US14752187

申请日：2015-06-26

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Kazuo SADAOKA ,  Yusuke ANO ,  Koji KASAI

IPC: B01J29/46 ,  B01J21/14 ,  B01J37/08 ,  B01J35/00 ,  B01J37/02 ,  B01J37/00 ,  B01J29/70 ,  B01J35/04

CPC classification number: B01J29/46 ,  B01D39/20 ,  B01D46/00 ,  B01D46/247 ,  B01J21/14 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7057 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0217 ,  B01J37/06 ,  B01J37/08 ,  C04B35/478 ,  C04B38/0006 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3201 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3213 ,  C04B2235/3217 ,  C04B2235/3418 ,  F01N3/0222 ,  F01N3/035 ,  F01N3/2066 ,  C04B38/0645

Abstract: A honeycomb filter comprising a partition wall forming a plurality of flow channels, and a catalyst supported on at least a portion of the surfaces of the partition wall and/or on at least a portion of the pore interiors of the partition wall, wherein the honeycomb filter has a first end face and a second end face, the plurality of flow channels comprising a plurality of first flow channels having their ends closed on the second end face side and a plurality of second flow channels having their ends closed on the first end face side, and when the elemental composition ratio of the partition wall is represented by the following compositional formula (I): Al2(1−x)MgxTi(1+y)O5+aAl2O3+bSiO2+cNa2O+dK2O+eCaO+fSrO  (I), the inequalities 0

Abstract translation: 一种蜂窝过滤器，包括形成多个流动通道的分隔壁和支撑在分隔壁的表面的至少一部分上和/或分隔壁的孔内部的至少一部分上的催化剂，其中蜂窝 过滤器具有第一端面和第二端面，所述多个流动通道包括多个第一流动通道，其端部在第二端面侧封闭，并且多个第二流动通道的端部在第一端面上封闭 并且当分隔壁的元素组成比由以下组成式（I）表示时：Al 2（1-x）Mg x Ti（1 + y）O 5 + aAl 2 O 3 + bSiO 2 + cNa 2 O + d K 2 O + eCaO + fSrO ），不等式0

公开(公告)号：US09168513B2

公开(公告)日：2015-10-27

申请号：US13759573

申请日：2013-02-05

Applicant: BASF SE

Inventor： Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Jeff Yang ,  Hans-Juergen Luetzel ,  Georg Uhl ,  Stefan Dumser

IPC: C01B39/02 ,  B01J29/86 ,  B01J29/04 ,  B01J29/89 ,  B01J29/70 ,  B01J35/00 ,  C01B39/12

CPC classification number: B01J29/04 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/7065 ,  B01J29/7088 ,  B01J29/86 ,  B01J29/89 ,  B01J35/002 ,  B01J35/026 ,  B01J37/0072 ,  B01J37/009 ,  B01J37/06 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/30 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/12 ,  C01B39/48

Abstract: The present invention relates to a process for process for the preparation of a zeolitic material which process comprises (i) providing a boron-containing zeolitic material and (ii) deboronating the boron-containing zeolitic material by treating the boron-containing zeolitic material with a liquid solvent system thereby obtaining a deboronated zeolitic material, which liquid solvent system does not contain an inorganic or organic acid, or a salt thereof.

Abstract translation: 本发明涉及一种制备沸石材料的方法，该方法包括（i）提供含硼沸石材料和（ii）通过用含硼沸石材料处理含硼沸石材料来使硼含量沸石材料脱硼 液体溶剂系统，从而获得脱硼沸石材料，该液体溶剂体系不含无机或有机酸或其盐。

公开(公告)号：US20150290635A1

公开(公告)日：2015-10-15

申请号：US14646349

申请日：2013-11-01

Applicant: HIROSHIMA UNIVERSITY

Inventor： Hitoshi Inokawa ,  Hiroki Miyaoka ,  Yoshitsugu Kojima ,  Takayuki Ichikawa ,  Michihiro Miyake ,  Yoshikazu Kameshima ,  Shunsuke Nishimoto

IPC: B01J37/34 ,  B01J29/14 ,  B01J37/08 ,  B01J35/02 ,  B01J35/10 ,  B01J37/18 ,  B01J31/22 ,  B01J35/00

CPC classification number: B01J37/345 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/087 ,  B01J29/088 ,  B01J29/103 ,  B01J29/106 ,  B01J29/123 ,  B01J29/126 ,  B01J29/143 ,  B01J29/146 ,  B01J29/163 ,  B01J29/166 ,  B01J29/185 ,  B01J29/20 ,  B01J29/22 ,  B01J29/24 ,  B01J29/26 ,  B01J29/40 ,  B01J29/405 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/7053 ,  B01J29/7057 ,  B01J29/7207 ,  B01J29/7215 ,  B01J29/7407 ,  B01J29/7415 ,  B01J29/7607 ,  B01J29/7615 ,  B01J29/7807 ,  B01J29/7815 ,  B01J31/2295 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/02 ,  B01J37/0238 ,  B01J37/03 ,  B01J37/08 ,  B01J37/086 ,  B01J37/16 ,  B01J37/18 ,  B01J37/34 ,  B01J2229/186 ,  B01J2229/34

Abstract: A method for producing a metal nanoparticle complex according to the present invention is a method for producing a metal nanoparticle complex in which metal nanoparticles are supported in pores of a porous body, said method comprising at least: an adsorption step of allowing an organic metal complex to adsorb in pores of a porous body; and a decomposition/reduction step of heating the porous body, which has had the organic metal complex adsorbed in the pores thereof, under a reductive atmosphere to decompose an organic compound in the organic metal complex adsorbed in the pores of the porous body and also reduce a metal cation in the organic metal complex, thereby causing metal nanoparticles to be supported in the pores of the porous body.

Abstract translation: 本发明的金属纳米粒子复合体的制造方法是将金属纳米粒子负载在多孔体的孔中的金属纳米粒子络合物的制造方法，所述方法至少包括：使有机金属络合物 吸附在多孔体的孔中; 以及在还原气氛下加热有机金属络合物吸附在其孔中的多孔体的分解/还原步骤，以分解吸附在多孔体的孔中的有机金属配合物中的有机化合物，并且还可以减少 有机金属络合物中的金属阳离子，从而使金属纳米粒子负载在多孔体的孔中。

公开(公告)号：US09108190B1

公开(公告)日：2015-08-18

申请号：US14025557

申请日：2013-09-12

Applicant: Wei Fan ,  Chun-Chih Chang ,  Paul Dornath ,  Zhuopeng Wang

Inventor： Wei Fan ,  Chun-Chih Chang ,  Paul Dornath ,  Zhuopeng Wang

IPC: B01J29/89 ,  B01J29/04 ,  C07D307/50 ,  B01J29/76 ,  C01B39/06 ,  C01B39/08 ,  B01J29/88 ,  C07H1/00 ,  B01J29/70

CPC classification number: B01J29/89 ,  B01J29/035 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/7615 ,  B01J29/88 ,  B01J2229/16 ,  B01J2229/183 ,  C01B37/005 ,  C01B39/06 ,  C01B39/065 ,  C01B39/085 ,  C01B39/087 ,  C07D307/50 ,  C07H1/00

Abstract: The invention provides methods for rapidly synthesizing heteroatom containing zeolites including Sn-Beta, Si-Beta, Ti-Beta, Zr-Beta and Fe-Beta. The methods for synthesizing heteroatom zeolites include using well-crystalline zeolite crystals as seeds and using a fluoride-free, caustic medium in a seeded dry-gel conversion method. The Beta zeolite catalysts made by the methods of the invention catalyze both isomerization and dehydration reactions.

Abstract translation: 本发明提供快速合成含有Sn-β，Si-β，Ti-β，Zr-β和Fe-β的杂原子的沸石的方法。 合成杂原子沸石的方法包括使用良好结晶的沸石晶体作为种子，并在接种的干凝胶转化方法中使用无氟化的苛性碱介质。 通过本发明方法制备的β沸石催化剂催化异构化和脱水反应。

公开(公告)号：US20150175898A1

公开(公告)日：2015-06-25

申请号：US14560129

申请日：2014-12-04

Applicant: Stephen J. McCarthy ,  Rohit VIJAY ,  Michael Francis RATERMAN ,  Brian PETERSON ,  Karlton J. HICKEY ,  Michel DAAGE ,  Brett LOVELESS ,  Ramesh GUPTA ,  Patricia A. BIELENBERG

Inventor： Stephen J. McCarthy ,  Rohit VIJAY ,  Michael Francis RATERMAN ,  Brian PETERSON ,  Karlton J. HICKEY ,  Michel DAAGE ,  Brett LOVELESS ,  Ramesh GUPTA ,  Patricia A. BIELENBERG

IPC: C10G3/00 ,  C10L1/06

CPC classification number: B01J29/405 ,  B01J21/04 ,  B01J23/06 ,  B01J27/14 ,  B01J29/061 ,  B01J29/40 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/90 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/28 ,  B01J38/02 ,  B01J38/12 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07C1/20 ,  C07C1/22 ,  C07C2523/06 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/70 ,  C10G3/45 ,  C10G3/49 ,  C10G3/55 ,  C10L1/06 ,  C10L2200/0423 ,  C10L2200/0469 ,  C10L2270/023 ,  Y02P20/584 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02 ,  C07C15/02

Abstract: Methods for organic compound conversion are disclosed. Particular methods include providing a first mixture comprising ≧10.0 wt % of at least one oxygenate, based on the weight of the first mixture; contacting said first mixture in at least a first moving bed reactor with a catalyst under conditions effective to covert at least a portion of the first mixture to a product stream comprising water, hydrogen, and one or more hydrocarbons; and separating from said product stream (i) at least one light stream and ii) at least one heavy stream, wherein the method is characterized by a recycle ratio of ≦5.0.

Abstract translation: 公开了有机化合物转化方法。 具体方法包括提供基于第一混合物的重量的包含≥10.0wt％的至少一种含氧化合物的第一混合物; 在有效地将至少一部分第一混合物转化成包含水，氢和一种或多种烃的产物流的条件下，使至少第一移动床反应器中的第一混合物与催化剂接触; 和从所述产物流（i）分离至少一种轻质物流和ii）至少一种重质流，其中所述方法的特征在于再循环比为＆lt;

公开(公告)号：US20150141670A1

公开(公告)日：2015-05-21

申请号：US14561351

申请日：2014-12-05

Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY

Inventor： MARK E. DAVIS ,  JOSHUA J. PACHECO

IPC: C07D493/08

CPC classification number: C07D493/08 ,  B01J29/0341 ,  B01J29/035 ,  B01J29/047 ,  B01J29/405 ,  B01J29/7057 ,  B01J29/89 ,  B01J2229/183 ,  C07C2/862 ,  C07C2/865 ,  C07C29/32 ,  C07C45/70 ,  C07C51/353 ,  C07C67/343 ,  C07C67/347 ,  C07C2529/00 ,  C07C2529/70 ,  C07C2529/89 ,  Y02P20/52 ,  C07C69/76 ,  C07C65/01 ,  C07C65/21 ,  C07C63/04 ,  C07C63/26 ,  C07C47/542 ,  C07C33/26 ,  C07C47/56 ,  C07C69/82 ,  C07C63/06 ,  C07C15/08

Abstract: The present disclosure is related to silica-based Lewis acid catalysts, being essentially devoid of strong Brønsted acid character, and their ability to effect the [4+2] cycloaddition and dehydrative aromatization of dienes and dienophiles containing oxygenated substituents to form substituted benzene products. In some embodiments, the processes comprise contacting biomass-derived substrates with ethylene to form terephthalic acid and its derivatives.

Abstract translation: 本公开涉及基本上没有强布朗斯台德酸性质的二氧化硅基路易斯酸催化剂，以及它们对含有氧化取代基的二烯和亲烯体的[4 + 2]环加成和脱水芳构化的能力，以形成取代的苯产物。 在一些实施方案中，该方法包括使生物质衍生的底物与乙烯接触以形成对苯二甲酸及其衍生物。

公开(公告)号：US08703635B2

公开(公告)日：2014-04-22

申请号：US13909326

申请日：2013-06-04

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Christine N. Elia ,  Frederick Y. Lo ,  Jeffrey T. Elks ,  Darryl D. Lacy ,  Mohan Kalyanaraman

IPC: B01J29/06

CPC classification number: B01J29/7088 ,  B01J21/063 ,  B01J29/08 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/80 ,  B01J37/0009 ,  B01J2229/42 ,  C07C2/66 ,  C07C6/126 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2529/70

Abstract: This disclosure relates to a catalyst composition comprising (a) MCM-22 family material; and (b) a binder comprising at least 1 wt. % of a titanium compound based on the weight of said catalyst composition, wherein said titanium compound was anatase and rutile phases.

Abstract translation: 本公开内容涉及包含（a）MCM-22族材料的催化剂组合物; 和（b）包含至少1重量％ ％的钛化合物，基于所述催化剂组合物的重量，其中所述钛化合物是锐钛型和金红石相。

公开(公告)号：US20140018232A1

公开(公告)日：2014-01-16

申请号：US13321056

申请日：2011-04-02

Applicant: Ye Wang ,  Jincan Kang ,  Lei Zhang ,  Qinghong Zhang ,  Kang Cheng ,  Qingge Zhai ,  Jiansheng Ding ,  Weiqi Hua ,  Yinchuan Lou

Inventor： Ye Wang ,  Jincan Kang ,  Lei Zhang ,  Qinghong Zhang ,  Kang Cheng ,  Qingge Zhai ,  Jiansheng Ding ,  Weiqi Hua ,  Yinchuan Lou

IPC: B01J29/80 ,  B01J29/14 ,  B01J29/48 ,  B01J29/76 ,  B01J29/24 ,  B01J29/46 ,  B01J29/78

CPC classification number: B01J29/80 ,  B01J29/072 ,  B01J29/088 ,  B01J29/146 ,  B01J29/166 ,  B01J29/185 ,  B01J29/22 ,  B01J29/24 ,  B01J29/26 ,  B01J29/405 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/7007 ,  B01J29/7038 ,  B01J29/7057 ,  B01J29/7088 ,  B01J29/7615 ,  B01J29/7676 ,  B01J29/7815 ,  B01J29/7876 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/18 ,  B01J2229/38 ,  C01B39/40 ,  C01B39/48 ,  C10G2/332 ,  C10G2/334 ,  C10G2300/70 ,  C10G2400/02 ,  C10L1/04

Abstract: The invention relates to a catalyst for selective synthesis of high-quality gasoline fractions from syngas and the preparation method of the catalyst. This catalyst consists of cobalt, a promoter and molecular sieve, wherein cobalt is presented in an amount of 1-30%, the promoter is represented in an amount of 0.01-5% and the balance is molecular sieve based on the weight of the catalyst. This catalyst provides superior selectivity for C5-C11 isoparaffins and relatively lower selectivity for wax-type hydrocarbons with more than 20 carbon atoms. Thereof, this catalyst can be used for the synthesis of high-quality gasoline and is good at preventing catalyst coking. Besides, the invention provides a preparation method of the catalyst.

Abstract translation: 本发明涉及用于从合成气中选择性合成高品质汽油馏分的催化剂及其制备方法。 该催化剂由钴，助催化剂和分子筛组成，其中钴的含量为1-30％，助催化剂的用量为0.01-5％，余量为基于催化剂重量的分子筛 。 该催化剂为C5-C11异链烷烃提供了优异的选择性，并且具有超过20个碳原子的蜡型烃具有较低的选择性。 因此，该催化剂可用于合成优质汽油，并且有效地防止催化剂焦化。 此外，本发明提供了催化剂的制备方法。