公开(公告)号：US20150174561A1

公开(公告)日：2015-06-25

申请号：US14560062

申请日：2014-12-04

Applicant: Stephen J. McCarthy ,  Rohit Vijay ,  Brett Loveless

Inventor： Stephen J. McCarthy ,  Rohit Vijay ,  Brett Loveless

IPC: B01J29/40 ,  B01J23/06 ,  C07C1/22

CPC classification number: B01J29/405 ,  B01J21/04 ,  B01J23/06 ,  B01J27/14 ,  B01J29/061 ,  B01J29/40 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/90 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/28 ,  B01J38/02 ,  B01J38/12 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07C1/20 ,  C07C1/22 ,  C07C2523/06 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/70 ,  C10G3/45 ,  C10G3/49 ,  C10G3/55 ,  C10L1/06 ,  C10L2200/0423 ,  C10L2200/0469 ,  C10L2270/023 ,  Y02P20/584 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02 ,  C07C15/02

Abstract: A catalyst composition comprises a self-bound zeolite and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10−2 sec−1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).

Abstract translation: 催化剂组合物包含自结合沸石和选自Zn，Cd或其组合的第12族过渡金属，硅与铝的比例为至少约10，催化剂组合物具有微孔 表面积为至少约340m 2 / g，第12族过渡金属与铝的摩尔比为约0.1至约1.3，以及至少一种：（a）大于约20m 2 / g的中孔度; （b）当在约120℃的温度和约60托（约8kPa）的2,2-二甲基丁烷压力下测量时，对于大于约1×10 -2秒-1的2,2-二甲基丁烷的扩散性 ）。

公开(公告)号：US09040766B2

公开(公告)日：2015-05-26

申请号：US12782498

申请日：2010-05-18

Applicant: Mika Kettunen ,  Vaino Sippola ,  Marja Tiitta

Inventor： Mika Kettunen ,  Vaino Sippola ,  Marja Tiitta

IPC: C07C5/13 ,  C07C5/22 ,  C07C5/03 ,  B01J29/00 ,  B01J29/064 ,  B01J29/068 ,  C07C5/27 ,  C07C9/22 ,  C10G45/62 ,  C10G45/64 ,  C10L1/08 ,  C10G3/00 ,  B01J29/03 ,  B01J29/70 ,  B01J29/85

CPC classification number: C07C5/03 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/064 ,  B01J29/068 ,  B01J29/70 ,  B01J29/85 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2229/62 ,  C07C5/2775 ,  C07C9/22 ,  C10G3/45 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G45/62 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/08 ,  Y02P30/10 ,  Y02P30/20

Abstract: The invention relates to a method for the manufacture of branched saturated hydrocarbons, said method comprising the steps where a feed comprising olefins having at least 10 carbons is simultaneously hydrogenated and isomerized in the presence of hydrogen at a temperature of 100-400° C., under hydrogen partial pressure of 0.01-10 MPa, in the presence of a catalyst comprising a metal selected from the metals of Group VIIIb of the Periodic Table of Elements, a molecular sieve selected from ten member ring molecular sieves, twelve member ring molecular sieves and mesoporous molecular sieves embedded with zeolite, and a carrier, to yield branched saturated hydrocarbons.

Abstract translation: 本发明涉及一种制备支链饱和烃的方法，所述方法包括以下步骤：其中包含具有至少10个碳原子的烯烃的进料在氢气存在下在100-400℃的温度下同时氢化和异构化， 在氢分压为0.01-10MPa的条件下，在包含选自元素周期表第Ⅷb族金属的金属催化剂存在下，选自十个成员环分子筛，十二个成员环分子筛和 嵌入沸石的介孔分子筛和载体，得到支链饱和烃。

公开(公告)号：US20150112110A1

公开(公告)日：2015-04-23

申请号：US14517583

申请日：2014-10-17

Applicant: SK INNOVATION CO., LTD. ,  SK LUBRICANTS CO., LTD.

Inventor： Yoon Kyung LEE ,  Seung Woo LEE ,  Jae Suk CHOI ,  Tae Jin Kim ,  Do Woan Kim ,  Seon Ju Lim

IPC: B01J29/70 ,  C07C5/27 ,  B01J29/78

CPC classification number: B01J29/7023 ,  B01J29/041 ,  B01J29/043 ,  B01J29/044 ,  B01J29/045 ,  B01J29/703 ,  B01J29/74 ,  B01J29/7461 ,  B01J29/76 ,  B01J29/7661 ,  B01J29/78 ,  B01J29/7846 ,  B01J29/7861 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/109 ,  B01J35/1095 ,  B01J2229/10 ,  B01J2229/14 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/26 ,  B01J2229/38 ,  B01J2229/42 ,  C07C5/2775 ,  C07C2529/06 ,  C07C2529/068 ,  C07C2529/072 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2529/76 ,  C10G45/64

Abstract: Disclosed herein is an activated EU-2 zeolite, including: pores having a diameter of 30 to 40 Å while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 Å, wherein the volume of the pores having a diameter of 30 to 40 Å is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 Å is 0.07 to 0.4 cc/g.

Abstract translation: 本文公开了一种活化的EU-2沸石，其包括：直径为30至40埃的孔，同时保持EU-2沸石的晶体结构; 直径为40〜200埃的孔，其直径为30〜40的孔的体积为0.01〜0.06cc / g，直径为40〜200的孔的体积为0.07〜 0.4cc / g。

公开(公告)号：US08901026B2

公开(公告)日：2014-12-02

申请号：US12527232

申请日：2008-01-28

Applicant: Richard Franklin Wormsbecher ,  Ruizhong Hu

Inventor： Richard Franklin Wormsbecher ,  Ruizhong Hu

IPC: B01J29/08 ,  B01J23/06 ,  B01J23/10 ,  C10G11/05 ,  C10G11/18 ,  B01J29/06

CPC classification number: B01J29/088 ,  B01J29/061 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/1037 ,  C10G2300/202 ,  C10G2400/02

Abstract: A catalytic cracking catalyst composition is disclosed that is suitable for reducing the sulfur content of catalytically cracking liquid products, in particularly gasoline products, produced during a catalytic cracking process. Preferably, the catalytic cracking process is a fluidized catalytic cracking (FCC) process. The composition comprises zeolite, zinc and at least one rare earth element having an ionic radius of less than 0.95 Å at a coordination number of 6. Preferably, zinc and the rare earth element are present as cations that have been exchanged on the zeolite. The zeolite is preferably a Y-type zeolite.

Abstract translation: 公开了一种催化裂化催化剂组合物，其适于降低在催化裂化过程中产生的催化裂化液体产物，特别是汽油产品中的硫含量。 优选地，催化裂化过程是流化催化裂化（FCC）方法。 组合物包含沸石，锌和至少一种具有小于0.95的离子半径的至少一种稀土元素，配位数为6.优选地，锌和稀土元素以在沸石上交换的阳离子存在。 沸石优选为Y型沸石。

公开(公告)号：US08882993B2

公开(公告)日：2014-11-11

申请号：US13412812

申请日：2012-03-06

Applicant: Wenyih Frank Lai ,  Robert E. Kay ,  Jason Wu ,  Kun Wang ,  Robert C. Lemon

Inventor： Wenyih Frank Lai ,  Robert E. Kay ,  Jason Wu ,  Kun Wang ,  Robert C. Lemon

IPC: B01J29/08 ,  B01J29/06 ,  B01J29/10 ,  B01J29/12 ,  C10G35/095 ,  C10G35/06 ,  C10G35/04

CPC classification number: C10G11/18 ,  B01J29/084 ,  B01J29/088 ,  B01J29/126 ,  B01J29/166 ,  B01J35/10 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/42 ,  C01B39/24 ,  C07C2/58 ,  C07C2/66 ,  C07C4/18 ,  C07C5/2518 ,  C07C5/2737 ,  C07C5/2775 ,  C07C6/123 ,  C07C6/126 ,  C07C2523/10 ,  C07C2529/08 ,  C10G45/62 ,  C10G45/64 ,  C10G47/14 ,  C10G47/16 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/085 ,  C07C15/08 ,  C07C15/04 ,  C07C11/02

Abstract: This invention relates to stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 μm. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more.

Abstract translation: 本发明涉及聚集成较大二次颗粒的沸石Y的小初级微晶的稳定聚集体。 至少80％的二次粒子可以包含至少5个初级微晶。 初级微晶的尺寸可以为至多约0.5微米，或至多约0.3微米，并且二次颗粒的尺寸可以为至少约0.8微米，或至少约1.0微米。 得到的稳定的聚集Y型沸石的二氧化硅与氧化铝的比例可以为4:1以上。

公开(公告)号：US08877669B2

公开(公告)日：2014-11-04

申请号：US13193890

申请日：2011-07-29

Applicant: Michael A. Loewenstein ,  Ahmad Moini ,  Ivan Petrovic

Inventor： Michael A. Loewenstein ,  Ahmad Moini ,  Ivan Petrovic

IPC: B01J29/06 ,  B01J27/182 ,  C10G3/00 ,  B01J37/08 ,  C10G65/04 ,  C10G45/64 ,  B01J29/85 ,  B01J29/74 ,  C10G45/62 ,  C10G45/02 ,  C10L1/02 ,  B01J37/02 ,  B01J23/755 ,  B01J23/40 ,  B01J23/89

CPC classification number: B01J29/7461 ,  B01J23/40 ,  B01J23/755 ,  B01J23/892 ,  B01J29/7469 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/85 ,  B01J37/0201 ,  B01J37/088 ,  B01J2229/20 ,  B01J2229/42 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G45/02 ,  C10G45/62 ,  C10G45/64 ,  C10G65/043 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08 ,  C10G2400/10 ,  C10L1/026 ,  Y02E50/13 ,  Y02P30/20

Abstract: Provided are hydroisomerization catalysts for processing a bio-based feedstock into biodiesel fuels. These catalysts comprise a catalytic material and a matrix component. The catalytic material is made up of a molecular sieve that has a pre-loaded platinum group metal. The catalytic material and the matrix component are processed together to form the hydroisomerization catalyst. Methods of making these hydroisomerization catalysts include synthesizing a molecular sieve; purifying the molecular sieve; associating the molecular sieve with a platinum group metal in the absence of the matrix component to form the pre-loaded molecular sieve before formation of a catalyst body; mixing the pre-loaded molecular sieve with the matrix component to form a mixture; processing the mixture to form a catalyst body; and drying and calcining the catalyst body to form the hydroisomerization catalyst. These hydroisomerization catalysts can be used to process hydrodeoxygenated plant- or animal-derived feeds to yield a biofuel.

Abstract translation: 提供了用于将生物基原料加工成生物柴油燃料的加氢异构化催化剂。 这些催化剂包括催化材料和基质组分。 催化材料由具有预加载的铂族金属的分子筛组成。 将催化材料和基体组分一起加工以形成加氢异构化催化剂。 制造这些加氢异构化催化剂的方法包括合成分子筛; 净化分子筛; 在不存在基质组分的情况下使分子筛与铂族金属缔合，在形成催化剂体之前形成预加载的分子筛; 将预加载的分子筛与基质组分混合以形成混合物; 处理混合物以形成催化剂体; 并干燥和煅烧催化剂体以形成加氢异构化催化剂。 这些加氢异构化催化剂可用于处理加氢脱氧的植物或动物来源的饲料以产生生物燃料。

公开(公告)号：US20140243188A1

公开(公告)日：2014-08-28

申请号：US14269905

申请日：2014-05-05

Applicant: W. R. GRACE & CO.-CONN.

Inventor： Ranjit KUMAR

IPC: B01J29/08

CPC classification number: B01J29/088 ,  B01J21/04 ,  B01J29/06 ,  B01J29/084 ,  B01J29/18 ,  B01J29/40 ,  B01J29/7007 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/05 ,  C10G11/18 ,  C10G2300/405 ,  C10G2400/02

Abstract: Alumina binder obtained from aluminum sulfate, the process of preparing the binder and the process of using the binder to prepare catalyst compositions are disclosed. Catalytic cracking catalyst compositions, in particularly, fluid catalytic cracking catalyst composition comprising zeolites, optionally clay and matrix materials bound by an alumina binder obtained from aluminum sulfate are disclosed.

Abstract translation: 公开了由硫酸铝获得的氧化铝粘合剂，制备粘合剂的方法和使用该粘合剂制备催化剂组合物的方法。 公开了催化裂化催化剂组合物，特别是包含由由硫酸铝获得的氧化铝粘合剂结合的沸石，任选的粘土和基质材料的流化催化裂化催化剂组合物。

公开(公告)号：US08790507B2

公开(公告)日：2014-07-29

申请号：US13159695

申请日：2011-06-14

Applicant: Kamala Krishna ,  Guan-Dao Lei

Inventor： Kamala Krishna ,  Guan-Dao Lei

IPC: C10G65/02 ,  C10G45/64

CPC classification number: C10G65/043 ,  B01J23/58 ,  B01J29/70 ,  B01J29/7492 ,  B01J29/80 ,  B01J37/0201 ,  B01J37/0244 ,  B01J2229/20 ,  B01J2229/42 ,  C01B39/48 ,  C10G45/62 ,  C10G45/64 ,  C10G65/04 ,  C10G2300/1022 ,  C10G2300/301 ,  C10G2300/304 ,  C10G2400/10

Abstract: Processes and catalyst systems are provided for dewaxing a hydrocarbon feedstock to form a lubricant base oil. A layered catalyst system of the present invention may comprise a first hydroisomerization dewaxing catalyst disposed upstream from a second hydroisomerization dewaxing catalyst. Each of the first and second hydroisomerization dewaxing catalysts may be selective for the isomerization of n-paraffins. The first hydroisomerization catalyst may have a higher level of selectivity for the isomerization of n-paraffins than the second hydroisomerization dewaxing catalyst. At least one of the first and second hydroisomerization dewaxing catalysts comprises small crystallite zeolite SSZ-32x.

Abstract translation: 提供了用于使烃原料脱蜡以形成润滑剂基础油的方法和催化剂体系。 本发明的层状催化剂体系可以包含设置在第二加氢异构化脱蜡催化剂上游的第一加氢异构化脱蜡催化剂。 第一和第二加氢异构化脱蜡催化剂中的每一种可以是正链烷烃异构化的选择性。 与第二加氢异构化脱蜡催化剂相比，第一加氢异构化催化剂对正链烷烃的异构化可具有更高的选择性。 第一和第二加氢异构化脱蜡催化剂中的至少一种包括小型微晶沸石SSZ-32x。

公开(公告)号：US08754247B2

公开(公告)日：2014-06-17

申请号：US13057846

申请日：2009-07-21

Applicant: Amandine Cabiac ,  Nicolas Cadran ,  Emmanuelle Guillon ,  Vincent Lecocq ,  Sylvie Maury

Inventor： Amandine Cabiac ,  Nicolas Cadran ,  Emmanuelle Guillon ,  Vincent Lecocq ,  Sylvie Maury

IPC: C09F7/00 ,  C11C3/00 ,  B01J29/04 ,  B01J29/06 ,  C07C2/68

CPC classification number: C11C3/003 ,  B01J29/70 ,  B01J29/7049 ,  B01J2229/20 ,  C07C1/24 ,  C07C2/66 ,  C07C11/02 ,  C10G45/12 ,  C10G50/00 ,  C10G2300/1088 ,  C10G2300/1096 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30 ,  Y02P30/42 ,  C07C15/107

Abstract: A catalyst is described which comprises at least one IZM-2 zeolite and at least one matrix, said zeolite having a chemical composition expressed as the anhydrous base in terms of moles of oxides by the following general formula: XO2: aY2O3: bMnO, in which X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or alkaline-earth metal, a and b respectively representing the number of moles of Y2O3 and MnO; and a is in the range 0.001 to 0.5, b is in the range 0 to 1 and n is in the range 1 to 2. Said catalyst is used in various processes for the transformation of hydrocarbon feeds.

Abstract translation: 描述了包含至少一种IZM-2沸石和至少一种基质的催化剂，所述沸石具有以氧化物的摩尔数表示为无水碱的化学组成，通过以下通式：XO 2：aY 2 O 3：bMnO，其中 X表示至少一种四价元素，Y表示至少一种三价元素，M表示至少一种碱金属和/或碱土金属，a和b分别表示Y 2 O 3和MnO的摩尔数; a在0.001至0.5的范围内，b在0至1的范围内，n在1至2的范围内。所述催化剂用于烃进料转化的各种方法中。

公开(公告)号：US20140162871A1

公开(公告)日：2014-06-12

申请号：US14007711

申请日：2012-03-26

Applicant: Marie Iwama

Inventor： Marie Iwama

IPC: B01J29/12

CPC classification number: B01J29/126 ,  B01J21/12 ,  B01J29/106 ,  B01J29/166 ,  B01J37/0018 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/10 ,  C10G47/14 ,  C10G49/06 ,  C10G65/14 ,  C10G2300/1022

Abstract: The present invention provides a method for producing a hydroprocessing catalyst including a supporting step of allowing a catalyst support having a content of a carbonaceous substance containing carbon atoms of 0.5% by mass or less in terms of carbon atoms to support an active metal component containing at least one active metal element selected from metals belonging to Group 6, Group 8, Group 9 and Group 10 in the periodic table, to obtain a catalyst precursor, and a calcining step of calcining the catalyst precursor obtained in the supporting step to obtain the hydroprocessing catalyst.

Abstract translation: 本发明提供一种加氢处理催化剂的制造方法，其特征在于，包括使碳原子数为碳原子数为0.5质量％以下的含碳物质的催化剂载体的支持工序，以支持含有 选自元素周期表中第6族，第8族，第9族和第10族的金属的至少一种活性金属元素，以获得催化剂前体，煅烧步骤，在支持步骤中煅烧获得的催化剂前体以获得加氢处理 催化剂。